Macromer and process for making polymer polyols

Patent metadata

Field	Value
Publication number	US-9994701-B2
Application number	US-201314429154-A
Country	US
Kind code	B2
Filing date	Sep 23, 2013
Priority date	Oct 5, 2012
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

Polymer polyols are made by polymerizing an ethylenically unsaturated monomer in a continuous polyol phase. The polymerization is stabilized with a macromer or a pre-formed polymer made by polymerizing or copolymerizing the macromer. The macromer is a random polymer of propylene oxide and ethylene oxide in defined ratios, which also contains polymerization carbon-carbon double or triple bond. Polymer polyols made in the process exhibit little viscosity rise when blended with water. Flexible polyurethane foam made from the polymer polyol exhibits excellent hardness, have good surface characteristics and, when pigmented, exhibit good, uniform coloration.

First claim

What is claimed is:

1. A polyurethane foam which is produced by reacting a polymer polyol with an organic polyisocyanate in the presence of a blowing agent, wherein the polymer polyol comprises a continuous polyol phase, a disperse phase of polymer particles, and 1.5 to 15%, based on the weight of the disperse phase of polymer particles, of a stabilizer, wherein the stabilizer includes a mixture or dispersion of a macromer in a carrier, the macromer being a random copolymer prepared by alkoxylating sorbitol with an alkylene oxide mixture that is 88.5% by weight propylene oxide and 11.5% by weight ethylene oxide, said random copolymer is capped with 1-2 isopropenyl-α,α-dimethylbenzylisocyanate groups per molecule, the macromer having a number average molecular weight of 10,000 to 15,000, and wherein the carrier is residual uncapped random copolymer which has not been capped with isopropenyl-α,α-dimethylbenzylisocyanate.

2. The polyurethane foam of claim 1 which is a flexible polyurethane foam, and the blowing agent is water or a mixture of water and a physical blowing agent.

3. The polyurethane foam of claim 2 , which has a density of 14 to 20 kg/m 3 .

4. The polyurethane foam of claim 2 , which further contains a pigment.

Assignees

• Dow Global Technologies Llc

Inventors

• Borella Ricco B
• Claessens Sven
• Masy Jean-Paul
• De Loos Stijn

Classifications

• C08J2425/12

  with unsaturated nitriles · CPC title

• C08G18/4072

  Mixtures of compounds of group C08G18/63 with other macromolecular compounds · CPC title

• C08G2101/0083

  Chemistry & Metallurgy · mapped topic

• C08L25/12 Primary

  with unsaturated nitriles · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title