Rubber modifier, rubber modifier dispersion, and rubber composition

Patent metadata

Field	Value
Publication number	US-10040926-B2
Application number	US-201514694412-A
Country	US
Kind code	B2
Filing date	Apr 23, 2015
Priority date	Oct 23, 2012
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

The present invention provides a rubber modifier capable of exhibiting good dispersibility in a dispersion thereof and excellent in a rubber-modifying effect such as rubber-reinforcing effect or the likes. The invention relates to a rubber modifier comprising cellulose fibers, in which the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the number of all the cellulose fibers therein, is 50% or more, to a rubber modifier dispersion comprising the rubber modifier and a dispersion medium, and to a rubber composition comprising the rubber modifier and a rubber component.

First claim

The invention claimed is:

1. A rubber modifier comprising cellulose fibers,
wherein the number of cellulose fibers having a fiber length of 450 urn or less, relative to the total number of the cellulose fibers in the rubber modifier, is 58% or more,
wherein the cellulose fibers comprise cellulose fibers modified by introduction of an acyl group and a carboxyl group, and
wherein a number-average fiber diameter of the cellulose fibers is 20 nm or less.

2. A rubber modifier dispersion comprising a rubber modifier and a dispersion medium,
wherein the rubber modifier comprises cellulose fibers, wherein the number of cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 58% or more,
wherein a boiling point of the dispersion medium is from 70° C. to 300° C.,
wherein a content of the cellulose fibers in the rubber modifier dispersion is from 0.01 wt. % to 50 wt. %,
wherein the cellulose fibers comprise cellulose fibers modified by introduction of an acyl group and a carboxyl group, and
wherein a number-average fiber diameter of the cellulose fibers is 20 nm or less.

3. The rubber modifier dispersion according to claim 2 , further comprising a rubber component, wherein a content of the rubber component in the rubber modifier dispersion is from 2 wt. % to 95 wt. % relative to the total weight of the rubber modified dispersion.

4. A rubber composition comprising a rubber modifier and a rubber component,
wherein the rubber modifier comprises cellulose fibers, wherein the number of cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 58% or more,
wherein a content of the cellulose fibers in the rubber composition is from 0.5 wt. % to 30 wt. % relative to the total the rubber composition,
wherein an amount of the cellulose fibers is from 1 part by weight to 100 parts by weight relative to 100 parts by weight of the rubber component,
wherein the cellulose fibers comprise cellulose fibers modified by introduction of an acyl group and a carboxyl group, and
wherein a number-average fiber diameter of the cellulose fibers is 20 nm or less.

5. The rubber modifier dispersion of claim 2 , wherein the dispersion medium has a boiling point of from 70° C. to 200° C.

6. The rubber modifier comprising cellulose fibers of claim 1 , wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier is 60% or more.

7. The rubber modifier dispersion of claim 2 , wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier is 60% or more.

8. The rubber composition of claim 4 , wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier is 60% or more.

9. The rubber modifier comprising cellulose fibers of claim 1 , wherein the acyl group is an acyl group having from 2 to 12 carbon atoms.

10. The rubber modifier dispersion of claim 2 , wherein the acyl group is an acyl group having from 2 to 12 carbon atoms.

11. The rubber composition of claim 4 , wherein the acyl group is an acyl group having from 2 to 12 carbon atoms.

12. The rubber modifier comprising cellulose fibers of claim 1 , wherein a content of the carboxyl group is from 0.1 mmol/g to 3.0 mmol/g relative to the weight of the cellulose fibers.

13. The rubber modifier dispersion of claim 2 , wherein a content of the carboxyl group is from 0.1 mmol/g to 3.0 mmol/g relative to the weight of the cellulose fibers.

14. The rubber composition of claim 4 , wherein a content of the carboxyl group is from 0.1 mmol/g to 3.0 mmol/g relative to the weight of the cellulose fibers.

15. The rubber modifier comprising cellulose fibers of claim 1 , wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 60% or more, and wherein a content of the carboxyl group the acyl group is from 0.1 mmol/g to 8.0 mmol/g in total relative to the weight of the cellulose fibers.

16. The rubber modifier dispersion of claim 2 , wherein wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 60% or more, and wherein a content of the carboxyl group and the acyl group is from 0.1 mmol/g to 8.0 mmol/g in total relative to the weight of the cellulose fibers.

17. The rubber composition of claim 4 , wherein the number of the cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 60% or more, and wherein a content of the carboxyl group and the acyl group is from 0.1 mmol/g to 8.0 mmol/g in total relative to the weight of the cellulose fibers.

18. A rubber composition comprising a rubber modifier and a rubber component,
wherein the rubber modifier comprises cellulose fibers, wherein the number of cellulose fibers having a fiber length of 450 nm or less, relative to the total number of the cellulose fibers in the rubber modifier, is 58% or more,
wherein a content of the cellulose fibers in the rubber composition is from 0.5 wt. % to 4.4 wt. % relative to the total the rubber composition,
wherein an amount of the cellulose fibers is from 1 part by weight to 100 parts by weight relative to 100 parts by weight of the rubber component,
wherein the cellulose fibers comprise cellulose fibers modified by introduction of a phosphoric acid-derived group,
wherein a content of the phosphoric acid-derived group is from 0.1 mmol/g to 8.0 mmol/g in total relative to the weight of the cellulose fibers, and
wherein a number-average fiber diameter of the cellulose fibers is 20 nm or less.

Assignees

• Mitsubishi Chem Corp

Inventors

• Akai Hideko
• Noishiki Yasutomo

Classifications

• C08L1/12

  Cellulose acetate · CPC title

• C08L97/02

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title

• C08B15/04

  Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide · CPC title

• C08L7/02 Primary

  Latex · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title