Method for producing thermoplastic resin composition, thermoplastic resin composition and copier/printer exterior part

Patent metadata

Field	Value
Publication number	US-9994708-B2
Application number	US-201615064100-A
Country	US
Kind code	B2
Filing date	Mar 8, 2016
Priority date	Mar 27, 2015
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

A method for producing a thermoplastic resin composition includes melt-blending 50 to 80 parts by mass of a crystalline polyester resin and 20 to 50 parts by mass of an amorphous polyester resin with an extruder, thereby producing a first polyester resin compound. The method further includes melt-blending 90 to 99 parts by mass of the crystalline polyester resin and 1 to 10 parts by mass of a styrene-acrylonitrile-glycidyl methacrylate terpolymer with the extruder or a different extruder, thereby producing a second polyester resin compound. The method further includes compounding 1 to 10 parts by mass of the first polyester resin compound, 1 to 10 parts by mass of the second polyester resin compound, and respective predetermined amounts of a polycarbonate resin, a flame retardant, an antidrip agent, an antioxidant, a lubricant and a toughening agent.

First claim

What is claimed is:

1. A method for producing a thermoplastic resin composition, the method comprising:
melt-blending 50 to 80 parts by mass of a crystalline polyester resin and 20 to 50 parts by mass of an amorphous polyester resin with an extruder, thereby producing a first polyester resin compound;
melt-blending 90 to 99 parts by mass of the crystalline polyester resin and 1 to 10 parts by mass of a styrene-acrylonitrile-glycidyl methacrylate terpolymer with the extruder used for producing the first polyester resin compound or a different extruder, thereby producing a second polyester resin compound; and
compounding 1 to 10 parts by mass of the first polyester resin compound, 1 to 10 parts by mass of the second polyester resin compound, 10 to 90 parts by mass of a polycarbonate resin, 1 to 40 parts by mass of a flame retardant, 0.1 to 1 parts by mass of an antidrip agent, 0.1 to 1 parts by mass of an antioxidant, 0.1 to 2 parts by mass of a lubricant and 1 to 20 parts by mass of a toughening agent.

2. The method according to claim 1 , wherein a heat discharge in a DSC melting curve of the first polyester resin compound to a heat discharge in a DSC melting curve of the crystalline polyester resin is 70% or less.

3. The method according to claim 1 , wherein the crystalline polyester resin is at least one of polyethylene terephthalate and polybutylene terephthalate.

4. The method according to claim 1 , wherein the amorphous polyester resin is at least one of PETG resin, PCTG resin and PCTA resin,
the PETG resin is a copolymer resin having terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol as monomer components, wherein an amount of the 1,4-cyclohexanedimethanol is 0.0001 mol % or more and less than 50 mol % based on a total amount of the ethylene glycol and the 1,4-cyclohexanedimethanol,
the PTCG resin is a copolymer resin having terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol as monomer components, wherein an amount of the 1,4-cyclohexanedimethanol is 50 mol % or more and 100 mol % or less based on a total amount of the ethylene glycol and the 1,4-cyclohexanedimethanol, and
the PCTA resin is a copolymer resin having terephthalic acid, isophthalic acid, and 1,4-cyclohexanedimethanol.

5. The method according to claim 1 , wherein the polycarbonate resin has a weight average molecular weight of 20,000 to 70,000.

6. The method according to claim 1 , wherein in the styrene-acrylonitrile-glycidyl methacrylate terpolymer, a content of glycidyl methacrylate is 1 to 5 mass %, and a content of acrylonitrile is 20 to 33 mass %.

7. A thermoplastic resin composition produced by the method according to claim 1 .

8. A copier/printer exterior part comprising the thermoplastic resin composition according to claim 7 .

9. The method according to claim 1 , wherein the compounding step forms a sea island structure having a sea phase comprising the polycarbonate and an island phase comprising the crystalline polyester resin, and the island phase is dispersed in the sea phase.

Assignees

• Konica Minolta Inc
• Shanghai Kumho Sunny Plastics Co Ltd

Inventors

• Mamino Masashi
• Miyazaki Keita
• Kitani Ryuji
• Xin Minqi
• Luo Minghua
• Li Qiang
• Li Wenqiang
• Gao Lei

Classifications

• B29B7/566

  provided with means to take material away from a set of rollers and to reconduct it to the same set; provided with endless belts, e.g. which can be in or out of cooperation with at least one of the rollers · CPC title

• B29B7/568

  with consecutive sets of rollers or a train of rollers · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L55/02

  ABS [Acrylonitrile-Butadiene-Styrene] polymers · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title