Negative-electrode material for nonaqueous-electrolyte secondary battery production process for the same, negative electrode for nonaqueous-electrolyte secondary battery, and nonaqueous-electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-9997772-B2
Application number	US-201314419495-A
Country	US
Kind code	B2
Filing date	Aug 23, 2013
Priority date	Aug 28, 2012
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

Providing a negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material including lithium silicate particles coated by a carbonaceous substance, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. A negative-electrode material for nonaqueous-electrolyte secondary battery includes lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of the carbon-containing compound or more and 1,100±° C. or less, the carbon-containing compound being a solid at ordinary temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

First claim

The invention claimed is:

1. A negative-electrode material for nonaqueous-electrolyte secondary battery, the negative-electrode material comprising lithium silicate particles having a surface at least some of which is coated by a carbonaceous substance formed by heating a carbon-containing compound at a thermal decomposition temperature of said carbon-containing compound or more and 1,100° C. or less, said carbon-containing compound being a solid at room temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP).

2. The negative-electrode material for nonaqueous-electrolyte secondary battery as set forth in claim 1 , wherein said lithium silicate particles are at least one member selected from the group consisting of Li 4 SiO 4 , Li 2 SiO 3 , Li 2 Si 2 O 5 , Li 4 Si 3 O 8 , Li 6 Si 4 O 11 , and LiSiO 1.5 .

3. The negative-electrode material for nonaqueous-electrolyte secondary battery as set forth in claim 1 , wherein said carbon-containing compound is at least one member selected from the group consisting of polycarbonate (or PC), polymethyl methacrylate (or PMMA), and polyamide-imide (or PAI).

4. A production process for negative-electrode material for nonaqueous-electrolyte secondary battery, the production process comprising:
a carbon-containing compound selection step of selecting a carbon-containing compound being solid at room temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP);
a solution preparation step of preparing a carbon-containing compound solution by dissolving said carbon-containing compound selected at said carbon-containing compound selection step in an organic solvent in a concentration of from 5% by mass to 50% by mass;
a mixing step of preparing a mixture by mixing lithium silicate particles with said carbon-containing compound solution in such a solid-content ratio as (said lithium silicate particles):(said carbon-containing compound)=from 10:1 to 10:100; and
a heating step of heating said mixture at a thermal decomposition temperature of said carbon-containing compound or more and 1,100° C. or less under an inert atmosphere, or under a reducing atmosphere.

5. The production process for negative-electrode material for nonaqueous-electrolyte secondary battery as set forth in claim 4 , wherein said carbon-containing compound to be selected is polycarbonate (or PC), polymethyl methacrylate (or PMMA), or polyamide-imide (or PAI).

6. A negative electrode for nonaqueous-electrolyte secondary battery, the negative electrode comprising the negative-electrode material for nonaqueous-electrolyte secondary battery as set forth in claim 1 .

7. The negative electrode for nonaqueous-electrolyte secondary battery as set forth in claim 6 , the negative electrode further comprising a negative-electrode active material including SiO x (where 0<“x”<2) or Si.

8. A nonaqueous-electrolyte secondary battery comprising the negative electrode for nonaqueous-electrolyte secondary battery as set forth in claim 6 .

9. The negative-electrode material for nonaqueous-electrolyte secondary battery as set forth in claim 1 , wherein said carbonaceous substance comprises an amorphous structure showing a peak (or “D” band) at around 1,360 cm −1 and another peak (or “G” band) at around 1,580 cm −1 in a Raman shift.

10. A production process for negative-electrode material for nonaqueous-electrolyte secondary battery, the production process comprising:
a carbon-containing compound selection step of selecting a carbon-containing compound being solid at room temperature and exhibiting a zeta-potential absolute value being 60 or more against N-methyl-2-pyrrolidone (or NMP);
a solution preparation step of preparing a carbon-containing compound solution by dissolving said carbon-containing compound selected at said carbon-containing compound selection step in an organic solvent in a concentration of from 5% by mass to 50% by mass;
a mixing step of preparing a mixture by mixing a particulate mixture including lithium silicate particles and SiO x particles (where 0<“x”<2) or Si particles with said carbon-containing compound solution in such a solid-content ratio as (said particulate mixture):(said carbon-containing compound)=from 10:1 to 10:100; and
a heating step of heating said mixture at a thermal decomposition temperature of said carbon-containing compound or more and 1,100° C. or less under an inert atmosphere, or under a reducing atmosphere.

Assignees

• Toyota Jidoshokki Kk

Inventors

• Niimi Tomohiro
• Sugiyama Yusuke
• Watanabe Nagisa
• Kawasumi Kazuhito
• Murase Masakazu
• Nakanishi Masataka

Classifications

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title