Transparent adhesive sheet

Patent metadata

Field	Value
Publication number	US-10005924-B2
Application number	US-201515119586-A
Country	US
Kind code	B2
Filing date	Feb 24, 2015
Priority date	Feb 28, 2014
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

The present invention is a transparent pressure-sensitive adhesive sheet that is formed of a resin composition [F], and has a storage modulus at 25° C. of 1×106 to 1×108 Pa, the resin composition [F] comprising a modified hydrogenated block copolymer [E] as a main component, the modified hydrogenated block copolymer [E] being obtained by introducing an alkoxysilyl group into a hydrogenated block copolymer [D], the hydrogenated block copolymer [D] being obtained by hydrogenating 90% or more of unsaturated bonds of a block copolymer [C] that comprises at least two polymer blocks [A] comprising a specific compound and at least one polymer block [B] comprising a specific compound, and a ratio (wA:wB) of a total weight fraction wA of the polymer block [A] in the block copolymer [C] to a total weight fraction wB of the polymer block [B] in the block copolymer [C] being 20:80 to 60:40.

First claim

The invention claimed is:

1. A transparent pressure-sensitive adhesive sheet that is formed of a resin composition [F], and has a storage modulus at 25° C. of 1×10 6 to 1×10 8 Pa, the resin composition [F] comprising a modified hydrogenated block copolymer [E] as a main component, and a tackifier [H] in a ratio of 1 to 50 parts by weight based on 100 parts by weight of the modified hydrogenated block copolymer [E], the modified hydrogenated block copolymer [E] being obtained by introducing an alkoxysilyl group into a hydrogenated block copolymer [D], the hydrogenated block copolymer [D] being obtained by hydrogenating 90% or more of unsaturated bonds of a block copolymer [C] that comprises at least two polymer blocks [A] and at least one polymer block [B], the polymer block [A] comprising a repeating unit derived from an aromatic vinyl compound as a main component, the polymer block [B] comprising a repeating unit derived from a chain conjugated diene compound as a main component, and a ratio (wA:wB) of a total weight fraction wA of the polymer block [A] in the block copolymer [C] to a total weight fraction wB of the polymer block [B] in the block copolymer [C] being 20:80 to 60:40.

2. The transparent pressure-sensitive adhesive sheet according to claim 1 , wherein the resin composition [F] further comprises a hydrocarbon-based polymer [G] having a number average molecular weight of 300 to 5,000 in a ratio of 1 to 50 parts by weight based on 100 parts by weight of the modified hydrogenated block copolymer [E].

3. The transparent pressure-sensitive adhesive sheet according to claim 1 , wherein the storage modulus at 25° C. is 2×10 6 to 5×10 7 Pa.

4. The transparent pressure-sensitive adhesive sheet according to claim 1 , wherein the storage modulus at 25° C. is 3×10 6 to 1×10 7 Pa.

5. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength at 70° C. of 0.1 to 2.0 N/cm.

6. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength at 70° C. of 0.2 to 1.5 N/cm.

7. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength at 70° C. of 0.3 to 1.0 N/cm.

8. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength after heating to 100° C. of 3.0 N/cm or more.

9. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength after heating to 100° C. of 5.0 N/cm or more.

10. The transparent pressure-sensitive adhesive sheet according to claim 1 , which has a 180° peel strength after heating to 100° C. of 7.0 N/cm or more.

Assignees

• Zeon Corp

Inventors

• Ishiguro Atsushi
• SAITOU Daisuke
• Kohara Teiji

Classifications

• C09J2453/00

  Presence of block copolymer · CPC title

• C09J2203/318

  for the production of liquid crystal displays · CPC title

• C09J153/02

  Vinyl aromatic monomers and conjugated dienes · CPC title

• C09J2423/00

  Presence of polyolefin · CPC title

• C09J153/025

  modified · CPC title