Method for producing ethanol and coproducing methanol

Patent metadata

Field	Value
Publication number	US-10059649-B2
Application number	US-201315103076-A
Country	US
Kind code	B2
Filing date	Dec 16, 2013
Priority date	Dec 16, 2013
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

A method for producing ethanol and coproducing methanol on a catalyst in a reactor using a co-feed of a synthesis gas and acetate as a reaction raw material comprising passing a raw material gas containing an acetate and a synthesis gas through a reactor loaded with a catalyst to produce ethanol and coproduce methanol under conditions of a reaction temperature of 150-350° C., a reaction pressure of 0.1-20.0 MPa, a reaction volume hourly space velocity of 100-45000 mlg−1h−1, and an acetate weight hourly space velocity of 0.01-5.0 h−1; and the active components of the catalyst are copper and optionally zinc and/or aluminum, which greatly facilitates the conversion of carbon monoxide to methanol, while an extremely high activity of acetate hydrogenation is maintained.

First claim

What is claimed is:

1. A method for producing ethanol and coproducing methanol, comprising passing a raw material gas containing an acetate and a synthesis gas through a reactor loaded with a catalyst to produce ethanol and coproduce methanol under conditions of a reaction temperature of 150-350° C., a reaction pressure of 0.1-20.0 MPa, a reaction volume hourly space velocity of 100-45000 mlg −1 h −1 , and an acetate weight hourly space velocity of 0.01-5.0 h −1 ; and the catalyst comprises, based on weight, about 80%-85% CuO, about 10%-15% ZnO, and about 5%-10% Al 2 O 3 .

2. The method according to claim 1 , wherein the acetate is methyl acetate and/or ethyl acetate.

3. The method according to claim 1 , wherein the catalyst further contains one or more of manganese, molybdenum, zirconium, chromium, iron, barium, magnesium, nickel, and calcium as a promoter.

4. The method according to claim 3 , wherein the catalyst comprises no more than 5% metal oxide of the promoter.

5. The method according to claim 1 , wherein the catalyst is subjected to reduction treatment with hydrogen gas and/or a synthesis gas before use.

6. The method according to claim 1 , wherein the molar ratio of synthesis gas/acetate in the raw material gas is 10-101/0.1-4, and the molar ratio of hydrogen gas/carbon monoxide in the synthesis gas is 9-100/1.

7. The method according to claim 1 , wherein the molar ratio of synthesis gas/acetate in the raw material gas is 21-101/2-4, and the molar ratio of hydrogen gas/carbon monoxide in the synthesis gas is 20-100/1.

8. The method according to claim 1 , wherein the reaction temperature is 180-300° C., the reaction pressure is 1.0-10.0 MPa, the reaction volume hourly space velocity is 400-35000 mlg −1 h −1 , and the acetate weight hourly space velocity is 0.1-3.0 h −1 .

Assignees

• Dalian Inst Chem & Physics Cas

Inventors

• Liu Yong
• Zhu Wenliang
• Liu Hongchao
• Ni Youming
• Liu Zhongmin
• Meng Shuanghe
• Li Lina
• Liu Shiping
• Zhou Hui

Classifications

• C07C29/154 Primary

  containing copper, silver, gold, or compounds thereof · CPC title

• C07C31/04

  Methanol · CPC title

• B01J23/868

  copper and chromium · CPC title

• C07C2523/755

  Nickel · CPC title

• C07C2523/34

  Manganese · CPC title