Anti-fogging coated transparent article

Patent metadata

Field	Value
Publication number	US-10011733-B2
Application number	US-201515316045-A
Country	US
Kind code	B2
Filing date	Jun 3, 2015
Priority date	Jun 5, 2014
Publication date	Jul 3, 2018
Grant date	Jul 3, 2018

Abstract

Provided is an anti-fogging coated transparent article including an anti-fog film, the anti-fog film being a single-layer film containing a water-absorbent resin, a hydrophobic group, and a metal oxide component. The hydrophobic group is a chain or cyclic alkyl group having 1 to 30 carbon atoms, preferably a linear alkyl group having 6 to 14 carbon atoms, in which at least one hydrogen atom is optionally substituted by a fluorine atom. The hydrophobic group is bonded directly to a metal atom of the metal oxide component. The anti-fog film contains, for example, the metal oxide component in an amount of 0.01 to 60 parts by mass and the hydrophobic group in an amount of 0.05 to 10 parts by mass per 100 parts by mass of the water-absorbent resin. The water-absorbent resin is, for example, polyvinyl acetal.

First claim

The invention claimed is:

1. An anti-fogging coated transparent article, comprising a transparent article and an anti-fog film formed on the transparent article, wherein
the anti-fog film is a single-layer film containing a water-absorbent resin, a hydrophobic group, and a metal oxide component,
the water-absorbent resin is polyvinyl acetal,
the anti-fog film includes at least 50% by mass of the water-absorbent resin,
the hydrophobic group is a linear alkyl group having 6 to 14 carbon atoms, and
the hydrophobic group is bonded directly to a metal atom of the metal oxide component.

2. The anti-fogging coated transparent article according to claim 1 , wherein the anti-fog film contains the metal oxide component in an amount of 0.1 to 60 parts by mass per 100 parts by mass of the water-absorbent resin.

3. The anti-fogging coated transparent article according to claim 1 , wherein a water contact angle on a surface of the anti-fog film is 70 degrees or more as measured for 4 mg of a water droplet placed on the surface.

4. The anti-fogging coated transparent article according to claim 1 , wherein the anti-fog film contains the hydrophobic group in an amount of 0.05 to 10 parts by mass per 100 parts by mass of the water-absorbent resin.

5. The anti-fogging coated transparent article according to claim 1 , wherein the polyvinyl acetal contains an acetal structure derived from an aromatic aldehyde.

6. The anti-fogging coated transparent article according to claim 1 , wherein the anti-fog film contains a cross-linked structure derived from at least one cross-linker selected from an organoboron compound, an organotitanium compound, and an organozirconium compound.

7. The anti-fogging coated transparent article according to claim 6 , wherein the anti-fog film contains a cross-linked structure derived from titanium lactate added to a coating liquid for forming the anti-fog film.

8. The anti-fogging coated transparent article according to claim 1 , wherein at least a portion of the metal oxide component is in the form of fine metal oxide particles.

9. The anti-fogging coated transparent article according to claim 1 , wherein
at least a portion of the metal oxide component is a metal oxide component derived from a hydrolyzable metal compound, or a hydrolysate of the hydrolyzable metal compound, added to a coating liquid for forming the anti-fog film, and
the hydrolyzable metal compound is at least one selected from: (a) a hydrolyzable metal compound having the hydrophobic group; and (b) a hydrolyzable metal compound that does not have the hydrophobic group.

10. The anti-fogging coated transparent article according to claim 1 , wherein
the metal oxide component comprises: a metal oxide component derived from fine metal oxide particles added to a coating liquid for forming the anti-fog film; and a metal oxide component derived from a hydrolyzable metal compound, or a hydrolysate of the hydrolyzable metal compound, added to the coating liquid, and
the hydrolyzable metal compound is at least one selected from: (a) a hydrolyzable metal compound having the hydrophobic group; and (b) a hydrolyzable metal compound that does not have the hydrophobic group.

11. The anti-fogging coated transparent article according to claim 9 , wherein (b) the hydrolyzable metal compound that does not have the hydrophobic group comprises at least one selected from a tetraalkoxysilane and a silane coupling agent.

12. The anti-fogging coated transparent article according to claim 1 , wherein the metal oxide component is a silica component, and the anti-fog film further contains a metal atom other than a silicon atom.

13. An anti-fogging coated transparent article, comprising a transparent article and an anti-fog film formed on the transparent article, wherein
the anti-fog film is a single-layer film containing a water-absorbent resin, a hydrophobic group, and a metal oxide component,
the water-absorbent resin is polyvinyl acetal,
the content of the water-absorbent resin in the anti-fog film is 50 mass % or more,
the hydrophobic group is at least one selected from: (1) a chain or cyclic alkyl group having 3 to 30 carbon atoms; and (2) a chain or cyclic alkyl group having 1 to 30 carbon atoms in which at least one hydrogen atom is substituted by a fluorine atom,
the hydrophobic group is bonded directly to a metal atom of the metal oxide component,
the metal oxide component is a silica component, and
the hydrophobic group and the silica component forms a component represented by the following formula:
R m SiO (4-m)/2 ,

where R is the hydrophobic group and m is an integer of 1 to 3.

14. The anti-fogging coated transparent article according to claim 13 , wherein
the anti-fog film contains the metal oxide component in an amount of 5.58 to 60 parts by mass per 100 parts by mass of the water-absorbent resin, and
a water contact angle on a surface of the anti-fog film is 70 degrees or more as measured for 4 mg of a water droplet placed on the surface.

15. The anti-fogging coated transparent article according to claim 13 , wherein the hydrophobic group is a methyl group or an ethyl group, and a water contact angle on a surface of the anti-fog film is 70 degrees or more as measured for 4 mg of a water droplet placed on the surface.

16. The anti-fogging coated transparent article according to claim 13 , wherein the anti-fog film contains the hydrophobic group in an amount of 0.05 to 10 parts by mass per 100 parts by mass of the water-absorbent resin.

17. The anti-fogging coated transparent article according to claim 13 , wherein the polyvinyl acetal contains an acetal structure derived from an aromatic aldehyde.

18. The anti-fogging coated transparent article according to claim 13 , wherein the anti-fog film contains a cross-linked structure derived from at least one cross-linker selected from an organoboron compound, an organotitanium compound, and an organozirconium compound.

19. The anti-fogging coated transparent article according to claim 18 , wherein the anti-fog film contains a cross-linked structure derived from titanium lactate added to a coating liquid for forming the anti-fog film.

20. The anti-fogging coated transparent article according to claim 13 , wherein at least a portion of the metal oxide component is in the form of fine metal oxide particles.

21. The anti-fogging coated transparent article according to claim 13 , wherein the anti-fog film further contains a metal atom other than a silicon atom.

22. An anti-fogging coated transparent article, comprising a transparent article and an anti-fog film formed on the transparent article, wherein
the anti-fog film is a single-layer film containing a water-absorbent resin, a hydrophobic group, and a metal oxide component,
the water-absorbent resin is polyvinyl acetal,
the content of the water-absorbent resin in the anti-fog film is 50 mass % or more,
the hydrophobic group is a chain or cyclic alkyl group having 1 to 30 carbon atoms in which at least one hydrogen atom is optionally substituted by a fluorine atom,
the hydrophobic group is bonded directly to a metal atom of the metal oxide component, the anti-fog film contains the metal oxide component in an amount of 5.58 to 60 parts by mass per 100 parts by mass of the water-absorbent resin, and
a water contact angle on a surface of the anti-fog film is 70 degrees or more as measured for 4 mg of a water droplet placed on the surface.

23. The anti-fogging coated transparen

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Oya Kazuaki
• Kamitani Kazutaka

Classifications

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C09D7/67

  Particle size smaller than 100 nm · CPC title

• B32B27/18

  characterised by the use of special additives · CPC title

• C09D159/00

  Coating compositions based on polyacetals; Coating compositions based on derivatives of polyacetals · CPC title

• B32B27/30

  comprising vinyl {(co)polymers; comprising acrylic (co)polymers} · CPC title