Polymers with improved processability for pipe applications

Patent metadata

Field	Value
Publication number	US-9994659-B2
Application number	US-201715792271-A
Country	US
Kind code	B2
Filing date	Oct 24, 2017
Priority date	Oct 24, 2014
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

A crosslinked metallocene-catalyzed polyethylene copolymer having a higher molecular weight (HMW) component and lower molecular weight (LMW) component wherein the HMW component is present in an amount of from about 10 wt. % to about 30 wt. % and wherein the LMW component is present in an amount of from about 70 wt. % to about 90 wt. %.

First claim

What is claimed is:

1. A polyethylene copolymer composition comprising a base resin and a peroxide modifier, wherein the base resin comprises a bimodal metallocene-catalyzed polyethylene copolymer having a higher molecular weight (HMW) component and lower molecular weight (LMW) component; wherein the HMW component is present in an amount of from 10 wt. % to 30 wt. %; wherein the LMW component is present in an amount of from 70 wt. % to 90 wt. %; wherein the bimodal metallocene-catalyzed polyethylene copolymer has a density of from 0.925 g/cc to 0.945 g/cc, when tested in accordance with ASTM D1505; wherein the bimodal metallocene-catalyzed polyethylene copolymer has gel present in an amount of less than 25/sq. ft., wherein the gels have a size greater than 200 microns; and wherein the peroxide modifier is present in the polyethylene copolymer in an amount of from 25 ppm to 400 ppm, based on the total weight of the base resin.

2. The polyethylene copolymer composition of claim 1 , wherein the peroxide modifier comprises 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane; 1,1-di(tert-butylperoxy)cyclohexane; 1,1-di(tert-amylperoxy)cyclohexane; 1,1-di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane; tert-butylperoxy 2-ethylhexyl carbonate; di-2-ethylhexyl peroxydicarbonate; tert-amyl peroxypivalate; tert-butyl peroxypivalate; di-(3,5,5-trimethylhexanoyl) peroxide; dilauroylperoxide; didecanoyl peroxide; 1,1,3,3-tetramethylbutyl-peroxy-2-ethyl hexanoate; dibenzoyl peroxide; 2,5-dimethyl-2,5-di(2-ethylhexanoyl peroxy)hexane; tert-amyl peroxy-2-ethylhexanoate; tert-butyl peroxy-2-ethylhexanoate; tert-butyl peroxy isobutyrate; OO-t-amyl-O-(2-ethylhexyl monoperoxy-carbonate); OO-t-butyl O-isopropyl monoperoxy-carbonate; OO-t-butyl-O-(2-ethylhexyl) monoperoxy-carbonate; butyl 4,4-di(t-butylperoxy)valerate; ethyl 3,3-di-(t-butylperoxy)butyrate; or combinations thereof.

3. The polyethylene copolymer composition of claim 1 , wherein the HMW component is present in the bimodal metallocene-catalyzed polyethylene copolymer in an amount of from 15 wt. % to 25 wt. %; and wherein the LMW component is present in the bimodal metallocene-catalyzed polyethylene copolymer in an amount of from 75 wt. % to 85 wt. %.

4. The polyethylene copolymer composition of claim 1 , wherein the bimodal metallocene-catalyzed polyethylene copolymer has a high load melt index of from 6 g/10 min to 25 g/0 min when tested in accordance with ASTM D1238 under a force of 21.6 kg.

5. The polyethylene copolymer composition of claim 1 , wherein the bimodal metallocene-catalyzed polyethylene copolymer has an oxidative induction temperature of greater than 220° C. when tested in accordance with ASTM D3895.

6. The polyethylene copolymer composition of claim 1 , wherein the bimodal metallocene-catalyzed polyethylene copolymer has a tensile natural draw ratio of from 380% to 500% when tested in accordance with ASTM D638.

7. A crosslinked metallocene-catalyzed polyethylene copolymer having a higher molecular weight (HMW) component and lower molecular weight (LMW) component; wherein the HMW component is present in an amount of from 10 wt. % to 30 wt. %; wherein the LMW component is present in an amount of from 70 wt. % to 90 wt. %; wherein the copolymer has gels present in an amount of less than 300/sq. ft., wherein the gels have a size greater than 200 microns; wherein the copolymer has a density of from 0.925 g/cc to 0.945 g/cc, when tested in accordance with ASTM D1505; and wherein the copolymer has an η0 (eta_0) that is increased by equal to or greater than 25% when compared to an η0 (eta_0) of a base resin prior to treatment with a peroxide modifier, and wherein the base resin is treated with the peroxide modifier to produce the crosslinked metallocene-catalyzed polyethylene copolymer.

8. The copolymer of claim 7 having an η0 (eta_0) that is increased by from 50% to 350% when compared to an η0 (eta_0) of a base resin prior to treatment with a peroxide modifier, and wherein the base resin is treated with the peroxide modifier to produce the crosslinked metallocene-catalyzed polyethylene copolymer.

9. The copolymer of claim 7 having a melt temperature that is within 5° C. of a melt temperature of a base resin prior to treatment with a peroxide modifier, and wherein the base resin is treated with the peroxide modifier to produce the crosslinked metallocene-catalyzed polyethylene copolymer.

10. The copolymer of claim 7 which when tested in accordance with ASTM D1238 under a force of 21.6 kg has a high load melt index that is decreased by less than 10% when compared to a high load melt index of a base resin prior to treatment with a peroxide modifier, and wherein the base resin is treated with the peroxide modifier to produce the crosslinked metallocene-catalyzed polyethylene copolymer.

11. The copolymer of claim 7 which when tested in accordance with ASTM D1238 under a force of 21.6 kg has a high load melt index of from 6 g/10 min to 25 g/10 min; and which when tested in accordance with ASTM D1238 under a force of 2.16 kg has a melt index of from 0.2 g/10 min to 0.8 g/10 min.

12. The copolymer of claim 7 having a N_100 that is increased by at least 2% when compared to a N_100 of a base resin prior to treatment with a peroxide modifier, and wherein the base resin is treated with the peroxide modifier to produce the crosslinked metallocene-catalyzed polyethylene copolymer.

13. A pipe formed from the copolymer of claim 7 .

14. The pipe of claim 13 , wherein the copolymer of claim 7 comprises a pre-pigmented resin.

15. The pipe of claim 13 , wherein the copolymer of claim 7 is contacted with a color pigment to form the pipe.

16. The pipe of claim 15 , wherein the color pigment comprises carbon black, and wherein the carbon black is present in the pipe in an amount of less than 2.5 wt. %, based on the weight of the pipe.

17. The pipe of claim 15 , wherein the pipe has a wall thickness of equal to or greater than 0.18 inches (4.6 mm).

18. The pipe of claim 13 , wherein the pipe has a diameter of equal to or greater than 8 inches; wherein the pipe is an extruded pipe; wherein the pipe displays an increase in η0 (eta_0) when compared to an η0 (eta_0) of a pipe formed from a base resin prior to treatment with a peroxide modifier; and wherein the increase in η0 (eta_0) improves the slump resistance in the extruded pipe.

19. The pipe of claim 13 , wherein the pipe has a diameter of equal to or greater than 8 inches; wherein the pipe is an extruded pipe; wherein the pipe displays an increase in η0 (eta_0) of equal to or greater than 50% when compared to an η0 (eta_0) of a pipe formed from a base resin prior to treatment with a peroxide modifier; and wherein the increase in η0 (eta_0) improves the slump resistance in the extruded pipe.

20. The pipe of claim 13 , wherein the pipe has a diameter of equal to or greater than 8 inches; wherein the pipe is an extruded pipe; wherein the pipe displays an increase in η0 (eta_0) of equal to or greater than 150% when compared to an η0 (eta_0) of a pipe formed from a base resin prior to treatment with a peroxide modifier; and wherein the increase in η0 (eta_0) improves the slump resistance in the extruded pipe.

21. The pipe of claim 13 , wherein the pipe has a diameter of equal to or greater than 8 inches; wherein the pipe is an extruded pipe; wherein the pipe displays an increase in η0 (eta_0) of from 60% to 450% when compared to an η0 (eta_0) of a pipe formed from a base resin prior to treatment with a peroxide modifier; and wherein the increase in η

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Rohatgi Vivek
• Inn Yongwoo
• Sukhadia Ashish M
• Yang Qing
• Deslauriers Paul J

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title

• C08J3/24

  Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/02

  Ethene · CPC title