Shaped porous carbon products

Patent metadata

Field	Value
Publication number	US-9993802-B2
Application number	US-201715441732-A
Country	US
Kind code	B2
Filing date	Feb 24, 2017
Priority date	Apr 29, 2014
Publication date	Jun 12, 2018
Grant date	Jun 12, 2018

Abstract

Shaped porous carbon products and processes for preparing these products are provided. The shaped porous carbon products can be used, for example, as catalyst supports and adsorbents. Catalyst compositions including these shaped porous carbon products, processes of preparing the catalyst compositions, and various processes of using the shaped porous carbon products and catalyst compositions are also provided.

First claim

What is claimed is:

1. A catalyst composition comprising a shaped porous carbon product as a catalyst support and a catalytically active component or precursor thereof, wherein the shaped porous carbon product comprises:
(a) carbon black and
(b) a carbonized binder comprising a carbonization product of a water soluble organic binder and wherein the shaped porous carbon product has a BET specific surface area from about 20 m 2 /g to about 500 m 2 /g, a mean pore diameter greater than about 5 nm, a specific pore volume greater than about 0.1 cm 3 /g, a carbon black content of at least about 35 wt. %, and a carbonized binder content from about 20 wt. % to about 50 wt. %, and
wherein the shaped porous carbon product has a radial piece crush strength greater than about 4.4 N/mm (1 lb/mm) and/or a mechanical piece crush strength greater than about 22 N (5 lbs), and wherein the shaped porous carbon product has a mean diameter of at least about 50 μm.

2. The catalyst composition of claim 1 , wherein the shaped porous carbon product has a BET specific surface area from about 20 m 2 /g to about 350 m 2 /g.

3. The catalyst composition of claim 2 , wherein the shaped porous carbon product has a mean pore diameter from about 5 nm to about 100 nm.

4. The catalyst composition of claim 3 , wherein the shaped porous carbon product has a pore size distribution such that the peak of the distribution is at a diameter greater than about 5 nm, but less than about 100 nm.

5. The catalyst composition of claim 1 , wherein the shaped porous carbon product has a specific pore volume of the pores having a diameter of 1.7 nm to 100 nm as measured by the BJH method that is from about 0.1 cm 3 /g to about 1.5 cm 3 /g.

6. The catalyst composition of claim 1 , wherein from about 35% to about 80% of the pore volume of the shaped porous carbon product, as measured by the BJH method on the basis of pores having a diameter from 1.7 nm to 100 nm, is attributable to pores having a mean pore diameter of from about 10 nm to about 50 nm.

7. The catalyst composition of claim 1 , wherein from about 50% to about 95% of the pore volume of the shaped porous carbon product, as measured by the BJH method on the basis of pores having a diameter from 1.7 nm to 100 nm, is attributable to pores having a mean pore diameter of from about 10 nm to about 100 nm.

8. The catalyst composition of claim 1 , wherein from about 0.1% to about 10% of the pore volume of the shaped porous carbon product, as measured by the BJH method on the basis of pores having a diameter from 1.7 nm to 100 nm, is attributable to pores having a mean pore diameter less than 3 nm.

9. The catalyst composition of claim 1 , wherein the shaped porous carbon product has a radial piece crush strength greater than about 4.4 N/mm (1 lb/mm) to about 88 N/mm (20 lbs/mm).

10. The catalyst composition of claim 1 , wherein the shaped porous carbon product has a mechanical piece crush strength greater than about 22 N (5 lbs) to about 88 N (20 lbs).

11. The catalyst composition of claim 1 , wherein the carbon black content of the shaped porous carbon product is from about 35 wt. % to about 80 wt. %.

12. The catalyst composition of claim 1 , wherein the shaped porous carbon product has a carbonized binder content from about 25 wt. % to about 40 wt. %.

13. The catalyst composition of claim 1 , wherein the composition exhibits a rotating drum attrition index as measured in accordance with ASTM D4058-96 such that the percent retained is greater than about 85%.

14. The catalyst composition of claim 1 , wherein the composition exhibits a horizontal agitation sieve abrasion loss of less than about 5%.

15. The catalyst composition of claim 1 , wherein the catalytically active component or precursor thereof comprises a metal.

16. The catalyst composition of claim 15 , wherein the metal is selected from the group consisting of cobalt, nickel, copper, zinc, iron, vanadium, molybdenum, manganese, barium, ruthenium, rhodium, rhenium, palladium, silver, osmium, iridium, platinum, gold, and combinations thereof.

17. The catalyst composition of claim 15 , wherein the metal comprises platinum.

18. A catalyst composition comprising a shaped porous carbon product as a catalyst support and a catalytically active component or precursor thereof, wherein the shaped porous carbon product comprises:
(a) carbon black and
(b) a carbonized binder comprising a carbonization product of a water soluble organic binder and wherein the shaped porous carbon product has a BET specific surface area from about 20 m 2 /g to about 500 m 2 /g, a mean pore diameter greater than about 5 nm, a specific pore volume greater than about 0.1 cm 3 /g, a carbon black content of at least about 35 wt. %, and a carbonized binder content from about 20 wt. % to about 50 wt. %, and
wherein the shaped porous carbon product has a radial piece crush strength greater than about 4.4 N/mm (1 lb/mm) and/or a mechanical piece crush strength greater than about 22 N (5 lbs), and wherein the binder comprises a saccharide selected from the group consisting of a monosaccharide, a disaccharide, an oligosaccharide, and combinations thereof.

19. The catalyst composition of claim 18 , wherein the binder comprises a monosaccharide.

20. The catalyst composition of claim 19 , wherein the monosaccharide is selected from the group consisting of glucose, fructose, hydrate thereof, syrup thereof, and combinations thereof.

21. The catalyst composition of claim 18 , wherein the binder further comprises a polymeric carbohydrate, derivative of a polymeric carbohydrate, or a non-carbohydrate synthetic polymer, or any combination thereof.

22. The catalyst composition of claim 21 , wherein the polymeric carbohydrate or derivative of the polymeric carbohydrate comprises a cellulosic compound.

23. The catalyst composition of claim 22 , wherein the cellulosic compound is selected from the group consisting of methylcellulose, ethylcellulose, ethylmethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylhydroxyethylcellulose, ethylhydroxyethylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, and mixtures thereof.

24. The catalyst composition of claim 21 , wherein the polymeric carbohydrate or derivative of the polymeric carbohydrate comprises a starch.

25. The catalyst composition of claim 21 , wherein the non-carbohydrate synthetic polymer is selected from the group consisting of polyacrylic acid, polyvinyl alcohols, polyvinylpyrrolidones, polyvinyl acetates, polyacrylates, polyethers, and copolymers derived therefrom.

26. The catalyst composition of claim 18 , wherein the binder comprises a saccharide selected from the group consisting of glucose, fructose, hydrates thereof and combinations thereof and a polymeric carbohydrate or derivative of the polymeric carbohydrate selected from the group consisting of hydroxyethylcellulose, methylcellulose, starch and combinations thereof.

27. The catalyst composition of claim 26 , wherein the weight ratio of (i) the saccharide to (ii) the polymeric carbohydrate or derivative of the polymeric carbohydrate is from about 5:1 to about 50:1.

28. The catalyst composition of claim 18 , wherein the catalytically active component or precursor thereof comprises a metal.

29. The catalyst composition of claim 28 , wherein the metal is selected from the group consisting of cobal

Assignees

• Archer Daniels Midland Co
• Archer Daniels Midland Co

Inventors

• Dias Eric L
• Hagemeyer Alfred
• Jiang Hong X
• Longmire James
• Shoemaker James A W
• Sokolovskii Valery
• Zhu Guang
• Murphy Vincent J
• Diamond Gary M

Classifications

• B01J37/0201

  Impregnation · CPC title

• C04B38/0615

  the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles (C04B38/0022 takes precedence) · CPC title

• B01J23/22

  Vanadium · CPC title

• C04B35/532

  containing a carbonisable binder · CPC title

• B01J37/0215

  Coating · CPC title