Thermoplastic resin, method of preparing the same and thermoplastic resin composition including the same

Patent metadata

Field	Value
Publication number	US-10066041-B2
Application number	US-201615510654-A
Country	US
Kind code	B2
Filing date	Jun 14, 2016
Priority date	Jun 15, 2015
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

The present invention relates to a thermoplastic resin, a method of preparing the same, and a thermoplastic resin composition including the same. A thermoplastic resin having superior latex stability and thermal stability and generating a small amount of gas during processing, and a method of preparing the thermoplastic resin are provided. In addition, a thermoplastic resin composition having superior mechanical properties, surface gloss, whiteness, gloss after retention, and heat discoloration after retention and a small content of residual total volatile organic compounds (TVOC), due to inclusion of the thermoplastic resin, is provided.

First claim

The invention claimed is:

1. A thermoplastic resin, wherein the thermoplastic resin is prepared by polymerizing a monomer mixture comprising a rubber polymer latex, an aromatic vinyl compound, and a vinyl cyan compound; and a C 5 to C 20 conjugated unsaturated fatty acid salt.

2. The thermoplastic resin according to claim 1 , wherein the rubber polymer latex is a large-diameter rubber polymer latex having a particle diameter of 2,500 to 5,000 Å.

3. The thermoplastic resin according to claim 1 , wherein a gel content in the rubber polymer latex is 80 to 99% by weight.

4. The thermoplastic resin according to claim 1 , wherein the rubber polymer latex is comprised in an amount of 50 to 80% by weight with respect to the monomer mixture based on solid content.

5. The thermoplastic resin according to claim 1 , wherein the aromatic vinyl compound is one or more selected from the group consisting of styrene, α-methyl styrene, p-methyl styrene, vinyl toluene, t-butyl styrene, and chlorostyrene and substituents thereof.

6. The thermoplastic resin according to claim 1 , wherein the aromatic vinyl compound is comprised in an amount of 15 to 30% by weight with respect to the monomer mixture.

7. The thermoplastic resin according to claim 1 , wherein the vinyl cyan compound is one or more selected from the group consisting of acrylonitrile and methacrylonitrile and substituents thereof.

8. The thermoplastic resin according to claim 1 , wherein the vinyl cyan compound is comprised in an amount of 1 to 20% by weight with respect to the monomer mixture.

9. The thermoplastic resin according to claim 1 , wherein the conjugated unsaturated fatty acid salt has a carbon number of 5 to 10.

10. The thermoplastic resin according to claim 1 , wherein the conjugated unsaturated fatty acid salt has an unsaturation degree of 3 or more.

11. The thermoplastic resin according to claim 1 , wherein the conjugated unsaturated fatty acid salt is comprised in an amount of 0.001 to 1.0 part by weight based on 100 parts by weight of the monomer mixture.

12. The thermoplastic resin according to claim 1 , wherein a residual emulsifier content in the thermoplastic resin is less than 23,000 ppm.

13. A method of preparing a thermoplastic resin, the method comprising a step of graft-polymerizing a monomer mixture comprising a rubber polymer latex, an aromatic vinyl compound, and a vinyl cyan compound; and a C 5 to C 20 conjugated unsaturated fatty acid salt.

14. The method according to claim 13 , wherein 1 to 50% by weight of the monomer mixture is added batchwise before reaction initiation, and a remainder of the monomer mixture is continuously added over 1 to 4 hours after reaction initiation.

15. The method according to claim 13 , wherein the conjugated unsaturated fatty acid salt is added batchwise before reaction initiation or is continuously added over 1 to 4 hours after reaction initiation.

16. The method according to claim 13 , wherein, in the step of graft-polymerizing, an emulsifier is further comprised.

17. A thermoplastic resin composition, comprising the thermoplastic resin according to claim 1 ; and an aromatic vinyl compound-vinyl cyan compound copolymer.

18. The thermoplastic resin composition according to claim 17 , wherein the thermoplastic resin is comprised in an amount of 10 to 50% by weight, and the aromatic vinyl compound-vinyl cyan compound copolymer is comprised in an amount of 50 to 90% by weight.

19. The thermoplastic resin composition according to claim 17 , wherein residual total volatile organic compounds (TVOC) content in the thermoplastic resin composition is 1,150 ppm or less.

Assignees

• Lg Chemical Ltd

Inventors

• Ahn Bong Keun
• Shim Hyung Seop
• Yoo Keun Hoon

Classifications

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08L25/12

  with unsaturated nitriles · CPC title

• C08F279/04

  Vinyl aromatic monomers and nitriles as the only monomers · CPC title

• C08F279/02 Primary

  on to polymers of conjugated dienes · CPC title

• C08J2300/22

  Thermoplastic resins · CPC title