Positive electrode active material and preparation method thereof, positive electrode plate, secondary battery, battery module, battery pack, and electric apparatus
US-2024429384-A1 · Dec 26, 2024 · US
US9991566B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9991566-B2 |
| Application number | US-201213664210-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 30, 2012 |
| Priority date | Nov 3, 2011 |
| Publication date | Jun 5, 2018 |
| Grant date | Jun 5, 2018 |
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Provided herein is an electrode active material comprising a lithium metal oxide and an overcharge protection additive having an operating voltage higher than the operating voltage of the lithium metal oxide.
Opening claim text (preview).
The invention claimed is: 1. A positive electrode comprising a physical mixture of a first electrode active material and a second electrode active material coated onto a collector of the positive electrode; and wherein the first electrode active material comprises a lithium metal oxide, and wherein the second electrode active material comprises an overcharge protection additive having an operating voltage higher than the operating voltage of the lithium metal oxide, wherein the overcharge protection additive is a Li-rich layered oxide, a lithium oxide spinel, an olivine phosphate, and combinations thereof. 2. A positive electrode comprising a physical mixture of a first electrode active material and a second electrode active material coated onto a collector of the positive electrode; and wherein the first electrode active material comprises a lithium metal oxide, and wherein the second electrode active material comprises an overcharge protection additive having an operating voltage higher than the operating voltage of the lithium metal oxide, wherein the overcharge protection additive has the formula xLi 2 M 1 O 3 (1−x)LiM 2 O 2 , wherein: M 1 is Mn, Ti, Zr, and combinations thereof; M 2 is Mn, Ni, Co, Cr, or combinations thereof, and x is greater than 0 and smaller than 1. 3. A lithium ion battery comprising a positive electrode comprising a positive electrode active material mixture, a negative electrode comprising a negative electrode active material, and an electrolyte, the positive electrode active material mixture comprises a physical mixture of a first electrode active material and a second electrode active material, wherein the first electrode active material comprises a lithium metal oxide, and wherein the second electrode active material comprises an overcharge protection additive having an operating voltage higher than an operating voltage of the lithium metal oxide, wherein the overcharge protection additive is a Li-rich layered oxide, a lithium oxide spinel, an olivine phosphate, and combinations thereof.
against overcharge · CPC title
of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title
as mixtures · CPC title
of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title
of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title
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