Production of base oils from petrolatum

Patent metadata

Field	Value
Publication number	US-10023822-B2
Application number	US-201615019225-A
Country	US
Kind code	B2
Filing date	Feb 9, 2016
Priority date	Mar 14, 2013
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Methods are provided for producing lubricant base oils from petrolatum. After solvent dewaxing of a brightstock raffinate to form a brightstock base oil, petrolatum is generated as a side product. The petrolatum can be hydroprocessed to form base oils in high yield. The base oils formed from hydroprocessing of petrolatum have an unexpected pour point relationship. For a typical lubricant oil feedstock, the pour point of the base oils generated from the feedstock increases with the viscosity of the base oil. By contrast, lubricant base oils formed from hydroprocessing of petrolatum have a relatively flat pour point relationship, and some of the higher viscosity base oils unexpectedly have lower pour points than lower viscosity base oils generated from the same petrolatum feed. The base oils from petrolatum are also unusual in yielding both high viscosity and high viscosity index and can be generated while maintaining a high yield.

First claim

What is claimed is:

1. A hydroprocessed effluent comprising a plurality of lubricant base stocks, the plurality of lubricant base stocks comprising:
a first lubricant base stock in the hydroprocessed effluent having a kinematic viscosity at 100° C. of at least 8.0 cSt; and
a second lubricant base stock in the hydroprocessed effluent having a kinematic viscosity at 100° C. of at least 3.5 cSt and less than the first lubricant base stock, the first lubricant base stock having a pour point equal to or less than a pour point of the second lubricant base stock, wherein the hydroprocessed effluent is formed by hydroprocessing at least a portion of a bottoms fraction of a feedstock to form a plurality of lubricant base oil products having a viscosity index of at least 120 and a pour point of −12° C. or less, the plurality of base oil products comprising at least the first base oil product and the second base oil product.

2. The hydroprocessed effluent of claim 1 , wherein the second lubricant base stock has a kinematic viscosity at 100° C. of at least 4.0 cSt.

3. The hydroprocessed effluent of claim 1 , wherein the first lubricant base stock has a kinematic viscosity at 100° C. of at least 7.5 cSt.

4. The hydroprocessed effluent of claim 1 , wherein the hydroprocessed effluent comprises at least 7 wt % of the second lubricant base stock.

5. The hydroprocessed effluent of claim 1 , wherein the hydroprocessed effluent comprises at least 11 wt % of the first lubricant base stock.

6. The hydroprocessed effluent of claim 1 , wherein the hydroprocessed effluent comprises a plurality of second lubricant base stocks.

7. The hydroprocessed effluent of claim 1 , wherein the first lubricant base stock and the second lubricant base stock having a viscosity index of at least 120.

8. The hydroprocessed effluent of claim 1 , wherein the first lubricant base stock and the second lubricant base stock having a viscosity index of at least 130.

9. The hydroprocessed effluent of claim 1 , wherein the second lubricant base stock has a pour point of −15° C. or less.

10. The hydroprocessed effluent of claim 1 , wherein the second lubricant base stock has a pour point of −18° C. or less.

11. The hydroprocessed effluent of claim 1 , wherein the hydroprocessed effluent further comprises one or more additional lubricant base stocks having a kinematic viscosity at 100° C. of at least 2 cSt.

12. The hydroprocessed effluent of claim 11 , wherein the hydroprocessed effluent comprises at least 65 wt % of the first lubricant base stock, the second lubricant base stock, and the one or more additional lubricant base stocks.

13. The hydroprocessed effluent of claim 1 , wherein the hydroprocessed effluent further comprises a third lubricant base stock having a kinematic viscosity at 100° C. of at least 12.0 cSt and a viscosity index of at least 130, the third lubricant base stock being different from the first lubricant base stock.

14. The hydroprocessed effluent of claim 13 , wherein the third lubricant base stock has a kinematic viscosity at 100° C. of at least 16.0 cSt.

15. The hydroprocessed effluent of claim 13 , wherein the third lubricant base stock has a pour point of −18° C. or less.

16. The hydroprocessed effluent of claim 13 , wherein the hydroprocessed effluent further comprises one or more additional lubricant base stocks having a kinematic viscosity at 100° C. of at least 2 cSt.

17. The hydroprocessed effluent of claim 16 , wherein the hydroprocessed effluent comprises at least 65 wt % of the first lubricant base stock, the second lubricant base stock, the third lubricant base stock, and the one or more additional lubricant base stocks.

18. The hydroprocessed effluent of claim 1 , wherein the pour point of the first lubricant base stock is less than the pour point of the second lubricant base stock.

19. The first lubricant base stock and the second lubricant base stock of claim 1 , wherein the first lubricant base stock and the second lubricant base stock are separated from the hydroprocessed effluent by fractionation.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Kim Jeenok T
• Schleicher Gary P
• Oumar-Mahamat Halou
• Mondor Chad H

Classifications

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title

• C10M101/02 Primary

  Petroleum fractions · CPC title

• C10G21/003

  Solvent de-asphalting · CPC title

• C10M2203/1025

  used as base material · CPC title