Method and apparatus for producing crystalline cladding and crystalline core optical fibers

Patent metadata

Field	Value
Publication number	US-10054735-B2
Application number	US-201715791762-A
Country	US
Kind code	B2
Filing date	Oct 24, 2017
Priority date	Jul 28, 2015
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

We provide methods and apparatus for preparing crystalline-clad and crystalline core optical fibers with minimal or no breakage by minimizing the influence of thermal stress during a liquid phase epitaxy (LPE) process as well as the fiber with precisely controlled number of modes propagated in the crystalline cladding and crystalline core fiber via precisely controlling the diameter of crystalline fiber core with under-saturated LPE flux. The resulting crystalline cladding and crystalline core optical fibers are also reported.

First claim

We claim:

1. A method for preparing a crystalline clad and crystalline core optical fiber, comprising:
securing a crystalline fiber core having a refractive index and a first end and a second end in a holder with no or minimized thermally induced stress, wherein the first end of the crystalline fiber core is secured in the holder and wherein the second end is free to move in at least an axial direction of the fiber within the holder;
immersing the crystalline fiber core into at least one molten liquid phase epitaxy (LPE) solution comprising at least one flux and at least one cladding until a crystalline cladding layer has formed thereon, said crystalline cladding layer having a lower refractive index than the crystalline fiber core refractive index;
further comprising adding the molten LPE solution through a 1-dimensional or 2-dimensional mesh type bottom support, wherein the molten flux passes through the mesh type bottom support and there is a relative movement between the fiber core preform and mesh bottom support along at least the axial direction of the fiber during an LPE growing process, resulting in a uniform cladding growth, wherein the crystalline fiber core and mesh type bottom support is separated while the molten flux is still at a molten liquid state by creating a relative translation along an axial direction of the crystalline fiber core, after the crystalline fiber core and mesh bottom support are pulled out of the crucible.

2. The method of claim 1 , wherein both the mesh bottom support and the fiber can move within the flux in addition to the relative movement between two.

3. The method of claim 1 , wherein the flux is selected from the group consisting of Li 2 MoO 4 —MoO 3 , Y 2 O 3 , Al 2 O 3 , Yb 2 O 3 , PbO—B 2 O 3 , BaO—B 2 O 3 —BaF 2 , PbO—PbF 2 —B 2 O 3 , PbO—V 2 O 5 , PbO—PbF 2 , KF—MoO3, KF—BaTiO 3 , K 2 CO 3 , PbF 2 —B 2 O 3 , and MoO 3 —K 2 MoO 4 —Y 2 O 3 .

4. The method of claim 1 , wherein the cladding material is selected from the group consisting of pure and/or doped garnet (Y 1−x−y−z , Gd x , Lu y , Tb z ) 3 (Al 1−w , Ga w ) 5 O 12 , where x, y, z, and w are within the range of 0 to 1, pure and/or doped yttrium lithium fluoride (YLF), pure and/or doped yttrium orthovanadate (YVO 4 ), pure and/or doped gadolinium orthovanadate (GdVO 4 ), pure and/or doped colquiriite (LiSaF), pure and/or doped alumina (Al 2 O 3 ), pure and/or doped spinel (MgAl 2 O 4 ), pure and/or doped aluminum oxynitride (AlON), pure and/or doped yttria (Y 2 O 3 ), pure and/or doped zirconia (ZrO 2 ), pure and/or doped aluminum nitride (AlN), pure and/or doped yttrium iron garnet (YIG), pure and/or doped potassium tantalate niobate (KTN), pure and/or doped lithium niobate (LiNbO 3 ), pure and/or doped tantalate niobate (LiTaO 3 ), pure and/or doped lanthanum lead zirconate-titanate (PLZT), pure and/or doped lead magnesium niobate-lead titanate (PMN-PT), gallium arsenide (GaAs), gallium aluminum arsenide (GaAlAs), gallium nitride (GaN) and combinations thereof.

5. The method of claim 1 , wherein the crystalline fiber core is selected from the group consisting of doped garnet (Y 1−x−y−z , Gd x , Lu y , Tb z ) 3 (Al 1−w , Ga w ) 5 O 12 , where x, y, z, and w are within the range of 0 to 1, pure and/or doped yttrium lithium fluoride (YLF), pure and/or doped yttrium orthovanadate (YVO 4 ), pure and/or doped gadolinium orthovanadate (GdVO 4 ), pure and/or doped colquiriite (LiSaF), pure and/or doped alumina (Al 2 O 3 ), pure and/or doped spinel (MgAl 2 O 4 ), pure and/or doped aluminum oxynitride (AlON), pure and/or doped yttria (Y 2 O 3 ), pure and/or doped zirconia (ZrO 2 ), pure and/or doped aluminum nitride (AlN), pure and/or doped yttrium iron garnet (YIG), pure and/or doped potassium tantalate niobate (KTN), pure and/or doped lithium niobate (LiNbO 3 ), pure and/or doped tantalate niobate (LiTaO 3 ), pure and/or doped lanthanum lead zirconate-titanate (PLZT), pure and/or doped lead magnesium niobate-lead titanate (PMN-PT), gallium arsenide (GaAs), gallium aluminum arsenide (GaAlAs), gallium nitride (GaN) and combinations thereof.

Assignees

• Penn State Res Found
• General Opto Solutions Llc

Inventors

• Yin Shizhuo
• Luo Fang

Classifications

• C01F7/78

  Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements (aluminates C01F7/02; compounds containing aluminium, fluorine and alkali or alkaline earth metals C01F7/54; nitrates containing other cations besides aluminium C01F7/66; sulfides, sulfites or sulfates containing other cations besides aluminium C01F7/70 - C01F7/74) · CPC title

• C30B19/12

  characterised by the substrate · CPC title

• C30B29/28

  with formula A3Me5O12 wherein A is a rare earth metal and Me is Fe, Ga, Sc, Cr, Co or Al, e.g. garnets · CPC title

• G02B6/021

  characterised by the core or cladding or coating, e.g. materials, radial refractive index profiles, cladding shape · CPC title

• H01S3/09415

  the pumping beam being parallel to the lasing mode of the pumped medium, e.g. end-pumping · CPC title