Modified poly (arylene ether) resin composition, method of preparing the same and molded article produced thereof

Patent metadata

Field	Value
Publication number	US-10072149-B2
Application number	US-201615111746-A
Country	US
Kind code	B2
Filing date	Feb 17, 2016
Priority date	Jul 14, 2015
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Disclosed is a poly(arylene ether) resin composition, and more specifically, a modified poly(arylene ether) resin composition including a poly(arylene ether) resin, a poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, a polyamide resin, a polyolefin resin, and an encapsulating agent, wherein the polyolefin resin is encapsulated by the encapsulating agent with the poly(arylene ether) resin and the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, and a molded article produced therefrom. The disclosed composition has an effect of providing a modified poly(arylene ether) resin composition which has less change in physical properties caused by moisture, and has low specific gravity and superior impact strength, weatherability and balance in physical properties.

First claim

What is claimed is:

1. A modified poly(arylene ether) resin composition comprising:
a poly(arylene ether) resin in an amount of 10-40% by weight;
1 to 10% by weight, with respect to the modified poly(arylene ether) resin composition, of a poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof;
a polyamide resin;
a polyolefin resin; and
an encapsulating agent,
wherein the modified poly(arylene ether) resin composition has a morphology comprising:
a) a domain resin comprising a core, the core comprising the polyolefin resin, a capsule surrounding the core, the capsule comprising the poly(arylene ether) resin and the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, and a membrane formed by the encapsulating agent between the core and the capsule; and
b) a matrix resin comprising the polyamide resin and wherein the composition has a notched Izod impact strength exceeding 11 kgf·cm/cm2.

2. The modified poly(arylene ether) resin composition according to claim 1 , wherein the poly(arylene ether) resin is a homopolymer having a unit represented by the following Formula 1 or Formula 2, or a copolymer having a unit represented by the following Formula 1 or Formula 2:

wherein R a , R 1 , R 2 , R 3 and R 4 are substituents of an arylene group (Ar) or a phenylene group, which are each independently or simultaneously a hydrogen, chlorine, bromine, iodine, methyl, ethyl, propyl, allyl, phenyl, methylbenzyl, chloromethyl, bromomethyl, cyanoethyl, cyano, methoxy, phenoxy or nitro group, n an integer of 4 to 20, and Ar is a C7-C20 arylene group.

3. The modified poly(arylene ether) resin composition according to claim 1 , wherein the poly(arylene ether) resin has a weight average molecular weight of 10,000 to 100,000 g/mol.

4. The modified poly(arylene ether) resin composition according to claim 1 , wherein a total content of the poly(arylene ether) resin, and the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof is present in an amount of 20% by weight or higher, with respect to the modified poly(arylene ether) resin composition.

5. The modified poly(arylene ether) resin composition according to claim 1 , wherein the polyamide resin is present in an amount of 30 to 70% by weight, with respect to the modified poly(arylene ether) resin composition.

6. The modified poly(arylene ether) resin composition according to claim 1 , wherein the polyolefin resin is a homopolymer of olefin or a copolymer of olefin and other vinyl monomers.

7. The modified poly(arylene ether) resin composition according to claim 1 , wherein the polyolefin resin is present in an amount of 1 to 20% by weight, with respect to the modified poly(arylene ether) resin composition.

8. The modified poly(arylene ether) resin composition according to claim 1 , wherein the encapsulating agent is a styrene-based block copolymer.

9. The modified poly(arylene ether) resin composition according to claim 1 , wherein the encapsulating agent comprises one or more selected from the group consisting of a styrene-butadiene copolymer, a styrene-ethylene-propylene copolymer, a styrene-isoprene copolymer, an α-methylstyrene-butadiene copolymer, a styrene-butadiene-styrene copolymer, a styrene-ethylene-propylene-styrene copolymer, a styrene-ethylene-butylene-styrene copolymer, a styrene-(ethylene-butylene/styrene copolymer)-styrene copolymer, a styrene-isoprene-styrene copolymer, an α-methylstyrene-butadiene-α-methylstyrene copolymer and hydrogenated analogs thereof.

10. The modified poly(arylene ether) resin composition according to claim 1 , wherein the encapsulating agent is present in an amount of 1 to 20% by weight, with respect to the modified poly(arylene ether) resin composition.

11. A modified poly(arylene ether) resin composition comprising:
a poly(arylene ether) resin;
a poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof;
a polyamide resin;
a polyolefin resin; and
an encapsulating agent,
wherein the modified poly(arylene ether) resin composition has a morphology comprising:
a) a domain resin comprising a core, the core comprising the polyolefin resin, a capsule surrounding the core, the capsule comprising the poly(arylene ether) resin and the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, and a membrane formed by the encapsulating agent between the core and the capsule; and
b) a matrix resin comprising the polyamide resin,

wherein the modified poly(arylene ether) resin composition further comprises 0.1 to 5% by weight of an inorganic filler and wherein the composition has a notched Izod impact strength exceeding 11 kgf·cm/cm2.

12. The modified poly(arylene ether) resin composition according to claim 11 , wherein the inorganic filler comprises one or more selected from the group consisting of talc, wollastonite, calcium carbonate, wood flour, chalk, glass flakes and glass fibers.

13. The modified poly(arylene ether) resin composition according to claim 1 , wherein the modified poly(arylene ether) resin composition has a specific gravity of 1.09 or less.

14. The modified poly(arylene ether) resin composition according to claim 1 , wherein the modified poly(arylene ether) resin composition has an impact strength exceeding 15 kgf·cm/cm 2 , measured in accordance with ASTM D256.

15. A molded article produced from the modified poly(arylene ether) resin composition according to claim 1 .

16. The modified poly(arylene ether) resin composition according to claim 1 , comprising:
10 to 40% by weight of the poly(arylene ether) resin, with respect to the modified poly(arylene ether) resin composition;
1 to 10% by weight of the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, with respect to the modified poly(arylene ether) resin composition;
30 to 70% by weight of the polyamide resin, with respect to the modified poly(arylene ether) resin composition;
1 to 20% by weight of the polyolefin resin, with respect to the modified poly(arylene ether) resin composition; and
1 to 20% by weight of the encapsulating agent, with respect to the modified poly(arylene ether) resin composition.

17. The modified poly(arylene ether) resin composition according to claim 1 , wherein the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof comprises 0.05 to 2% by weight unsaturated carboxylic acid or an anhydride thereof, with respect to the poly(arylene ether) resin.

18. The modified poly(arylene ether) resin composition according to claim 1 , wherein a total content of the poly(arylene ether) resin, and the poly(arylene ether) resin modified with unsaturated carboxylic acid or an anhydride thereof, is present in an amount of 20 to 40% by weight, with respect to the modified poly(arylene ether) resin composition.

Assignees

• Lg Chemical Ltd

Inventors

• Park Nam Jib
• Lee Sang Ho
• Ju Se Yeong
• Lee Sung Ho
• Ahn Sung Tae

Classifications

• C08L71/126

  modified by chemical after-treatment · CPC title

• C08L71/12 Primary

  Polyphenylene oxides · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L71/123

  not modified by chemical after-treatment · CPC title

• C08L2207/53

  Core-shell polymer · CPC title