Manufacturing process

Patent metadata

Field	Value
Publication number	US-9260360-B2
Application number	US-201314078673-A
Country	US
Kind code	B2
Filing date	Nov 13, 2013
Priority date	Dec 5, 2012
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

The invention relates to minimizing ammonia poisoning of a catalyst and to a xylene isomerization process using said catalyst.

First claim

What is claimed is:

1. A process in a reactor system comprising a reactor having a rhenium-based MFI zeolite catalyst therein, said process comprising:
(i) a step comprising introducing nitrogen gas into said reactor system to at least partially displace any oxygen and/or moisture in said reactor system under conditions including a temperature T 1 and a pressure P 1 , and then contacting said rhenium-based MFI zeolite catalyst with said nitrogen gas for a predetermined period of time and/or until oxygen and/or moisture in said reactor system fall to a predetermined level;
(ii) a step comprising introducing hydrogen gas into said reactor system to at least partially displace said nitrogen in said reactor system under conditions including a temperature T 2 and a pressure P 2 , and then contacting said rhenium-based MFI zeolite catalyst with said hydrogen gas for a period of time which may be predetermined and/or measured by one or more of reactor system characteristics selected from ammonia levels, oxygen levels, moisture levels, and nitrogen gas levels measured in said reactor system;
wherein said conditions include T 2 <180° C.<T 1 and P 2 <0.5 MPa<P 1 ; and
(iii) a step comprising contacting said rhenium-based MFI zeolite catalyst with a paraxylene-depleted feedstream comprising orthoxylene and metaxylene, whereby at least a portion of said orthoxylene and metaxylene are isomerized to paraxylene.

2. The process of claim 1 , further comprising, after step (ii) and before step (iii), at least one step (a), comprising increasing said reactor system pressure by increasing the pressure of hydrogen gas in said reactor system, followed by venting of said reactor system to decrease said reactor system pressure.

3. The process of claim 1 , wherein hydrogen is introduced into said reactor to displace nitrogen at a temperature less than T 1 and a pressure less than P 1 for a period of time until at least one of the following conditions is measured in said reactor system: (i) ammonia levels are at or below a predetermined level; and (ii) nitrogen levels are at or below 1.0 vol %, based on the volume of total gases.

4. The process of claim 1 , wherein T 2 ≦160° C.

5. The process of claim 1 , wherein at least one of the following conditions is measured during the contacting of step (ii) before beginning step (iii): (aa) the moisture level as measured in the recycle gas line is less than 500 vppm; (bb) nitrogen level as measured in the recycle gas line has decreased to below 1.0 vol %; (cc) ammonia level as measured in the recycle gas line is at or below 5 vppm.

6. The process of claim 5 , wherein at least two of said conditions are measured during said contacting of step (ii) before beginning step (iii).

7. The process of claim 5 , wherein all of said conditions are measured during said contacting of step (ii) before beginning step (iii).

Assignees

• Exxonmobil Chem Patents Inc

Inventors

• Cao Chunshe
• Andrews Jeffrey L
• Molinier Michel

Classifications

• C07C5/2737 Primary

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C07C2529/78

  containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium · CPC title

• C07C15/08

  Xylenes · CPC title