PVD-metallic effect pigments with diffractive structure and metal nanoparticles, process for preparing them and use thereof
US-9453131-B2 · Sep 27, 2016 · US
US9995944B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9995944-B2 |
| Application number | US-201515315947-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 3, 2015 |
| Priority date | Jun 13, 2014 |
| Publication date | Jun 12, 2018 |
| Grant date | Jun 12, 2018 |
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Optical stacks including a grating structure that generates diffraction in two in-plane dimensions. The optical stacks may include two gratings, which may be one-directional or two-directional, or may include a single two-directional grating. The optical stacks include particles selected to give controlled diffusion of light. The optical stacks are suitable for reducing sparkle in displays.
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What is claimed is: 1. An optical stack, comprising a first layer and a second layer adjacent the first layer, wherein an interface between the first layer and the second layer comprises a first grating, wherein the first layer has a refractive index n 1 , the second layer has a refractive index n 2 , the first grating has a peak to valley height of h, |n 1 −n 2 | multiplied by h is between about 150 nm and about 350 nm, the first grating has a first pitch in a range of about 2 microns to about 50 microns and wherein the first layer or the second layer or both the first layer and the second layer includes a plurality of particles having a size, a refractive index and a number density such that when the optical stack is illuminated with a laser light having a wavelength of about 532 nm, a diffraction pattern is produced including: a central diffraction peak having an intensity I 0 ; a nearest neighbor diffraction peak located a distance d from the central diffraction peak; and an intensity distribution including: an intensity I mid at a point halfway between the central diffraction peak and the nearest neighbor diffraction peak; an intensity I 2d at a point a distance 2d from the central diffraction peak, wherein I mid is greater than about 0.01 times I 0 and I 2d is less than about 0.001 times I 0 . 2. The optical stack of claim 1 , wherein the first grating is a one-directional grating. 3. The optical stack of claim 1 , wherein the first grating is a two-directional grating. 4. The optical stack of claim 1 , wherein I mid is greater than about 0.1 times I 0 . 5. The optical stack of claim 1 , wherein the first layer includes an optically clear adhesive. 6. The optical stack of claim 1 , wherein the first layer includes a polymer or a polymer composite. 7. The optical stack of claim 1 , wherein the second layer includes an optically clear adhesive. 8. The optical stack of claim 1 , wherein the second layer includes a polymer or polymer composite. 9. The optical stack of claim 1 further comprising a third layer adjacent the second layer opposite the first layer. 10. The optical stack of claim 9 , wherein the third layer includes a polymer or a polymer composite or an optically clear adhesive. 11. The optical stack of claim 9 , wherein an interface between the second layer and the third layer comprises a second grating. 12. The optical stack of claim 11 , wherein the first grating is a first one-directional grating extending substantially along a first direction and the second grating is a second one-directional grating extending substantially along a second direction different from the first direction. 13. The optical stack of claim 1 , wherein the plurality of particles have a mean diameter in a range of about 0.5 microns to about 30 microns. 14. The optical stack of claim 1 , wherein an absolute value of a refractive index difference between particles in the plurality of particles and a medium in which they are located is in a range of about 0.001 to about 0.1. 15. The optical stack of claim 1 , further comprising an anti-glare layer proximate the first layer opposite the second layer. 16. The optical stack of claim 1 , wherein the first layer further includes an outer major surface opposite the second layer, wherein the outer major surface includes anti-glare features. 17. The optical stack of claim 1 , wherein the plurality of particles are substantially monodispersed. 18. A display comprising the optical stack of claim 1 , wherein the display comprises a plurality of pixels and the optical stack is positioned proximate the plurality of pixels such that when a first pixel of the plurality of pixels having a first color is illuminated and viewed through the optical stack, a plurality of secondary images are produced, each secondary image having a lateral displacement from the first pixel, the first pixel having a plurality of primary neighbor pixels having the first color and a plurality of secondary neighbor pixels having the first color, wherein the lateral displacement of each secondary image is such that each secondary image overlaps with the plurality of primary neighbor pixels or overlaps with a space between the first pixel and the plurality of primary neighbor pixels, and wherein there is substantially no overlap of the plurality of secondary images with the secondary neighbor pixels. 19. A display comprising the optical stack of claim 1 , wherein the display comprises a plurality of pixels and the optical stack is positioned proximate the plurality of pixels such that the first grating is at a distance Z from a plane containing the plurality of pixels, the plurality of pixels have a first pitch P, the plurality of particles are substantially monodispersed and have a diameter D, wherein D is in a range of about 0.7 to about 2.5 times Z divided by P in microns.
by means of dispersed particles · CPC title
in an overlapping or superposed manner · CPC title
correcting geometrical aberrations · CPC title
having plural diffractive elements positioned sequentially along the optical path · CPC title
structurally combined with one or more further optical elements, e.g. lenses, mirrors, prisms or other diffraction gratings (G02B5/189 takes precedence) · CPC title
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