Method for recovering crude tall oil

Patent metadata

Field	Value
Publication number	US-10047320-B2
Application number	US-201515315906-A
Country	US
Kind code	B2
Filing date	Jun 2, 2015
Priority date	Jun 5, 2014
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

The present invention relates to a method for recovering crude tall oil from a soap which method comprises the steps of: determining a correlation between the crude tall oil content and the water content of the soap, determining an amount of acid and water needed in order to separate an optimal amount of crude tall oil from the soap dependent on the crude tall oil content of the soap, measuring the water content of the soap, adding the optimal amount of acid and water to the soap, mixing the added acid and water with the soap whereby an acidulated soap is formed and the crude tall oil is separated and recovering the separated crude tall oil from the acidulated soap.

First claim

The invention claimed is:

1. A method for recovering crude tall oil from a soap comprising the steps of:
(a) determining a correlation between the crude tall oil content and a water content of the soap by measuring the crude tall oil content of samples of the soap containing different water content,
(b) determining an amount of acid and water needed in order to separate an optimal amount of crude tall oil from the soap dependent on the crude tall oil content of the soap by adding different amounts of acid and water to samples of soaps having different crude tall oil content and identifying the amount of acid and water providing the highest amount of recovered crude tall oil for a given crude tall oil content,
(c) measuring a water content of the soap,
(d) determining the crude tall oil content of the soap from the water content measured in step (c) and the correlation determined in step (a),
(e) determining an optimal amount of acid and water for the crude oil content determined in step (d) based on the amount of acid and water identified in step (b) as providing the highest amount of recovered crude tall oil,
(f) adding the optimal amount of acid and water to the soap,
(g) mixing the added optimal amount of acid and water with the soap whereby acidulated soap is formed and crude tall oil is separated from a lignin phase and a spent acid phase, and
(h) recovering the separated crude tall oil from the acidulated soap.

2. The method according to claim 1 wherein the water content is measured on-line on a soap flow.

3. The method according to claim 1 , wherein a pH of the spent acid D fraction of the acidulated soap after addition of the acid and water in step (g) is less than 5.

4. The method according to claim 1 , wherein a temperature of the D acidulated soap in step (g) is between 80 to 102° C.

5. The method according to claim 1 , wherein step (g) is followed by D a retention time before entering the recovery step (h).

6. The method according to claim 1 , wherein the acid added in step (f) is a strong acid.

7. The method according to claim 6 , wherein the acid added in step (f) is sulfuric acid which is added in an amount of between 120 to 300 kg/t crude tall oil.

8. The method according claim 1 , wherein a hydrodynamic separator, centrifugal separator or decanter type processes are used for the recovery of the separated crude tall oil in step (h).

9. The method according to claim 1 , wherein the water content of said soap measured in step (b) is between 25 to 55 wt-%.

10. The method according to claim 1 , wherein step (a) also comprises the step of measuring a black liquor content of the soap and adjusting the black liquor content to 3 to 30 volume %.

11. The method according to claim 1 , wherein the water content of said soap measured in step (c) is between 32 to 44 wt-%.

Assignees

• Stora Enso Oyj

Inventors

• Finer Tiia
• Timonen Olli

Classifications

• C11B3/04

  with acids · CPC title

• C11B13/02 Primary

  from soap stock · CPC title

• C11B3/006

  by extraction · CPC title

• D21C11/0007

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title

• Y02W30/74

  Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes · CPC title