Method for preparing double-sealed-end glycol ether

Patent metadata

Field	Value
Publication number	US-10040739-B2
Application number	US-201415537928-A
Country	US
Kind code	B2
Filing date	Dec 22, 2014
Priority date	Dec 22, 2014
Publication date	Aug 7, 2018
Grant date	Aug 7, 2018

Abstract

Disclosed is a method for preparing a double end capped glycol ether, the method comprising: introducing into a reactor a raw material comprising a glycol monoether and a monohydric alcohol ether, and enabling the raw material to contact and react with an acidic molecular sieve catalyst to generate a double end capped glycol ether, a reaction temperature being 50-300° C., a reaction pressure being 0.1-15 MPa, a WHSV of the glycol monoether in the raw material being 0.01-15.0 h−1 , and a mole ratio of the monohydric alcohol ether to the glycol monoether in the raw material being 1-100:1. The method of the present invention enables a long single-pass lifespan of the catalyst and repeated regeneration, has a high yield and selectivity of a target product, low energy consumption during separation of the product, a high economic value of a by-product, and is flexible in production scale and application.

First claim

The invention claimed is:

1. A method for preparing a double end-capped ethylene glycol ether, in which a raw material containing an ethylene glycol monoether and a monohydric alcohol ether is introduced into a reactor, contacting with a catalyst containing an acidic molecular sieve and reacting to produce the double end-capped ethylene glycol ether;
wherein, the reaction temperature is in a range from 50° C. to 300° C., and the reaction pressure is in a range from 0.1 Mpa to 15 Mpa;
the weight hourly space velocity of the ethylene glycol monoether in the raw material is in a range from 0.01 h −1 to 15.0 h −1 ; and
the molar ratio of the monohydric alcohol ether to the ethylene glycol monoether in the raw material is that monohydric alcohol ether:ethylene glycol monoether is in a range from 1:1 to 100:1.

2. The method according to claim 1 , wherein the ethylene glycol monoether is at least one selected from the group consisting of compounds with the structure represented by Formula I:
R 1 —O—CH 2 —CH 2 —OH  Formula I;

the monohydric alcohol ether is at least one selected from the group consisting of compounds with the structure represented by Formula II:
R 2 —O—R 2   Formula II;

the double end-capped ethylene glycol ether is at least one selected from the group consisting of compounds with the structure represented by Formula III:
R 1 —O—CH 2 —CH 2 —O—R 2   Formula III;

wherein, R 1 is selected from the group consisting of alkyl groups with carbon atoms from 1 to 20, and R 2 is selected from the group consisting of alkyl groups with carbon atoms from 1 to 20.

3. The method according to claim 2 , wherein R 1 is any one selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, and n-butyl; and R 2 is any one selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, and n-butyl.

4. The method according to claim 1 , wherein the acidic molecular sieve is one or more selected from the group consisting of molecular sieves with structural types of MWW, FER, MFI, MOR, FAU, and BEA.

5. The method according to claim 1 , wherein the acidic molecular sieve includes one or more selected from the group consisting of hydrogen-type MCM-22 molecular sieve, hydrogen-type ferrierite, hydrogen-type ZSM-5 molecular sieve, hydrogen-type mordenite, hydrogen-type Y zeolite, and hydrogen-type Beta molecular sieve.

6. The method according to any one of claims 1 , 4 and 5 , wherein the atomic ratio of silicon to aluminum in the acidic molecular sieve is that Si:Al is in a range from 4:1 to 140:1.

7. The method according to claim 1 , wherein the reaction temperature is in a range from 100° C. to 200° C., and the reaction pressure is in a range from 3.5 Mpa to 8 Mpa;
the weight hourly space velocity of the ethylene glycol monoether in the raw material is in a range from 0.5 h −1 to 5.0 h −1 ; and
the molar ratio of the monohydric alcohol ether to the ethylene glycol monoether in the raw material is that monohydric alcohol ether:ethylene glycol monoether is in a range from 1:1 to 5:1.

8. The method according to claim 1 , wherein the raw material contains a carrier gas;
wherein gaseous hourly space velocity of the carrier gas is in a range from 0 h −1 to 10,000 h −1 ; and the carrier gas is one or more selected from the group consisting of nitrogen gas, helium gas and argon gas.

9. The method according to claim 8 , wherein the gaseous hourly space velocity of the carrier gas is in a range from 100 h −1 to 2000 h −1 .

10. The method according to claim 1 , wherein the reactor contains one or more fixed bed reactors.

Assignees

• Dalian Inst Chem & Physics Cas

Inventors

• Ni Youming
• Zhu Wenliang
• Liu Hongchao
• Liu Yong
• Liu Zhongmin
• Li Lina
• Liu Shiping
• Zhou Hui

Classifications

• C07C43/10

  of polyhydroxy compounds · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title

• B01J29/7038

  MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25 · CPC title

• C07C41/14 Primary

  by exchange of organic parts on the ether-oxygen for other organic parts, e.g. by trans-etherification · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title