Multi-layer cast film

Patent metadata

Field	Value
Publication number	US-9994003-B2
Application number	US-201214128100-A
Country	US
Kind code	B2
Filing date	Jun 19, 2012
Priority date	Jun 27, 2011
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

A multi-layer polymer film comprising a core layer and a sealing layer, said sealing layer comprises a propylene copolymer composition, said propylene copolymer composition—has a comonomer content in the range of 3.0 to 8.0 wt.-%, the comonomers are C 5 to C 12 α-olefins, —comprises a polypropylene (A) and a polypropylene (B) in the weight ratio [(A)/(B)] of 20/80 to 80/20, wherein—said polypropylene (A) has a comonomer content of equal or below 4.0 wt.-%, the comonomers are C 5 to C 12 α-olefins, and—said propylene copolymer (B) has a comonomer content of 4.0 to 20.0 wt.-%, the comonomers are C 5 to C 12 α-olefins.

First claim

The invention claimed is:

1. A multi-layer polymer film comprising:
(a) a core layer (CL) being selected from the group consisting of polyvinyl alcohols, polyacrylates, polyamides, poly(ethylene terephthalate), polyolefins (PO) and mixtures thereof, and
(b) a sealing layer (SL), said sealing layer (SL) comprises a propylene copolymer composition (P), said propylene copolymer composition (P);
(c1) has a comonomer content in the range 3.0 to 8.0 wt. %, the comonomer is C 6 α-olefin,
(c2) comprises a polypropylene (A) and a polypropylene (B) in the weight ratio [(A)/(B)] of 35/65 to 50/50, wherein
said polypropylene (A) is a propylene homopolymer (H-A) or a propylene copolymer (C-A) having a comonomer content of below 4.0 wt. %, the comonomer is C 6 α-olefin, and
said propylene copolymer (B) has a comonomer content of 4.0 to 20.0 wt. %, the comonomer is C 6 α-olefin,
(c3) fulfills the ratio
MFR( A )/MFR( P )<1.0

wherein MFR(A) is the melt flow rate MFR 2 (230° C.) [g/10 min] measured according to ISO 1133 of the polypropylene (A), MFR(P) is the melt flow rate MFR 2 (230° C.) [g/10 min] measured according to ISO 1133 of the propylene copolymer composition (P),
(c4) has a xylene soluble content (XCS) determined at 25° C. according to ISO 16152 in the range of below 16.0 wt. %
(c5) has a melting temperature Tm determined by differential scanning calorimetry (DSC) of at least 135° C.,
(c6) has a heat sealing initiation temperature (SIT) of equal or below 115° C., and
(c7) is free of any elastomeric copolymer component, and wherein the multilayer polymer film is cast and not subjected to a stretching step.

2. A multilayer polymer film according to claim 1 , wherein the multi-layer polymer film is unoriented.

3. A multi-layer polymer film according to claim 1 , wherein the sealing layer (SL) and/or the propylene copolymer composition (P) has/have:
(a) a molecular weight distribution (MWD) measured by gel permeation chromatography (GPC) of at least 2.5, and/or
(b) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 2.0 to 50.0 g/10 min.

4. A multi-layer polymer film according to claim 1 , wherein:
com (P)-com (A) is at least 1.0 wherein com (A) is the comonomer content of the polypropylene (A) given in weight percent [wt. %], com (P) is the comonomer content of the propylene copolymer composition (P) given in weight percent [wt. %].

5. A multi-layer polymer film according to claim 1 , wherein the sealing layer (SL) and/or the propylene copolymer composition (P) fulfill(s) the equation (1):
Tm −SIT≥22° C.  (1)

wherein Tm is the melting temperature of the sealing layer (SL) and/or of the propylene copolymer composition (P) determined by differential scanning calorimetry (DSC) and given in centigrade [° C.],
SIT is the heat sealing initiation temperature (SIT) given in centigrade [° C.] of the sealing layer (SL) and/or of the propylene copolymer composition (P).

6. A multi-layer polymer film according to claim 1 , wherein the polypropylene (A) of the propylene copolymer composition (P):
(a) is a propylene copolymer (C-A) with a comonomer content in the range of 0.5 to below 4.0 wt. %, and/or
(b) has a melt flow rate MFR, (230° C.) measured according to ISO 1133 of at least 1.5 g/10 min, and/or
(c) has a xylene soluble content (XCS) of below 2.5 wt. %.

7. A multi-layer polymer film according to claim 1 , wherein said core layer (CL) comprises a propylene homopolymer.

8. A multi-layer polymer film according to claim 1 , wherein said core layer (CL) is a polypropylene (PP) or a propylene homopolymer, having:
(a) a melt flow rate MFR, (230° C.) measured according to ISO 1133 in the range of 1.0 to 15.0 g/10 min, and/or
(b) a melting temperature Tm determined by differential scanning calorimetry (DSC) of at least 155° C.

9. A multi-layer polymer film according to claim 1 , wherein:
(a) core layer (CL) has a thickness in the range of 20 to 100 μm, and/or
(b) the sealing layer (SL) has a thickness in the range of 2 to 15 μm.

10. A multi-layer polymer film according to claim 1 , wherein said multi-layer polymer film comprises three layers, namely a core layer (CL), a sealing layer (SL) and at least one of (a) an outer layer (OL) being a polyolefin (PO), or (b) a further sealing layer (SL), (c) a metal layer (ML);
wherein the multi-layer polymer film has the stacking order: (a1) sealing layer (SL)-core layer (CL)-outer layer (OL); or (b1) sealing layer (SL)-core layer (CL)-sealing layer (SL); or (c1) sealing layer (SL)-core layer (CL)-a metal layer (ML).

Assignees

• Fiebig Joachim
• Reichelt Kristin
• Borealis Ag

Inventors

• Fiebig Joachim
• Reichelt Kristin

Classifications

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title

• Y10T428/2804

  Next to metal · CPC title

• B32B2439/70

  Food packaging · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• Y10T428/24975

  No layer or component greater than 5 mils thick · CPC title