Method and apparatus for preconcentrating a gaseous sample

Patent metadata

Field	Value
Publication number	US-10067100-B2
Application number	US-201615139703-A
Country	US
Kind code	B2
Filing date	Apr 27, 2016
Priority date	Apr 30, 2015
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

A system for concentrating an analyte gas in a gas stream of an analytical system is provided. The system comprises at least one separation device, at least one gas inlet line, at least one detector, at least one gas outlet line, a first split line in connected to the gas inlet line, and a first split valve for controlling gas flow in the first split line. Also provided is a method for concentrating an analyte gas.

First claim

The invention claimed is:

1. A system for concentrating an analyte gas in a gas stream of an analytical system, the system comprising
at least one separation device, for separating components of an analyte gas;
at least one gas inlet line, for delivering the analyte gas from a supply of analyte gas to the separation device;
at least one detector, for detecting components of the analyte gas;
at least one gas outlet line, for delivering the components from the separation device to the detector;
a first split line in fluid communication with the gas inlet line at a first junction, and a first split valve for controlling gas flow in the first split line;
wherein opening of the first split line releases a part of a gas flow through the first split line and thereby reduces a flow rate through the separation device.

2. The system of claim 1 , further comprising a second split line in fluid communication with the gas outlet line at a second junction, upstream from the detector, and a second split valve for controlling gas flow in the second split line.

3. The system of claim 2 , wherein the second split valve for controlling gas flow is arranged at the second junction, the valve having a first position in which gas is able to flow through the second split line and the gas outlet line towards the detector, and a second position in which gas is able to flow along the gas outlet line towards the detector but is prevented from flowing along the second split line.

4. The system of claim 2 , wherein the first split line and the second split line meet at a split line junction, and wherein a flow control gas line is connected to the split line junction.

5. The system of claim 4 , wherein the split line junction comprises a split line valve for selectively controlling gas flow in the first split line, the second split line and/or the flow control gas line.

6. The system of claim 4 , wherein the flow control gas line further comprises a flow controlling device that is provided as a first restriction line and a second restriction line that meet at a restriction junction that is fluidly connected to the flow control gas line, and wherein the first restriction line and the second restriction line each comprise a fixed flow restriction for controlling gas flow.

7. The system of claim 6 , wherein a valve for controlling gas flow is positioned at the restriction junction, the valve having a first position, in which gas is able to flow through the first restriction line but is prevented from flowing through the second restriction line, and a second position, in which gas is able to flow through the second restriction line but is prevented from flowing through the first restriction line.

8. The system of claim 1 , wherein the first and/or second split valve has a first position in which gas is able to flow through the split line, and a second position in which gas is prevented from flowing through the split line.

9. The system of claim 1 , wherein the first split line and/or the second split line is open to atmosphere.

10. The system of claim 1 , wherein the first split line and/or the second split line is connected to a gas supply line for providing gas into the supply of analyte gas and/or a sample introduction system for providing a sample into the supply of analyte gas.

11. The system of claim 1 , wherein the first split valve for controlling gas flow is arranged at the first junction, the valve having a first position in which gas is able to flow through the first split line and the gas inlet line towards the separating device, and a second position in which gas is able to flow along the gas inlet line towards the separation device but is prevented from flowing through the first split line.

12. The system of claim 1 , wherein the analyte gas is provided in a carrier gas that is preferably selected from helium and argon.

13. The system of claim 1 , where the supply of analyte gas is provided by a chemical reactor.

14. The system of claim 1 , further comprising a chemical trap that is arranged upstream of the separation device on the gas inlet line.

15. The system of claim 1 , further comprising a secondary carrier gas inlet line that is fluidly connected to the gas inlet line at a carrier gas junction, between the analyte gas supply and the first split line.

16. The system of claim 15 , wherein the secondary carrier gas inlet line is provided with gas flow control means for controlling gas flow into the gas inlet line.

17. The system of claim 15 , further comprising an analyte gas split line that is arranged on the gas inlet line, between the analyte gas supply and the carrier gas junction, the analyte gas split line further comprising a valve for directing flow of gas through the analyte gas split line, the valve having a first position in which analyte gas is able to flow through the analyte gas split line and in which gas is prevented from flowing through the gas inlet line downstream from the analyte gas split line, and a second position in which analyte gas is prevented from flowing through the analyte gas split line but is able to flow through the gas inlet line.

18. The system of claim 15 , further comprising a valve arranged at, or in fluid communication with, the carrier gas junction, wherein the valve has a first position in which gas is able to flow from the analyte gas supply through the gas inlet line towards the first junction and in which the secondary carrier gas is prevented from flowing into the gas inlet line, and a second position in which analyte gas is prevented from flowing from the analyte gas supply through the gas inlet line towards the first junction and in which the secondary carrier gas is able to flow into the gas inlet line, towards the first junction.

19. The system of claim 1 , further comprising a second separation device, wherein the second separation device is arranged downstream from the second split line, between the second split line and the detector.

20. The system of claim 1 , further comprising a controller for controlling valve position of at least one of the valves, and wherein the controller optionally receives an input from the detector, and wherein the position of at least one valve is based on the determination of presence or absence of at least one component of the analyte gas.

21. The system of claim 20 , wherein the controller receives an input from the detector about at least one analyte gas, and wherein the position of at least one valve is adjusted based on a determination of the concentration of the analyte gas.

22. The system of claim 20 , wherein the controller is configured to simultaneously adjust the position of two or more valves, so that the controller is configured to adjust the position of the first split valve and the second split valve, so that when the first split valve is open the second split valve is closed, and so that when the first split valve is closed the second split valve is open.

23. The system of claim 1 , wherein the separation device is a gas chromatograph.

24. A method of concentrating a sample gas for detection in a continuous flow retention-based analytical device having a gas inlet and a gas outlet, the method comprising steps of:
providing a flow of gas into the analytical device at a first flow rate, wherein the gas contains an analyte gas comprising at least one component that is retained in the device and a carrier gas that is not retained;
reducing the flow rate of the carrier ga

Assignees

• Thermo Fisher Scient Bremen Gmbh

Inventors

• Krummen Michael
• Schwieters Johannes
• Schlueter Hans-Juergen
• Kracht Oliver

Classifications

• G01N2030/065

  using different phases to separate parts of sample · CPC title

• G01N30/10 Primary

  using a splitter · CPC title

• G01N2030/8886

  Analysis of industrial production processes · CPC title

• G01N2030/8868

  elemental analysis, e.g. isotope dilution analysis · CPC title

• G01N1/40 Primary

  Concentrating samples · CPC title