Multiple layer panels having reduced levels of edge defects

Patent metadata

Field	Value
Publication number	US-9994000-B2
Application number	US-201414496677-A
Country	US
Kind code	B2
Filing date	Sep 25, 2014
Priority date	Oct 8, 2013
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

A process for producing a multilayer glass laminate panel having two glass sheets with a poly(vinyl butyral) interlayer sandwiched therebetween, the process comprising the steps of: providing two glass sheets; providing a poly(vinyl butyral) interlayer, and inserting the interlayer between the two glass sheets to produce a laminate; removing air from the produced laminate; applying heat and pressure to the laminate for a hold time, wherein the laminate is free of bubbles at the edges of the laminate. The multilayer glass laminate panel has improved optical properties, and specifically reduced levels of edge defects, such as edge bubbles in the laminate.

First claim

The invention claimed is:

1. A process for producing a multilayer glass laminate panel comprising two glass sheets with a poly(vinyl butyral) interlayer sandwiched therebetween, the process comprising the steps of:
providing two glass sheets;
providing a poly(vinyl butyral) interlayer, and inserting the interlayer between the two glass sheets to produce a laminate, wherein said interlayer comprises at least one skin layer and at least one core layer adjacent to said skin layer, wherein said core layer comprises a poly(vinyl butyral) resin comprising at least 8 weight percent and not more than 18 weight percent of residual hydroxyl groups and not more than 5 weight percent of residual ester groups;
removing air from the produced laminate;
autoclaving the produced laminate by applying heat and pressure to the produced laminate for a hold time, wherein the heat applied achieves a maximum autoclave temperature in the range of from about 110° C. to about 155° C., wherein the pressure applied achieves a maximum autoclave pressure in the range of less than 7 bars, and the hold time is in a range of from about 10 minutes to about 60 minutes,
wherein the glass laminate panel is free of bubbles at the edges of the laminate panel.

2. The process of claim 1 , wherein the maximum autoclave temperature is in the range of from about 115° C. to about 150° C.

3. The process of claim 1 , wherein the maximum autoclave temperature is in the range of from about 130° C. to about 150° C.

4. The process of claim 1 , wherein the hold time is in a range of from about 20 minutes to about 40 minutes.

5. The process of claim 1 , wherein the multilayer glass laminate panel is a windshield.

6. A process for producing a multilayer glass laminate panel comprising two glass sheets with a poly(vinyl butyral) interlayer sandwiched therebetween, the process comprising the steps of:
providing two glass sheets;
providing a multilayer poly(vinyl butyral) interlayer, and inserting the interlayer between the two glass sheets to produce a laminate;
removing air from the produced laminate;
autoclaving the produced laminate by applying heat and pressure to the produced laminate for a hold time, wherein the heat applied achieves a maximum autoclave temperature in the range of from about 110° C. to about 155° C., wherein the pressure applied achieves a maximum autoclave pressure in the range of less than 7 bars, and the hold time is in a range of from about 10 minutes to about 60 minutes,
wherein the glass laminate panel is free of bubbles at the edges of the laminate panel.

7. The process of claim 6 , wherein the maximum autoclave temperature is in the range of from about 130° C. to about 150′ C.

8. The process of claim 6 , wherein the hold time is in a range of from about 20 minutes to about 40 minutes.

9. The process of claim 1 , wherein the skin layer is a high-flow skin layer having a flow (measured as the DF135) of greater than about 0.18 mm and said skin layer has a stress relaxation at 150° C. of less than about 100 Pascals.

10. The process of claim 1 , wherein said core layer is softer than said skin layer and said core layer has a glass transition temperature of 10° C. or less.

11. The process of claim 6 , wherein said interlayer comprises at least one skin layer and at least one core layer, wherein said core layer is softer than said skin layer and said core layer has a glass transition temperature of 10° C. or less.

12. The process of claim 6 , wherein the poly(vinyl butyral) interlayer comprises a poly(vinyl butyral) resin having a molecular weight less than about 140,000 Daltons.

13. The process of claim 6 , wherein at least one layer of the poly(vinyl butyral) interlayer has a flow (measured as the DF135) of greater than about 0.18 mm and at least one layer of the poly(vinyl butyral) interlayer has a stress relaxation at 150° C. of less than about 100 Pascals.

14. A process for producing a multilayer glass laminate panel comprising two glass sheets with a poly(vinyl butyral) interlayer sandwiched therebetween, the process comprising the steps of:
providing two glass sheets;
providing a poly(vinyl butyral) interlayer, and inserting the interlayer between the two glass sheets to produce a laminate;
removing air from the produced laminate;
autoclaving the produced laminate by applying heat and pressure to the produced laminate for a hold time, wherein the heat applied achieves a maximum autoclave temperature in the range of from about 110° C. to about 155° C., wherein the pressure applied achieves a maximum autoclave pressure in the range of less than 7 bars, and the hold time is in the range of from about 10 minutes to about 60 minutes,
wherein the glass laminate panel is free of bubbles at the edges of the laminate panel.

15. The process of claim 14 , wherein the maximum autoclave temperature in the range of from about 130° C. to about 150° C. and wherein the hold time is in the range of from about 20 minutes to about 40 minutes.

16. The process of claim 14 , wherein said poly(vinyl butyral) interlayer is a single layer interlayer.

17. The process of claim 14 , wherein the multilayer glass laminate panel is a windshield.

Assignees

• Solutia Inc

Inventors

• Lu Jun
• Aw Kok Leong William
• D'Errico John Joseph

Classifications

• B32B17/10036 Primary

  comprising two outer glass sheets · CPC title

• B32B17/1055 Primary

  characterized by the resin layer, i.e. interlayer · CPC title

• Y10T428/31627

  Next to aldehyde or ketone condensation product · CPC title

• B32B17/10761

  containing vinyl acetal · CPC title

• B32B17/10871

  in combination with particular heat treatment · CPC title