Production of high strength titanium

Patent metadata

Field	Value
Publication number	US-10053758-B2
Application number	US-69195210-A
Country	US
Kind code	B2
Filing date	Jan 22, 2010
Priority date	Jan 22, 2010
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

Certain embodiments of a method for increasing the strength and toughness of a titanium alloy include plastically deforming a titanium alloy at a temperature in an alpha-beta phase field of the titanium alloy to an equivalent plastic deformation of at least a 25% reduction in area. After plastically deforming the titanium alloy in the alpha-beta phase field, the titanium alloy is not heated to or above the beta transus temperature of the titanium alloy. After plastic deformation, the titanium alloy is heat treated at a heat treatment temperature less than or equal to the beta transus temperature minus 20° F. (11.1° C.).

First claim

I claim:

1. A method for increasing the strength and fracture toughness of a titanium alloy, the method consisting of:
plastically deforming a titanium alloy to an equivalent plastic deformation of at least a 25% reduction in area at a temperature starting at or above a beta transus temperature of the titanium alloy to a final plastic deformation temperature in an alpha-beta phase field of the titanium alloy and not less than 222° C. below the beta transus temperature of the titanium alloy, wherein at least a 25% reduction in area of the titanium alloy occurs in the alpha-beta phase field of the titanium alloy, and wherein after plastically deforming the titanium alloy the titanium alloy is not heated to a temperature at or above a beta transus temperature of the titanium alloy;
optionally, cooling the titanium alloy; and
heat treating the titanium alloy, wherein heat treating the titanium alloy consists of a one-step heat treatment at a heat treatment temperature less than or equal to the beta transus temperature minus 20° F. for a heat treatment time sufficient to produce a heat treated alloy, wherein a fracture toughness (K Ic ) of the heat treated alloy is related to a yield strength (YS) of the heat treated alloy according to the equation:
K Ic ≥173−(0.9)YS.

2. The method of claim 1 , wherein the fracture toughness (K Ic ) of the heat treated alloy is related to the yield strength (YS) of the heat treated alloy according to the equation:
217.6−(0.9)YS≥ K Ic ≥173−(0.9)YS.

3. The method of claim 1 wherein the fracture toughness (K Ic ) of the heat treated alloy is related to the yield strength (YS) of the heat treated alloy according to the equation:
K Ic ≥217.6−(0.9)YS.

4. The method of claim 1 , wherein plastically deforming the titanium alloy comprises plastically deforming the titanium alloy to an equivalent plastic deformation in the range of greater than a 25% reduction in area to a 99% reduction in area.

5. The method of claim 1 , wherein heat treating the titanium alloy comprises heating the titanium alloy at a heat treatment temperature in the range of 900° F. (482° C.) to 1500° F. (816° C.) for a heat treatment time in the range of 0.5 hours to 24 hours.

6. The method of claim 1 , wherein plastically deforming the titanium alloy comprises at least one of forging, rotary forging, drop forging, multi-axis forging, bar rolling, plate rolling, and extruding the titanium alloy.

7. The method of claim 1 , wherein the equivalent plastic deformation comprises an actual reduction in area of a cross-section of the titanium alloy.

8. The method of claim 1 , wherein plastically deforming the titanium alloy results in an actual reduction in area of a cross-section of the titanium alloy of 5% or less.

9. The method of claim 4 , wherein the equivalent plastic deformation comprises an actual reduction in area of a cross-section of the titanium alloy.

10. The method of claim 1 , wherein the titanium alloy is a titanium alloy that is capable of retaining beta-phase at room temperature.

11. The method of claim 10 , wherein the titanium alloy is selected from a beta titanium alloy, a metastable beta titanium alloy, an alpha-beta titanium alloy, and a near-alpha titanium alloy.

12. The method of claim 10 , wherein the titanium alloy is Ti-5Al-5V-5Mo-3Cr alloy.

13. The method of claim 10 , wherein the titanium alloy is Ti-15Mo.

14. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy exhibits an ultimate tensile strength in the range of 138 ksi to 179 ksi.

15. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy exhibits a K Ic fracture toughness in the range of 59 ksi·in 1/2 to 100 ksi·in 1/2 .

16. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy exhibits a yield strength in the range of 134 ksi to 170 ksi.

17. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy exhibits a percent elongation in the range of 4.4% to 20.5%.

18. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy exhibits an average ultimate tensile strength of at least 166 ksi, an average yield strength of at least 148 ksi, a percent elongation of at least 6%, and a K Ic fracture toughness of at least 65 ksi·in 1/2 .

19. The method of claim 1 , wherein after heat treating the titanium alloy, the titanium alloy has an ultimate tensile strength of at least 150 ksi and a K Ic fracture toughness of at least 70 ksi·in 1/2 .

20. A method for thermomechanically treating a titanium alloy to increase strength and fracture toughness, the method consisting of:
working a titanium alloy at a working temperature starting from at or up to 200° F. (111° C.) above a beta transus temperature of the titanium alloy to a final temperature not less than 222° C. below the beta transus temperature of the titanium alloy and in an alpha-beta phase field of the titanium alloy, wherein at least a 25% reduction in area of the titanium alloy occurs in the alpha-beta phase field of the titanium alloy, wherein the titanium alloy is not heated above the beta-transus temperature after the at least 25% reduction in area of the titanium alloy in the alpha-beta phase field of the titanium alloy;
optionally, cooling the titanium alloy; and
heat treating the titanium alloy, wherein heat treating the titanium alloy consists of a one-step heat treatment in a heat treatment temperature range between 900° F. (482° C.) and 1500° F. (816° C.) for a heat treatment time sufficient to produce a heat treated alloy having a fracture toughness (K Ic ) that is related to the yield strength (YS) of the heat treated alloy according to the equation:
K Ic ≥173−(0.9)YS.

21. The method of claim 20 , wherein the heat treatment time is in the range of 0.5 to 24 hours.

22. The method of claim 20 , wherein working the titanium alloy provides an equivalent plastic deformation in the range of greater than a 25% reduction in area to a 99% reduction in area.

23. The method of claim 20 , wherein working the titanium alloy comprises working the titanium alloy substantially entirely in the alpha-beta phase field.

24. The method of claim 20 , wherein working the titanium alloy comprises working the titanium alloy from a temperature at or above the beta transus temperature, into the alpha-beta field, and to a final working temperature in the alpha-beta field.

25. The method of claim 20 , wherein the titanium alloy is a titanium alloy that is capable of retaining beta-phase at room temperature.

26. The method of claim 20 , wherein after heat treating the titanium alloy, the titanium alloy has an average ultimate tensile strength of at least 166 ksi, an average yield strength of at least 148 ksi, a K Ic fracture toughness of at least 65 ksi·in 1/2 , and a percent elongation of at least 6%.

27. The method of claim 20 , wherein the fracture toughness (K Ic ) of the heat treated alloy is related to the yield strength (YS) of the heat treated alloy according to the equation:
217.6−(0.9)YS≥ K Ic ≥173−(0.9)YS.

28. The method of claim 20 , wherein the fracture toughness (K Ic ) of the heat treated alloy is related to the yield strength (YS) of the heat treated alloy according to the equation:
K Ic ≥217.6−(0.9)YS.

Assignees

• Bryan David J
• Ati Properties Llc

Inventors

• Bryan David J

Classifications

• C22C14/00 Primary

  Alloys based on titanium · CPC title

• C22F1/183 Primary

  of titanium or alloys based thereon · CPC title