Adsorbing contaminants from a gas stream

Patent metadata

Field	Value
Publication number	US-10016717-B2
Application number	US-201514853340-A
Country	US
Kind code	B2
Filing date	Sep 14, 2015
Priority date	Nov 6, 2014
Publication date	Jul 10, 2018
Grant date	Jul 10, 2018

Abstract

A method and systems for adsorbing contaminants from a gas stream are provided herein. The method includes flowing the gas stream into a treating vessel and through a moving bed of adsorbents. The method includes flowing the adsorbents out of the treating vessel and into a fluidized bed of a regenerator. The method includes desorbing the contaminants from the adsorbents in the fluidized bed of the regenerator to form regenerated adsorbents. The method further includes cooling the adsorbents and returning the cooled, regenerated adsorbents to the treating vessel.

First claim

What is claimed is:

1. A method for adsorbing contaminants from a gas stream, the method comprising:
flowing the gas stream through a plurality of separate trays in a treating vessel, each of the plurality of separate trays comprising a moving bed of adsorbents to adsorb contaminants in the gas stream;
flowing the adsorbents in each of the plurality of separate trays directly out of the treating vessel and into a fluidized bed of a regenerator without being flowed onto another of the plurality of separate trays;
desorbing the contaminants from the adsorbents in the fluidized bed of the regenerator to form regenerated adsorbents;
cooling the regenerated adsorbents; and
returning the cooled, regenerated adsorbents to the treating vessel.

2. The method of claim 1 , wherein the adsorbents comprise a blend of different adsorbent types.

3. The method of claim 1 , wherein the adsorbent moves counter-current to the gas stream in the treating vessel at a flow rate of about 0.4 cm/s to about 4 cm/s.

4. The method of claim 1 , wherein desorbing the contaminants in the gas stream comprises flowing a regeneration gas into the regenerator at a velocity of about 8 cm/s to about 50 cm/s.

5. The method of claim 1 , comprising adjusting a particle size of the adsorbents to substantially match fluidization characteristics.

6. The method of claim 1 , comprising adjusting the amount of regenerated adsorbents before reintroduction into the treating vessel.

7. The method of claim 1 , wherein the regenerated adsorbents are cooled via a cooler before reintroduction into the treating vessel.

8. The method of claim 1 , wherein each tray contains a different blend of various adsorbent types.

9. The method of claim 1 , comprising flowing the adsorbents out of the treating vessel and into a plurality of fluidized bed regenerators, wherein each fluidized bed regenerator is associated with one of the plurality of separate trays.

10. The method of claim 1 , comprising returning a plurality of regenerated adsorbent streams to the treating vessel.

11. The method of claim 1 , wherein the adsorbents comprise a plurality of adsorbents selected to adsorb a plurality of contaminants, wherein the adsorbents are based on the type of contaminants, and further comprising:
blending the plurality of adsorbents; and
feeding the blend of adsorbents through the treating vessel as a blended moving bed of adsorbents.

12. The method of claim 2 , wherein the blend of different adsorbent types comprises molecular sieves, silica gel, activated alumina, metal-organic-framework molecular sieves, zeolite molecular sieves, amine-treated molecular sieves, metal-impregnated adsorbents, or any combinations thereof.

13. The method of claim 1 , wherein the adsorbents remove contaminants from a gas stream comprising water, hydrogen sulfide, carbon dioxide, mercaptans, or heavier hydrocarbons, or any combinations thereof.

14. The method of claim 1 , wherein a particle size of the adsorbents ranges from about 100 μm to about 5000 μm.

15. The method of claim 1 , wherein a particle density of the adsorbents ranges from about 1.4 g/cm−3 to about 5.0 g/cm−3.

16. The method of claim 1 , wherein each of the plurality of separate trays are v-shaped.

Assignees

• Calafell Dag O
• Northrop P Scott
• Exxonmobil Upstream Res Co

Inventors

• Calafell Dag O
• Northrop P Scott

Classifications

• B01D2253/204

  Metal organic frameworks (MOF's) · CPC title

• B01D2257/602

  Mercury or mercury compounds · CPC title

• B01J20/34

  Regenerating or reactivating · CPC title

• B01D2256/245

  Methane · CPC title

• B01D2257/306

  Organic sulfur compounds, e.g. mercaptans · CPC title