Method of producing ultra-low density fiber composite materials

Patent metadata

Field	Value
Publication number	US-9994712-B2
Application number	US-201415146942-A
Country	US
Kind code	B2
Filing date	Nov 5, 2014
Priority date	Nov 5, 2013
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

A method of producing ultra-low density fiber composite (ULDC) foam materials using natural fibers with gas injection through liquid foaming is disclosed, wherein in a particular embodiment includes also cellulose filaments. The method includes a continuous overflow foaming process and a novel apparatus to produce the ULDC materials. The disclosed ULDC composite foam produced includes moisture, mold, decay and fire resistant properties which can be used for building thermal and acoustic insulations, protection packaging, air filter products, hygiene products. The apparatus comprise a vessel, counter rotating dual impellor, a plurality of baffles and gas injection that produce.

First claim

The invention claimed is:

1. A method for producing a natural fiber ultra-low density composite (ULDC) foam, the method comprising the steps of:
feeding a fiber suspension and at least one additive into a continuous overflow apparatus;
disintegrating the fiber in the fiber suspension;
sparging gas into the apparatus from the base;
agitating the suspension and the at least one additive to produce the foam; and
discharging the foam through an outlet by overflow.

2. The method of claim 1 , wherein the suspension has 0.1-30% by weight fiber consistency.

3. The method of claim 1 , wherein the foam has a dry weight based density between 10 kg/m 3 to 150 kg/m 3 .

4. The method of claim 1 , further comprising drainage and drying of the discharged foam from the apparatus to produce a ULDC foam mat.

5. The method of claim 4 , wherein the ULDC mat is dried to reduce moisture content in the mat to less than 15% by weight moisture as a percentage of the total mat.

6. The method of claim 1 , wherein cellulose filament (CF) is fed to the apparatus.

7. The method of claim 1 , comprising adding an inorganic component into the apparatus.

8. The method of claim 1 , wherein the at least one additive is an adhesive, an adhesive hardener, a sizing agent, a mold resistant compound, a fiber decay resistant compound, a fire resistant compound, a smoke resistant compound, a foaming agent, or a combinations thereof.

9. The method of claim 8 , wherein the adhesive is polyvinyl alcohol (PVA), poly(vinyl acetate) (PVAc), or a combination thereof; the sizing agent is alkyketene dimer (AKD) or any other chemicals can do the sizing function; the inorganic component is zinc borate, cupric carbonate (CuCO3), disodium octaborate, cupric sulfate (CuSO4), boric acid, perlite, silicon dioxide (SiO2), potassium sulfate (K2SO4), or a combination thereof; and/or the foaming agent is sodium dodecyl sulphate (SDS) or/and other surfactants.

10. The method of claim 1 , wherein said fiber suspension comprises wood pulp.

11. A natural fiber ultra-low density composite (ULDC) foam comprising:
a natural fiber,
cellulose filament (CF); and
a foaming agent,
wherein the foam has a density from 10 kg/m 3 to 150 kg/m 3 with open cell foam structure; and wherein the CF comprises lengths of 300-350 μm.

12. The foam of claim 11 , further comprising nanofilament.

13. The foam of claim 11 , wherein the CF is from wood pulp or plant pulp.

14. The nanofilament of claim 12 , wherein the nanofilament is from wood pulp or plant pulp.

15. The foam of claim 11 , further comprising at least one additive.

16. The foam of claims 15 , wherein the at least one additive is an adhesive, an adhesive hardener, a sizing agent, a mold resistant compound, a fiber decay resistant compound, a fire resistant compound, a smoke resistant compound, a foaming agent, or a combinations thereof.

17. A method for producing a natural fiber ultra-low density composite (ULDC) foam, the method comprising the steps of:
mixing pulp and at least one additive to produce a foamable pulp;
adding water to the foamable pulp producing a fiber suspension;
feeding the fiber suspension to an apparatus consisting of a refiner;
sparging gas into the refiner;
mixing the fiber suspension to produce the foam; and
discharging the foam through an outlet by overflow.

18. The method of claim 1 , wherein the apparatus is a counter-rotating dual rotor tank, a Lamort pulper, a helico pulper, a refiner or a paper mill pulping tank.

Assignees

• Fpinnovations

Inventors

• Cai Xiaolin
• Deng Xixian (James)
• Dery Nicolas
• Lebel Sebastien
• Brunette Gilles
• Dorris Gilles Marcel
• Ben Yuxia
• Ricard Michelle
• Zhang Yaolin Zhang
• Yang Dian-Qing
• Sacciadis George

Classifications

• C08J2333/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title

• C08J9/06

  by a chemical blowing agent · CPC title

• C08J2431/04

  Homopolymers or copolymers of vinyl acetate · CPC title

• D21F11/002

  by using a foamed suspension · CPC title

• C08L33/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title