Latex composition for dip-forming including carboxylic acid modified-nitrile based copolymer latex and dip-formed article prepared therefrom

Patent metadata

Field	Value
Publication number	US-10023728-B2
Application number	US-201515507940-A
Country	US
Kind code	B2
Filing date	Oct 20, 2015
Priority date	Oct 20, 2014
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The present invention relates to a latex composition for dip-forming including two different types of carboxylic acid modified-nitrile based copolymer latex, and a dip-formed article prepared therefrom having excellent durability for sweat, and having high tensile strength and elongation percentage. Accordingly, the latex composition for dip-forming has excellent tensile strength, elongation percentage, stress and durability, and is useful in industries requiring these, for example, a rubber glove industry and the like.

First claim

What is claimed is:

1. A latex composition for dip-forming comprising:
a) carboxylic acid modified-nitrile based copolymer latex having a glass transition temperature of −30° C. to −5° C. and an average particle diameter of 100 nm to 200 nm, and including a reactive compound; and
b) carboxylic acid modified-nitrile based copolymer latex having a glass transition temperature of −30° C. to −15° C. and an average particle diameter of 100 nm to 200 nm, wherein the reactive compound is not included,
wherein the composition includes the a) carboxylic acid modified-nitrile based copolymer latex and the b) carboxylic acid modified-nitrile based copolymer latex in a weight ratio of 3:7 to 8:2, and wherein the reactive compound is a compound having one or more types of reactive groups selected from the group consisting of a vinyl group, an epoxy group and a glycidyl group.

2. The latex composition for dip-forming of claim 1 , wherein the a) carboxylic acid modified-nitrile based copolymer latex includes 0.1 parts by weight to 5 parts by weight of the reactive compound with respect to 100 parts by weight of a monomer mixture, and the monomer mixture includes 40% by weight to 89% by weight of a conjugated diene-based monomer; 10% by weight to 50% by weight of an ethylenically unsaturated nitrile-based monomer; and 0.1% by weight to 10% by weight of an ethylenically unsaturated acid monomer, and
wherein the b) carboxylic acid modified-nitrile based copolymer latex includes 40% by weight to 89% by weight of a conjugated diene-based monomer; 10% by weight to 50% by weight of an ethylenically unsaturated nitrile-based monomer; and 0.1% by weight to 10% by weight of an ethylenically unsaturated acid monomer.

3. The latex composition for dip-forming of claim 2 , wherein the reactive compound is one or more types selected from the group consisting of a poly(tetramethylene ether)glycol diglycidyl ether compound, a 3-alkoxy-2-hydroxypropyl acrylate compound having 12 to 13 carbon atoms and a propylene glycol polybutyrene glycol monoacrylate compound.

4. The latex composition for dip-forming of claim 2 , wherein the reactive compound has a weight average molecular weight of 250 to 1000.

5. The latex composition for dip-forming of claim 2 , wherein the conjugated diene-based monomer is one or more types selected from the group consisting of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene, 2-ethyl-1,3-butadiene, 1,3-pentadiene and isoprene.

6. The latex composition for dip-forming of claim 2 , wherein the ethylenically unsaturated nitrile-based monomer is one or more types selected from the group consisting of acrylonitrile, methacrylonitrile, fumaronitrile, α-chloronitrile and α-cyanoethyl acrylonitrile.

7. The latex composition for dip-forming of claim 2 , wherein the ethylenically unsaturated acid monomer is an ethylenically unsaturated monomer having a carboxyl group, a sulfonic acid group or an acid anhydride group.

8. The latex composition for dip-forming of claim 2 , wherein the ethylenically unsaturated acid monomer is one or more types selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, maleic anhydride, citraconic anhydride, styrenesulfonic acid, monobutyl fumarate, monobutyl maleate and mono-2-hydroxypropyl maleate.

9. The latex composition for dip-forming of claim 2 , wherein the a) carboxylic acid modified-nitrile based copolymer latex and the b) carboxylic acid modified-nitrile based copolymer latex each further includes 0.1% by weight to 20% by weight of an ethylenically unsaturated monomer.

10. The latex composition for dip-forming of claim 9 , wherein the ethylenically unsaturated monomer is one or more types selected from the group consisting of styrene, alkyl styrene, vinyl naphthalene, fluoroethyl vinyl ether, (meth)acrylamide, N-methylol (meth)acrylamide, N,N-dimethylol (meth)acrylamide, N-methoxymethyl (meth)acrylamide, N-propoxymethyl (meth)acrylamide, vinyl pyridine, vinyl norbornene, dicyclopentadiene, 1,4-hexadiene, methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, trifluoroethyl (meth)acrylate, tetrafluoropropyl (meth)acrylate, dibutyl maleate, dibutyl fumarate, diethyl maleate, methoxymethyl (meth)acrylate, ethoxyethyl (meth)acrylate, methoxyethoxyethyl (meth)acrylate, cyanomethyl (meth)acrylate, 2-cyanoethyl (meth)acrylate, 1-cyanopropyl (meth)acrylate, 2-ethyl-6-cyanohexyl (meth)acrylate, 3-cyanopropyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, glycidyl (meth)acrylate and dimethylaminoethyl (meth)acrylate.

11. The latex composition for dip-forming of claim 1 comprising the a) carboxylic acid modified-nitrile based copolymer latex and the b) carboxylic acid modified-nitrile based copolymer latex in 80% by weight to 99% by weight with respect to a total weight of the composition, and a solid concentration of 10% to 40% by weight with respect to the total weight of the composition.

12. The latex composition for dip-forming of claim 1 , which has a pH of 8 to 12.

13. A dip-formed article prepared from the latex composition for dip-forming of claim 1 .

14. The dip-formed article of claim 13 , which has nitrogen content of 6.69% by weight to 8.94% by weight based on a total weight of the dip-formed article.

15. The dip-formed article of claim 13 , which is one or more types of molded articles selected from the group consisting of an examination glove, a condom, a catheter, an industrial glove, a household glove and a health care product.

Assignees

• Lg Chemical Ltd

Inventors

• Cha Yu Jin
• Han Jung Su
• Kim Ji Hyun
• Yeu Seung Uk

Classifications

• C08L13/02 Primary

  Latex · CPC title

• C08L51/04

  grafted on to rubbers · CPC title

• C08L9/04 Primary

  Latex · CPC title

• C08L15/005

  Hydrogenated nitrile rubber · CPC title

• C08F220/46

  with carboxylic acids, sulfonic acids or salts thereof · CPC title