Production of base oils from petrolatum

Patent metadata

Field	Value
Publication number	US-9284500-B2
Application number	US-201414196050-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 14, 2013
Publication date	Mar 15, 2016
Grant date	Mar 15, 2016

Abstract

Methods are provided for producing lubricant base oils from petrolatum. After solvent dewaxing of a brightstock raffinate to form a brightstock base oil, petrolatum is generated as a side product. The petrolatum can be hydroprocessed to form base oils in high yield. The base oils formed from hydroprocessing of petrolatum have an unexpected pour point relationship. For a typical lubricant oil feedstock, the pour point of the base oils generated from the feedstock increases with the viscosity of the base oil. By contrast, lubricant base oils formed from hydroprocessing of petrolatum have a relatively flat pour point relationship, and some of the higher viscosity base oils unexpectedly have lower pour points than lower viscosity base oils generated from the same petrolatum feed. The base oils from petrolatum are also unusual in yielding both high viscosity and high viscosity index and can be generated while maintaining a high yield.

First claim

What is claimed is:

1. A method for forming lubricant base oils, comprising:
separating a feedstock into at least a first fraction and a bottoms fraction, a distillation cut point for separating the first fraction and the bottoms fraction being at least 950° F. (510° C.);
deasphalting the bottoms fraction to form a deasphalted bottoms fraction and an asphalt product;
extracting the deasphalted bottoms in the presence of an extraction solvent to form a raffinate stream and an extract stream, an aromatics content of the raffinate stream being lower than an aromatics content of the deasphalted bottoms;
dewaxing the raffinate stream in the presence of a dewaxing solvent to form a lubricant base oil product and a waxy product having a wax content of at least 70 wt %;
hydrotreating at least a portion of the waxy product under effective hydrotreating conditions to form a hydrotreated effluent, the effective hydrotreating conditions being effective for conversion of 10 wt % or less of a portion of the waxy product boiling above 700° F. (371° C.) to a portion boiling below 700° F. (371° C.);
separating the hydrotreated effluent to form at least a liquid hydrotreated effluent;
dewaxing the liquid hydrotreated effluent in the presence of a dewaxing catalyst under effective dewaxing conditions to form a dewaxed effluent, the effective dewaxing conditions being effective for conversion of 10 wt % to 35 wt % of a portion of the hydrotreated effluent boiling above 700° F. (371° C.) to a portion boiling below 700° F. (371° C.); and
fractionating the dewaxed effluent to form a plurality of lubricant base oil products having a viscosity index of at least 120 and a pour point of −12° C. or less, the plurality of base oil products comprising at least a first base oil product having a lower pour point that a second base oil product, the first base oil product having a higher viscosity at 100° C. than the second base oil product.

2. The method of claim 1 , wherein the first base oil product and the second base oil product have a viscosity index of at least 130.

3. The method of claim 1 , wherein the plurality of lubricant base oil products have a pour point of −15° C. or less.

4. The method of claim 1 , wherein the waxy product has a T50 boiling point of at least 1050° F. (566° C.).

5. The method of claim 1 , wherein the first base oil product has a viscosity of at least 7.5 cSt at 100° C.

6. The method of claim 1 , wherein the second base oil product has a viscosity of at least 3.5 cSt at 100° C.

7. The method of claim 1 , wherein the first base oil has a viscosity of at least 12 cSt at 100° C.

8. The method of claim 1 , wherein the plurality of base oils further comprises a third base oil having a viscosity of at least 12 cSt at 100° C., the third base oil having a viscosity index of at least 130.

9. The method of claim 1 , wherein the plurality of base oils are substantially free of haze.

10. The method of claim 1 , wherein the amount of conversion during hydrotreating is 8 wt % or less relative to a conversion temperature of 371° C.

Assignees

• Kim Jeenok T
• Schleicher Gary Paul
• Oumar-Mahamat Halou
• Mondor Chad Hinden
• Exxonmobil Res & Eng Co

Inventors

• Kim Jeenok T
• Schleicher Gary Paul
• Oumar-Mahamat Halou
• Mondor Chad Hinden

Classifications

• C10N2020/02

  Viscosity; Viscosity index · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10G45/58

  to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins (C10G32/00 takes precedence; improving or increasing the octane number or aromatic content of naphtha C10G35/00) · CPC title

• C10G2300/302

  Viscosity · CPC title

• C10G2400/10

  Lubricating oil · CPC title