Polycrystalline vanadium oxide nanosheets

Patent metadata

Field	Value
Publication number	US-9997778-B2
Application number	US-201314440849-A
Country	US
Kind code	B2
Filing date	Nov 5, 2013
Priority date	Nov 5, 2012
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

Improved V 2 O 5 materials are disclosed herein in the form of 2D leaf-like nanosheets. Methods of forming the V 2 O 5 nanosheets and batteries (e.g., lithium-ion) incorporating the V 2 O 5 nanosheets are also provided.

First claim

The invention claimed is:

1. A method of forming polycrystalline V 2 O 5 nanosheets comprising the steps of:
(a) providing a V 2 O 5 gel by sonicating a solution of hydrogen peroxide and V 2 O 5 powder;
(b) freezing the V 2 O 5 gel to provide a pre-frozen V 2 O 5 gel;
(c) lyophilizing the pre-frozen V 2 O 5 gel to provide lyophilized V 2 O 5 ; and
(d) annealing the lyophilized V 2 O 5 by heating to a temperature of at least 350° C. to provide polycrystalline V 2 O 5 nanosheets,
wherein the hydrogen peroxide and the V 2 O 5 powder are present in a molar ratio of H 2 O 2 :V 2 O 5 of about 16:1.

2. The method of claim 1 , wherein the freezing step lasts at least one day at 20° C.

3. The method of claim 1 , wherein the lyophilizing step is a temperature of 50° C. or less and a vacuum of 0.1 Torr or less.

4. The method of claim 1 , wherein the annealing step is performed in an atmosphere selected from the group consisting of air, oxygen, nitrogen, carbon monoxide, carbon dioxide, argon, and combinations thereof.

5. The method of claim 1 , further comprising adding a carbon source to the solution and performing the annealing step in an oxygen-free atmosphere to provide polycrystalline V 2 O 5 nanosheets with a continuous carbon network throughout the nanosheets.

6. The method of claim 1 , wherein the V 2 O 5 gel comprises a dopant selected from the group consisting of Mn, Fe, Ni, Co, Cr, Ag, Ti, Zn, Sn, Cu, Al, K, Mg, Ca, B, Bi, and combinations thereof.

Assignees

• Univ Washington Through Its Center For Commercialization

Inventors

• Cao Guozhong
• Li Yanwei

Classifications

• C30B5/02

  with addition of doping materials · CPC title

• C01P2006/40

  Electric properties · CPC title

• C30B5/00

  Single-crystal growth from gels (under a protective fluid C30B27/00) · CPC title

• C30B29/60

  characterised by shape · CPC title

• C01P2006/12

  Surface area · CPC title