Process and reactor for exothermal reaction

Patent metadata

Field	Value
Publication number	US-9718685-B2
Application number	US-201415030985-A
Country	US
Kind code	B2
Filing date	Oct 24, 2014
Priority date	Oct 28, 2013
Publication date	Aug 1, 2017
Grant date	Aug 1, 2017

Abstract

The present disclosure relates to a reactor and a method of operation for an exothermal process being catalyzed by a catalytically active material receiving a reactant gas and providing a product gas, in which said exothermal process has a heat development having a potential for thermally degrading said catalytically active material, and which exothermal process operates at a temperature at which the reactants and at least 80% or all of the products are present as gases, said method comprising the steps of a) directing the reactant gas to a first zone of a material catalytically active in the exothermal process producing an first product gas, and b) directing the first product gas to a second zone of a material catalytically active in the exothermal process producing a product gas, with the option of fully or partially by-passing either said first zone or said second zone, while directing a non-condensing gas stream having a temperature at least 50° C. lower than the product gas to said by-passed zone, wherein the choice of by-passing said zone is made based on the time of operation or a process parameter reflecting the catalytic activity of the zone of catalytically active material which is not by-passed with the associated benefit of reducing the extent of thermal deactivation of the catalytically active material, and thus increasing the overall lifetime of the catalytically active material.

First claim

The invention claimed is:

1. A method of operation for an exothermal process being catalyzed by a catalytically active material comprising a dispersed active metal compound, said process converting a reactant synthesis gas to a product gas, in which the peak temperature of said catalytically active material is at least 40% of the absolute melting temperature of said active metal compound, said method comprising the steps of
a) directing the reactant gas to a first zone of a material catalytically active in the exothermal process producing a first product gas,
b) directing the first product gas to a second zone of a material catalytically active in the exothermal process producing a second product gas, and
c) operating said exothermic process to fully or partially by-pass said first zone or said second zone, while directing a non-condensing gas stream having a temperature at least 50° C. lower than the product gas to said by-passed zone, said full or partial by-pass based on the time of operation or a process parameter reflecting the catalytic activity of the zone of catalytically active material which is not by-passed; wherein a condensable compound is present as reactant or product in a concentration resulting in a dew point above 50° C.

2. The method according to claim 1 , further comprising one or more additional steps of directing gas to zones of catalytically active material or by-passing said one or more zones, and by-passing said one or more additional zones based on time of operation or process parameters reflecting the catalytic activity of the one or more of the other zones of material catalytically active in the exothermal process.

3. The method according to claim 1 , wherein the parameter reflecting the catalytic activity is outlet gas temperature, temperature of catalytically active material, the concentration of one or more of a reactant or a product selected from the group consisting of CO, CO 2 , H 2 O, CH 3 OH and CH 4 .

4. The method according to claim 1 , wherein the exothermal process comprises one of methanation, water gas shift reaction or methanol synthesis.

5. The method according to claim 1 , wherein the catalytically active material is one of zinc, cobalt, molybdenum, nickel, copper or iron, in reduced, oxide or sulfide form.

6. The method according to claim 1 , wherein the exothermal process is methanation and wherein the inlet temperature of the synthesis gas is in the range of 300° C. to 400° C.

7. The method according to claim 6 , wherein the exothermal process is methanation and wherein the inlet temperature of the synthesis gas is in the range of 330° C. to 360° C.

8. The method according to claim 1 wherein the exothermal process is water gas shift reaction and wherein the inlet temperature of the synthesis gas is in the of range 180° C. to 250° C.

9. The method according to claim 8 , wherein the exothermal process is water gas shift reaction and wherein the inlet temperature of the synthesis gas is in the range of 190° C. to 210° C.

10. The method according to claim 1 , wherein the exothermal process is water gas shift reaction and wherein the inlet temperature of the synthesis gas is in the range of 300° C. to 400° C.

11. The method according to claim 10 , wherein the exothermal process is water gas shift reaction and wherein the inlet temperature of the synthesis gas is in the range of 330° C. to 360° C.

12. The method according to claim 1 , wherein the exothermal process is methanol synthesis and wherein the inlet temperature of the synthesis gas is in the range of 180° C.

13. The method according to claim 1 , wherein the exothermal process is methanol synthesis and wherein the inlet temperature of the synthesis gas is in the range of 180° C. to 250° C.

14. The method according to claim 1 , wherein a specific zone of catalytically active material is by-passed if the temperature approach at the exit of the active zone is less than 50° C.

15. The method according to claim 14 , wherein a specific zone of catalytically active material is by-passed if the temperature approach at the exit of the active zone is less than 20° C.

16. The method according to claim 1 , in which an amount of purge gas having a flow rate less than 50% of the flow rate of reactant gas, is directed to the by-passed zones of material catalytically active in the exothermal process.

17. The method according to claim 16 in which the purge gas comprises product gas and/or product gas having reacted further by at least 20%.

18. The method according to claim 17 in which the at least an amount of the purge gas acts as a suction gas in an ejector with one of pressurized steam or at least a fraction of the reactant gas.

19. The method according to claim 1 in which a condensable compound, is present as reactant or product in a concentration resulting in a dew point above 150° C.

Assignees

• Haldor Topsoe As
• Haldor Topsoe As

Inventors

• Stummann Troels Dahlgaard
• Andersen Niels Ulrik
• Janardhanan Madhanakrishnan
• Rostrup-Nielsen Jens R

Classifications

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C07C2523/28

  Molybdenum · CPC title

• B01J2219/1943

  cylindrical · CPC title

• C01B2203/061

  Methanol production · CPC title

• B01J8/0492 Primary

  Feeding reactive fluids (for solid material, see B01J8/0015) · CPC title