Unconventional reservoir enhanced or improved oil recovery

Patent metadata

Field	Value
Publication number	US-RE50086-E
Application number	US-202117359161-A
Country	US
Kind code	E1
Filing date	Jun 25, 2021
Priority date	Aug 18, 2017
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

A method of enhanced oil recovery from an unconventional resource reservoir comprises injecting an enhanced recovery fluid into the unconventional resource reservoir via an injection well and producing hydrocarbons from the unconventional resource reservoir via the injection well or a production well offset from the injection well.

First claim

The invention claimed is:

1. A method for enhanced or improved hydrocarbon recovery, comprising:
injecting an enhanced or improved recovery fluid through an injection well into an unconventional resource reservoir at a pressure below the unconventional resource reservoir fracture pressure to mobilize and displace hydrocarbons, wherein the injection well of the unconventional resource reservoir has been previously hydraulically fractured and contains one or more sections of hydraulic fractures, wherein the enhanced or improved recovery fluid comprises an unfractionated hydrocarbon liquid mixture that is a byproduct of a condensed and de-methanized hydrocarbon stream that is miscible with hydrocarbons in the unconventional resource reservoir, wherein the unfractionated hydrocarbon mixture is condensed out of the hydrocarbon stream at a temperature at or below 0 degrees Fahrenheit, wherein the unfractionated hydrocarbon mixture comprises ethane, propane, and butane in an amount of at least 75% by volume, and wherein the unfractionated hydrocarbon mixture comprises pentane plus in an amount less than 25% by volume;
alternating slugs of the enhanced or improved recovery fluid into the unconventional resource reservoir with slugs of a gas;
injecting a final displacement fluid into the unconventional resource reservoir at the conclusion of the injection of the enhanced or improved recovery fluid and the gas at a pressure below the unconventional resource reservoir fracture pressure to mobilize the enhanced or improved recovery fluid and hydrocarbons in the unconventional resource reservoir; and
producing hydrocarbons from the unconventional resource reservoir via the injection well or a production well offset from the injection well, wherein the injection well comprises an array of vertical or horizontal injection wells, and wherein the production well comprises an array of vertical or horizontal production wells offset from the array of injection wells.

2. The method of claim 1 , wherein the final displacement fluid comprises at least one of a gas, water, and viscosified water.

3. The method of claim 1 , wherein the enhanced or improved recovery fluid further comprises at least one of carbon dioxide, nitrogen, natural gas, LNG, methane, ethane, water, and viscosified water.

4. The method of claim 3 , wherein the nitrogen is sourced in liquid form from an air separation plant, stored at the well site in liquid, then vaporized to gaseous form.

5. The method of claim 3 , wherein the nitrogen is sourced in pressurized form from an air separation plant.

6. The method of claim 1 , wherein the unconventional resource reservoir is a residual oil zone (ROZ).

7. The method of claim 1 , further comprising adding a secondary fluid to the enhanced or improved recovery fluid, wherein the secondary fluid comprises at least one of aromatics, alkanes, and crude oil, and wherein the secondary fluid comprises 10% or less by volume of the enhanced or improved recovery fluid.

8. The method of claim 7 , wherein the crude oil comprises at least one of residual oil in the unconventional resource reservoir, medium oil, light oil, and condensate.

9. The method of claim 1 , further comprising adding nanoparticles to the enhanced or improved recovery fluid.

10. The method of claim 1 , further comprising mixing the unfractionated hydrocarbon mixture with a surfactant and a gas to form a hydrocarbon foam as the enhanced or improved recovery fluid.

11. The method of claim 10 , wherein the gas comprises at least one of nitrogen, carbon dioxide, methane, ethane, LNG, or natural gas.

12. The method of claim 11 , wherein the nitrogen is sourced in liquid form from an air separation plant, stored at the well site in liquid form, then vaporized to gaseous form.

13. The method of claim 11 , wherein the nitrogen is sourced in pressurized form from an air separation plant.

14. The method of claim 10 , wherein the surfactant comprises at least one of an anionic surfactant and a nonionic surfactant.

15. The method of claim 14 , wherein the surfactant is a nonionic surfactant, and wherein the nonionic surfactant comprises at least one of a siloxane surfactant, a fluorosurfactant, a fatty acid ester, a glyceride, a silicon emulsifier, and a hydrophobic silica powder, wherein the surfactant comprises a mass concentration of up to 5%.

16. The method of claim 10 , further comprising adding a secondary fluid to the hydrocarbon foam, wherein the secondary fluid comprises at least one of aromatics, alkanes, and crude oil, and wherein the secondary fluid comprises 10% or less by volume of the hydrocarbon foam.

17. The method of claim 16 , wherein the crude oil comprises at least one of residual oil in the unconventional resource reservoir, medium oil, light oil, and condensate.

18. The method of claim 10 , further comprising adding nanoparticles to the hydrocarbon foam.

19. The method of claim 1 , further comprising mixing the unfractionated hydrocarbon mixture with a surfactant, a gas, and water to form an emulsion based foam as the enhanced or improved recovery fluid.

20. The method of claim 19 , wherein the surfactant acts as one or both of a foaming agent and an emulsifying agent.

21. The method of claim 19 , wherein the water is formation water, brine, or seawater and comprises up to 25% of the liquid phase of the emulsion based foam.

22. The method of claim 19 , wherein the water is potassium chloride water and comprises up to 25% of the liquid phase of the emulsion based foam, and wherein the potassium chloride water comprises up to 4% potassium chloride.

23. The method of claim 19 , wherein the gas mixed with the unfractionated hydrocarbon mixture, the surfactant, and the water to form the emulsion based foam comprises at least one of nitrogen, carbon dioxide, natural gas, methane, LNG, and ethane.

24. The method of claim 23 , wherein the nitrogen is liquid nitrogen sourced from an air separation device configured to separate nitrogen from air and supply the nitrogen to a nitrogen source.

25. The method of claim 24 , wherein the air separation device is a modular air separation plant with a liquification unit to create liquid nitrogen.

26. The method of claim 19 , wherein the surfactant comprises at least one of a nonionic surfactant, an anionic surfactant, and a cationic surfactant, and wherein the surfactant comprises a mass concentration of up to 5%.

27. The method of claim 26 , wherein the nonionic surfactant comprises at least one of a siloxane surfactant, a fluorosurfactant, a fatty acid ester, a glyceride, a silicon emulsifier, and a hydrophobic silica powder.

28. The method of claim 22 , further comprising adding a secondary fluid to the emulsion based foam, wherein the secondary fluid comprises 10% or less by volume of the emulsion based foam, wherein the secondary fluid comprises at least one of aromatics, alkanes, and crude oil.

29. The method of claim 28 , wherein the crude oil comprises at least one of residual oil in the unconventional resource reservoir, medium oil, light oil, and condensate.

30. The method of claim 22 , further comprising adding nanoparticles to the emulsion based foam.

31. The method of claim 1 , further comprising mixing the unfractionated hydrocarbon mixture with an emulsifying agent and water to form an emulsion as the

Assignees

• Linde Ag
• Babcock John A

Inventors

• Babcock John A
• Siess Iii Charles P
• Watts Kevin G
• Watts Roberta

Classifications

• E21B43/305

  comprising at least one inclined or horizontal well · CPC title

• E21B43/20

  Displacing by water · CPC title

• E21B43/168

  Injecting a gaseous medium · CPC title

• E21B43/164 Primary

  Injecting CO2 or carbonated water (in combination with organic material C09K8/594) · CPC title

• E21B43/16

  Enhanced recovery methods for obtaining hydrocarbons · CPC title