Process and apparatus for the production of para-xylene

Patent metadata

Field	Value
Publication number	US-10059643-B2
Application number	US-201615345990-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Mar 19, 2015
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

A process for producing para-xylene (PX) comprises supplying a hydrocarbon feed comprising xylenes and ethylbenzene (EB) to a PX recovery unit, where a PX-rich stream and at least one PX-depleted stream are recovered from the feed. The PX-depleted stream is then separated into an EB-rich stream and an EB-depleted stream in a divided wall column. The EB-depleted stream is then isomerized under at least partial liquid phase conditions to produce a first isomerized stream having a higher PX concentration than the PX-depleted stream, and the EB-rich stream is isomerized under at least partial vapor phase conditions to produce a second isomerized stream having a higher PX concentration than the PX-depleted stream. The first and second isomerized streams are then recycled to the PX recovery unit to recover additional PX and the process is repeated to define a so-called xylene isomerization loop.

First claim

The invention claimed is:

1. An apparatus for the production of para-xylene comprising:
a para-xylene recovery unit, which produces a para-xylene-rich stream and at least one para-xylene-depleted stream from a hydrocarbon feed, fluidly connected to a divided wall column in which the at least one para-xylene-depleted stream is separated into an ethylbenzene-rich stream, which contains a majority portion of the ethylbenzene from the at least one para-xylene-depleted stream, and an ethylbenzene-depleted stream, which contains a minor portion of the ethylbenzene from the at least one para-xylene-depleted stream;
a liquid phase isomerization unit fluidly connected to the divided wall column to isomerize the ethylbenzene-depleted stream back towards an equilibrium concentration of the xylenes isomers and produce a first isomerized stream having a higher para-xylene concentration than the para-xylene-depleted stream;
a vapor phase isomerization unit fluidly connected to the divided wall column to isomerize the ethylbenzene-rich stream back towards an equilibrium concentration of the xylenes isomers and produce a second isomerized stream having a higher para-xylene concentration than the para-xylene-depleted stream; and
a xylenes fractionation column fluidly connected to the liquid phase isomerization unit, the vapor phase isomerization unit and the para-xylene recovery unit, wherein the xylenes fractionation column is downstream of the liquid phase isomerization unit and the vapor phase isomerization unit and upstream of the para-xylene recovery unit.

2. The apparatus of claim 1 , further comprising a detoluenizing fractionation column fluidly connected to the vapor phase isomerization unit and the xylenes fractionation column, wherein the detoluenizing fractionation column is downstream of the vapor phase isomerization unit and upstream of the xylenes fractionation column.

3. The apparatus of claim 1 , wherein the first isomerized stream is sent to a higher location in the xylenes fractionation column than the second isomerized stream.

4. The apparatus of claim 1 , wherein the para-xylene recovery unit produces two para-xylene-depleted streams.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Bender Timothy P
• Porter John R
• Pilliod Dana L

Classifications

• C07C5/2737 Primary

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• B01D15/185

  characterised by the components to be separated · CPC title

• C07C5/2775

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• B01J19/2445

  placed in parallel · CPC title