Systems and methods for flexible propane recovery

Patent metadata

Field	Value
Publication number	US-9989305-B2
Application number	US-201414587842-A
Country	US
Kind code	B2
Filing date	Dec 31, 2014
Priority date	Jan 2, 2014
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

Systems and methods that utilize feed gases that are supplied in a wide range of compositions and pressure to provide highly efficient recovery of NGL products, such as propane, utilizing isenthalpic expansion, propane refrigeration, and shell and tube exchangers are described. Plants utilizing such systems and methods can be readily reconfigured between propane recovery and ethane recovery.

First claim

What is claimed is:

1. A method of processing a gas stream, comprising:
separating a feed gas stream into a first vapor stream and a first liquid stream;
combining the first vapor stream with a recycle stream and with a vapor portion of the first liquid stream to form a mixed stream;
cooling the mixed stream to produce a cooled mixed stream;
separating the cooled mixed stream into a second vapor stream and a second liquid stream;
isenthalpically expanding the second liquid stream to form an expanded liquid steam which provides at least partial cooling to the mixed steam;
isenthalpically expanding the second vapor stream to form an expanded vapor stream;
sending the expanded vapor stream to an absorber to produce a bottom stream and an overhead product;
transferring at least a portion of the expanded liquid stream and at least a portion of the bottom stream to a fractionation column;
producing a C3+ product and a fractionation column overhead product from the fractionation column;
operating the fractionation column in a propane recovery mode by recovering the C3+ product from the fractionation column; separating the first liquid stream into the vapor portion and a hydrocarbon stream; stripping the hydrocarbon stream to form a C2 rich vapor stream and a C2 depleted bottom stream; compressing the C2 rich vapor stream to produce a compressed vapor stream; and cooling the compressed vapor stream to form the recycle stream.

2. The method of claim 1 , wherein the system is operated in an ethane recovery mode to recover C2+ liquid by rerouting at least a portion of the fractionation column overhead product from the fractionation column to the bottom of the absorber.

3. The method of claim 1 , wherein the second vapor stream is expanded using a Joule-Thomson valve, and wherein the second liquid stream is expanded using a Joule-Thomson valve.

4. The method of claim 1 , wherein the fractionation column is a non-refluxed column.

5. The method of claim 1 , wherein the fractionation column is a deethanizer.

6. The method of claim 1 , wherein the fractionation column overhead product is cooled using propane refrigeration during propane recover.

7. The method of claim 1 , wherein the mixed stream is cooled using propane refrigeration.

8. The method of claim 2 , wherein the second liquid stream is a C2+ enriched liquid fraction and the second vapor stream is a C2+ depleted vapor fraction during ethane recovery operation, and the second liquid stream is a C3+ enriched liquid fraction and the second vapor stream is a C3+ depleted vapor fraction during propan recovery operation.

9. The method of claim 1 wherein the feed gas has an initial pressure of at least 100 psia, and wherein the mixed stream is cooled at a pressure between 500 psia and 1200 psia, and wherein the second vapor stream is expanded to a pressure of between 300 psig and 500 psig.

10. The method of claim 2 , further comprising a step of separately expanding the second vapor stream and the second liquid stream, wherein the second vapor stream is expanded using a Joule-Thomson valve prior to transferring the expanded vapor stream to the absorber during propane recovery, and further comprising: dividing the fractionation column overhead product into a first portion and a second portion, wherein the first portion is routed to an absorber subcooler to form a methane rich reflux to the absorber during ethane recovery operation, and wherein the second portion is the portion of the fractionation column overhead product from the fractionation column to the bottom of the absorber.

11. The method of claim 1 , wherein cooling the mixed stream is performed using a shell and tube heat exchanger.

12. The method of claim 1 , wherein the absorber and the fractionation column are operated at a pressure of between 200 psig to 500 psig.

13. The method of claim 2 , further comprising a step of cooling the fractionation column overhead product by propane refrigeration, wherein at least a portion of the fractionation column overhead product thus cooled forms at least part of a reflux of the absorber during propane recovery operation.

14. The method of claim 13 wherein the reflux has a temperature between −34° C. (−30° F.) to −57° C. (−70° F.) during propane recovery.

15. The method of claim 1 , wherein the bottom stream from the absorber is used to provide cooling to the fractionation column overhead product prior to introducing the fractionation column overhead product to the absorber.

16. The method of claim 1 , wherein a recovery of propane from the feed gas stream in the C3+ product is at least 85%.

17. The method of claim 1 , wherein a recovery of propane from the feed gas stream in the C3+ product is at least 95%.

18. A method of processing a gas stream, comprising:
separating a feed gas stream into a first vapor stream and a first liquid stream;
combining the first vapor stream with a recycle stream and with a vapor portion of the first liquid stream to form a mixed stream;
cooling the mixed stream to produce a cooled mixed stream;
separating the cooled mixed stream into a second vapor stream and a second liquid stream;
isenthalpically expanding the second liquid stream to form an expanded liquid stream which provides at least partial cooling to the mixed stream;
isenthalpically expanding the second liquid vapor stream to form an expanded vapor stream;
sending the expanded vapor stream to an absorber to produce a bottom stream and an overhead product;
transferring at least a portion of the expanded liquid stream to a fractionation column;
pumping at least a portion of the bottom stream from the absorber to the fractionation column;
producing a C3+ product and a fractionation column overhead product from the fractionation column; separating the first liquid stream into the vapor portion and a hydrocarbon stream; stripping the hydrocarbon stream to form a C2 rich vapor stream and a C2 depleted bottom stream; compressing the C2 rich vapor stream to produce a compressed vapor stream; and cooling the compressed vapor stream to form the recycle steam.

19. The method of claim 18 , wherein the fractionation column is a non-refluxed column.

20. A method of processing a gas stream, comprising
separating a feed gas stream into a first vapor stream and a first liquid stream;
combining the first vapor stream with a recycle stream and with a vapor portion of the first liquid stream to form a mixed stream;
cooling the mixed stream to produce a cooled mixed steam;
separating the cooled mixed stream into a second vapor stream and a second liquid stream;
isenthalpically expanding the second liquid stream to from an expanded liquid stream which provides at least partial cooling to the mixed stream;
isenthalpically expanding the second vapor stream to form an expanded vapor stream;
sending the expanded vapor stream to an absorber to produce a bottom stream and an overhead product;
transferring at least a portion of the expanded liquid stream and at least a portion of the bottom stream to a fractionation column;
producing a C3+ product and a fractionation column overhead product from the A fractionation column;
cooling the fractionation column overhead product through heat exchange contact with the overhead product from the absorber; separating the first liquid stream into the vapor portion and a hydrocarbon stream; stripping the hydrocarbon stream to form a C2 rich vapor stream and a C2 depleted bottom stream; compressing the C2 rich vapor stream to produce a compressed va

Assignees

• Fluor Tech Corp

Inventors

• Mak John

Classifications

• F25J2270/12

  External refrigeration with liquid vaporising loop · CPC title

• C10L2290/48

  Expanders, e.g. throttles or flash tanks · CPC title

• F25J2240/40

  Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval · CPC title

• C10L2290/46

  Compressors or pumps · CPC title

• F25J2205/04

  in the feed line, i.e. upstream of the fractionation step · CPC title