Zeolite catalyst composition

Patent metadata

Field	Value
Publication number	US-2016237356-A1
Application number	US-201415029185-A
Country	US
Kind code	A1
Filing date	Oct 24, 2014
Priority date	Oct 25, 2013
Publication date	Aug 18, 2016
Grant date	—

Abstract

A low density zeolite composition includes a zeolite in the amount of less than 80 wt % of total composition and a crystalline non-zeolite metal oxide-containing binder. The composition has a pore volume of at least 0.4 mL/g and an average meso-pore diameter of 20-500 Å, and macroporosity with average pore diameter greater than 500 Å.

First claim

What is claimed is:

1 . A low density zeolite composition, comprising:
a zeolite in the amount of less than 80 wt % of total composition; and a crystalline non-zeolite metal oxide-containing binder, wherein the composition has a pore volume of at least 0.4 mL/g and an average mesopore diameter of 20-500 Å, and wherein the composition has macroporosity with average pore diameter greater than 500 Å.

2 . The zeolite composition of claim 1 , wherein the low density zeolite composition demonstrates the same fuel production efficiency as a catalyst composition using 80 wt % of the same zeolite in a composition lacking macroporosity.

3 . The zeolite composition of claim 1 , wherein the low density zeolite composition demonstrates a lower durene production during fuel production as compared to a catalyst using 80 wt % of the same zeolite in a composition lacking macroporosity.

4 . The composition of claim 1 , wherein the zeolite comprises ZSM-5.

5 . The composition of claim 1 , wherein the non-zeolite metal-oxide-containing binder is selected from the group consisting of silica, titania, zirconia, talc, magnesia, alumina, calcium oxide, kaolin, and combinations of these oxides.

6 . The composition of claim 5 , wherein the non-zeolite metal-oxide-containing binder comprises kaolin clay.

7 . The composition of claim 6 , wherein the non-zeolite metal-oxide-containing binder further comprises alumina.

8 . The composition of claim 1 , wherein the composition has a bulk density of 25-40 lb/ft 3 .

9 . The composition of claim 1 , wherein the zeolite in the amount of 50-70 wt % of total composition.

10 . A precursor to a low density zeolite composition, comprising:
a zeolite in the amount of less than 80 wt % of total composition; and a crystalline non-zeolite metal-oxide-containing binder; and a sacrificial organic compound having particle size and burn out properties selected to provide the desired mesopores and macropore size and pore distribution.

11 . The precursor of claim 10 , wherein the sacrificial organic compound is selected from the group consisting of cellulose, starch, polyethylene, PTFE, latex, polyethylene glycol (PEG), acicular carbons, carbon black, activated carbon, graphite, carboxylic acids such as oxalic acid, and lingo-sulfonic acid and combinations thereof.

12 . The precursor of claim 10 , wherein the sacrificial organic compound comprises cellulose.

13 . The precursor of claim 10 , wherein the sacrificial organic compound comprises acicular carbon.

14 . The precursor of claim 10 , wherein the non-zeolite metal-oxide-containing binder is selected from the group consisting of silica, titania, zirconia, talc, magnesia, alumina, calcium oxide, kaolin, and combinations of these oxides.

15 . The precursor of claim 14 , wherein the non-zeolite metal-oxide-containing binder comprises kaolin clay.

16 . The precursor of claim 15 , wherein the non-zeolite metal-oxide-containing binder further comprises alumina.

17 . The precursor of claim 16 , wherein the alumina comprises an alumina sol.

18 . A method of making a renewable fuel, comprising:
receiving a gaseous product comprising oxyen, hydrogen and carbon in a catalytic reactor comprising the low density zeolite catalyst of claim 1 ; and contacting the gaseous product with the low density zeolite catalyst to obtain a renewable fuel, said renewable fuel containing less than 10 wt % durene.

19 . The method of claim 18 , wherein the gaseous product is obtained from the pyrolysis of a biomass.

20 . The method of claim 18 , wherein the gaseous product comprises methanol, ethanol and dimethyl ether.

Assignees

• Cool Planet Energy Systems Inc

Inventors

• Malyala Rajashekharam
• Traxler Vern S
• Thompson Timothy Alan
• Jarand Mark L

Classifications

• B01J21/16

  Clays or other mineral silicates · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• Y02P30/20

  using bio-feedstock · CPC title

• C10G2/334

  containing molecular sieve catalysts · CPC title

• B01J38/12

  Treating with free oxygen-containing gas · CPC title