Hydroxyalkyl acrylate and method for producing same

Patent metadata

Field	Value
Publication number	US-10023522-B2
Application number	US-201314427108-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Sep 24, 2012
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

The hydroxyalkyl acrylate according to the present invention is characterized in that a content amount of an ester generated from acrylic acid dimer and an alkylene oxide is not more than 0.10 mass %. The method for producing a hydroxyalkyl acrylate according to the present invention is characterized in comprising the step of reacting acrylic acid with an alkylene oxide in the presence of a catalyst, wherein a content amount of acrylic acid dimer in the raw material acrylic acid is not more than 3.00 mass %.

First claim

The invention claimed is:

1. A method for producing a hydroxyalkyl acrylate,
comprising the step of reacting a raw material acrylic acid comprising acrylic acid and acrylic acid dimer with an alkylene oxide in the presence of a catalyst,
wherein an amount of acrylic acid dimer in the raw material acrylic acid is less than or equal to 3.00 mass %, and
wherein a molar ratio of the alkylene oxide relative to the acrylic acid is adjusted to be more than or equal to 1.010 and less than or equal to 1.055, and the molar ratio is calculated by the following formula:
molar ratio of AO/AA=(mass of AO/molecular weight of AO)/({mass of raw material AA×[(100−concentration of AA dimer)/100]}/molecular weight of AA),

wherein AO represents alkylene oxide, AA represents acrylic acid, molar ratio of AO/AA represents the molar ratio of the alkylene oxide relative to the acrylic acid, units of mass of AO and mass of AA are g, and a unit of concentration of AA dimer is mass %.

2. The method according to claim 1 , further comprising the step of adjusting the amount of acrylic acid dimer in the raw material acrylic acid to be less than or equal to 3.00 mass % when the amount of the acrylic acid dimer is more than 3.00 mass %.

3. The method according to claim 1 , wherein an initial charged amount of the raw material acrylic acid is adjusted to be less than or equal to 90 mass % of the whole use amount, and after all of or a part of the alkylene oxide is supplied, the rest of the raw material acrylic acid is supplied.

4. The method according to claim 1 , wherein ethylene oxide or propylene oxide is used as the alkylene oxide.

5. The method according to claim 2 , wherein an initial charged amount of the raw material acrylic acid is adjusted to be less than or equal to 90 mass % of the whole use amount, and after all or a part of the alkylene oxide is supplied, the rest of the raw material acrylic acid is supplied.

6. The method according to claim 2 , wherein ethylene oxide or propylene oxide is used as the alkylene oxide.

7. The method according to claim 3 , wherein ethylene oxide or propylene oxide is used as the alkylene oxide.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• Nakamura Masataka
• Ishida Tokumasa
• Takaki Hiroyuki
• Jinno Hiroshi

Classifications

• C07C67/26 Primary

  with an oxirane ring · CPC title

• C07C69/54

  Acrylic acid esters; Methacrylic acid esters · CPC title