Method for producing synthetic quartz glass of SiO2 granulate and SiO2 granulate suited therefor

Patent metadata

Field	Value
Publication number	US-10029938-B2
Application number	US-201514864103-A
Country	US
Kind code	B2
Filing date	Sep 24, 2015
Priority date	Sep 29, 2014
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

A method for producing synthetic quartz glass by fusion of SiO2 granulate involves synthesizing amorphous SiO2 primary particles, granulating the amorphous SiO2 primary particles to form an open-pore SiO2 granulate, sintering the open-pore SiO2 granulate by heating in a sintering atmosphere at a sintering temperature and for a sintering period to form a densified SiO2 granulate, and melting the densified SiO2 granulate at a melting temperature to form the synthetic quartz glass. To provide an inexpensive production of low-bubble transparent components of quartz glass despite the use of still open-pore SiO2 granulate, the sintering atmosphere, sintering temperature and sintering duration are adjusted such that the densified SiO2 granulate still comprises open pores but manifests a material-specific infrared transmission T1700 at a wavelength of 1700 nm. This transmission is in the range of 50-95% of the infrared transmission T1700 of quartz glass granules of the same material.

First claim

We claim:

1. A method for producing synthetic quartz glass, comprising the following method steps:
(a) synthesizing amorphous SiO 2 primary particles,
(b) granulating the amorphous SiO 2 primary particles to form an open-pore SiO 2 granulate,
(c) sintering the open-pore SiO 2 granulate by heating in a sintering atmosphere at a sintering temperature and for a sintering period to form a densified SiO 2 granulate, and
(d) melting the densified SiO 2 granulate at a melting temperature to form the synthetic quartz glass;

wherein for the production of transparent quartz glass, the sintering atmosphere, the sintering temperature, and the sintering duration are adjusted during sintering in step (c) such that the densified SiO 2 granulate still comprises open pores and manifests a material-specific infrared transmission T 1700 at a wavelength of 1700 nm, wherein the transmission is in a range of 50-95% of the infrared transmission T 1700 of reference quartz glass granules formed by complete vitrification of same SiO 2 granulate.

2. The method according to claim 1 , wherein the infrared transmission T 1700 is in a range of 60-90% of the infrared transmission T 1700 of reference quartz glass granules formed by complete vitrification of same SiO 2 granulate.

3. The method according to claim 1 , wherein the sintering atmosphere, the sintering temperature, and the sintering duration are adjusted during sintering in step (c) such that the densified SiO 2 granulate manifests a material-specific infrared transmission T 500 at a wavelength of 500 nm, and wherein a ratio T 500 /T 1700 is 0.8 or less.

4. The method according to claim 1 , wherein the melting in step (d) comprises heating a bulk material of SiO 2 granulate or a compact comprising the SiO 2 granulate under negative pressure at the melting temperature.

5. The method according to claim 1 , wherein the densified SiO 2 granulate has a bulk density in a range of 0.9 kg/l to 1.3 kg/l.

6. The method according to claim 1 , wherein the densified SiO 2 granulate has a specific BET surface area in a range of 1 m 2 /g to 25 m 2 /g.

7. The method according to claim 1 , wherein the sintering atmosphere contains chlorine and the sintering temperature is at least 1000° C.

8. The method according to claim 1 , wherein the sintering in step (c) is performed in a rotary furnace.

9. The method according to claim 1 , wherein the granulating in step (b) is performed by spray granulation, and wherein granulate particles with a spherical morphology are obtained.

10. The method according to claim 1 , wherein the granulating in step (b) is performed by freeze granulation, and wherein granulate particles with a platelet-shaped morphology are obtained.

11. The method according to claim 1 , wherein during granulating in step (b), open-pore SiO 2 granulate is produced from granulate particles having a mean particle size of at least 150 μm, and wherein the open-pore SiO 2 granulate has a BET surface area in a range of 20 m 2 /g to 100 m 2 /g.

12. The method according to claim 1 , wherein the granulate particles of the densified granulate have a narrow particle size distribution, wherein the particle size assigned to a D 90 value is at the most three times as large as the particle size assigned to a D 10 value.

13. The method according to claim 1 , wherein during step (b), pyrogenically obtained SiO 2 primary particles are used, and wherein the SiO 2 primary particles are obtained by oxidation or flame hydrolysis of a chlorine-free silicon-containing feedstock.

14. An open-pore granulate consisting of synthetically produced amorphous SiO 2 primary particles, wherein at a wavelength of 1700 nm the granulate manifests a material-specific infrared transmission T 1700 in a range of 50-95% of the infrared transmission T 1700 of reference quartz glass granules formed by complete vitrification of same SiO 2 granulate.

15. The granulate according to claim 14 , wherein the infrared transmission T 1700 is in a range of 60-90% of the infrared transmission T 1700 of reference quartz glass granules formed by complete vitrification of same SiO 2 granulate, and wherein at a wavelength of 500 nm the SiO 2 granulate manifests a material-specific infrared transmission T 500 , and wherein a ratio T 500 /T 1700 is 0.8 or less.

Assignees

• Heraeus Quarzglas

Inventors

• Hofmann Achim
• Kayser Thomas
• Otter Matthias
• Kühn Bodo

Classifications

• C03B19/1095

  Thermal after-treatment of beads, e.g. tempering, crystallisation, annealing · CPC title

• C03B19/108

  Forming porous, sintered or foamed beads (chemical aspects C03C11/00) · CPC title

• C03C11/00

  Multi-cellular glass {; Porous or hollow glass or glass particles} · CPC title

• C03C12/00

  Powdered glass (C03C8/02 takes precedence); Bead compositions · CPC title

• C03C3/06 Primary

  with more than 90% silica by weight, e.g. quartz {(C03C3/045 takes precedence)} · CPC title