Process for preparing a hydrotreating catalyst

Patent metadata

Field	Value
Publication number	US-9993809-B2
Application number	US-201415033926-A
Country	US
Kind code	B2
Filing date	Nov 4, 2014
Priority date	Nov 7, 2013
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

Process for preparing a hydrotreating catalyst comprising of from 5 wt % to 50 wt % of molybdenum, of from 0.5 wt % to 20 wt % of cobalt, and of from 0 to 5 wt % of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating a nickel containing carrier with molybdenum, cobalt and of from 1 to 60% wt of gluconic acid, based on weight of carrier, and optionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200° C., and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650° C. to obtain the calcined treated carrier.

First claim

That which is claimed is:

1. A process for preparing a hydrotreating catalyst, wherein said hydrotreating catalyst comprises from 5 wt % to 50 wt % molybdenum, from 0.5 wt % to 20 wt % cobalt, and from 0 to 5 wt % phosphorus, all based on total dry weight of said hydrotreating catalyst, which process comprises:
(a) providing a nickel-containing carrier extrudate, comprising alumina and from 0.1 to 5 wt % nickel, calculated as metal and based on said nickel-containing carrier extrudate, wherein said nickel-containing carrier extrudate is prepared by mixing said nickel with pseudo-boehmite to provide a mixture, extruding said mixture to provide an extrudate, and driving and calcining said extrudate to provide said nickel-containing carrier extrudate;
(b) treating said nickel containing carrier extrudate with a gluconic acid solution, comprising molybdenum, cobalt, phosphorus, and an amount of gluconic acid to provide from 2 to 40 wt % gluconic acid on said nickel containing carrier extrudate, to thereby provide a treated carrier;
(c) drying said treated carrier at a temperature of from 40 to 200° C. to thereby provide a treated and dried carrier; and
(d) calcining said treated and dried carrier at a temperature of from 200 to 650° C. to obtain said hydrotreating catalyst.

2. A process according to claim 1 , wherein the amount of gluconic acid in said gluconic acid solution is from 3 to 30% wt.

3. A process according to claim 1 , wherein said hydrotreating catalyst contains phosphorus in an amount from 1.5 to 3.5% wt.

4. A process according to claim 1 , in which the hydrotreating catalyst comprises from 1 wt % to 15 wt % cobalt, from 8 wt % to 40 wt % molybdenum and from 0.1 to 5 wt %.

5. A process according to claim 1 , in which the ratio of weight of gluconic acid to the total weight of cobalt and molybdenum deposited on the carrier before calcination is of from 0.1 to 5.

6. A process according to claim 1 which process further comprises:
(d) sulphiding the hydrotreating catalyst to obtain a sulphided hydrotreating catalyst.

7. A process for hydrotreating a sulphur-containing hydrocarbon feedstock which process comprises contacting the hydrocarbon feedstock at a hydrogen partial pressure from 1 to 70 bar and a temperature of from 200 to 420° C. with a catalyst obtained according to claim 6 .

Assignees

• Shell Oil Co

Inventors

• Winter Ferry
• Van Welsenes Jen Arend
• Rigutto Marcello Stefano
• Giltay Patricia Johanna Anne Maria
• Van Vlaanderen Johannes Jacobus Maria
• Azghay Ali

Classifications

• B01J37/024

  Multiple impregnation or coating · CPC title

• B01J31/04

  containing carboxylic acids or their salts {(B01J31/0277 - B01J31/0298 take precedence; multi-metal carboxylate complexes like Pd (II) acetate, i.e. Pd3 (OAc) 6 or Cr(II)acetate, i.e. Cr2(OAc)4 B01J31/2226)} · CPC title

• B01J35/0026

  Operations & Transport · mapped topic

• B01J35/1061

  Operations & Transport · mapped topic

• B01J2523/51

  Phosphorus · CPC title