Elastomer composites, blends and methods for preparing same

Patent metadata

Field	Value
Publication number	US-9988502-B2
Application number	US-201414786628-A
Country	US
Kind code	B2
Filing date	May 19, 2014
Priority date	May 20, 2013
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

Blends of elastomer composites with unfilled or less highly filled elastomer reduces hysteresis without compromising reinforcement. Hysteresis may also be reduced by adjusting the compounding method.

First claim

What is claimed is:

1. A process for producing an elastomeric composition containing a filler, the process comprising:
preparing an elastomer composite having less than 3% moisture comprising natural rubber and a first filler loading of carbonaceous aggregated filler having an STSA of at least 120 m 2 /g, the first filler loading being greater than 60 phr, by a wet masterbatch method; and
blending the elastomer composite with a second elastomer material comprising an elastomer and optional particulate filler to produce an elastomer composite blend having a second filler loading, the second filler loading being at least about 10 phr lower than the first filler loading, wherein M300/M100 of a vulcanizate of the elastomer composite blend is at least 0.5 higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

2. The process of claim 1 , wherein the M300/M100 of the vulcanized elastomer composite blend is at least (0.017*COAN-0.7) higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

3. The process of claim 1 , wherein the elastomer in the second elastomer material is natural rubber and the vulcanized elastomer composite blend satisfies tan delta 60≤0.04 (M300/M100)−0.106.

4. The process of claim 1 , wherein the elastomer in the second elastomer material is a synthetic rubber and the vulcanized elastomer composite blend exhibits M300/M100 of at least −0.0064*STSA+6.39.

5. The process of claim 1 , further comprising vulcanizing the elastomer composite blend.

6. The process of claim 1 , wherein the wet mixing method comprises:
i) combining a first fluid comprising elastomer latex with a second fluid comprising particulate filler;
ii) causing the elastomer latex to coagulate, thereby forming masterbatch crumb; and
iii) drying the masterbatch crumb.

7. The process of claim 1 , further comprising, before blending, masticating the elastomer composite for 30-60 seconds.

8. The process of claim 7 , wherein masticating comprises mixing the elastomer composite in an internal mixer at a fill factor of 70-85% for 30 to about 60 seconds.

9. The process of claim 1 , wherein blending further includes adding a cross-linking agent to the elastomer composite, wherein the cross-linking agent and the second elastomer material are mixed with the elastomer composite simultaneously.

10. A process for producing an elastomeric composition containing a filler, the process comprising:
preparing an elastomer composite having a moisture content less than 3% comprising natural rubber and a first filler loading of carbonaceous aggregated filler, the first filler loading being greater than 60 phr, by a wet masterbatch method; and
blending the elastomer composite with a second elastomer material comprising natural rubber and optional particulate filler to produce an elastomer composite blend having a second filler loading, the second filler loading being at least about 10 phr lower than the first filler loading, wherein M300/M100 of a vulcanizate of the elastomer composite blend is at least 0.5 higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

11. The process of claim 10 , wherein the M300/M100 of the vulcanized elastomer composite blend is at least (0.017*COAN-0.7) higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

12. The process of claim 10 , wherein the elastomer in the second elastomer material is natural rubber and the vulcanized elastomer composite blend satisfies tan delta 60≤0.04 (M300/M100)−0.106.

13. The process of claim 10 , further comprising vulcanizing the elastomer composite blend.

14. A process for producing an elastomeric composition containing a filler, the process comprising:
providing an elastomer composite having less than 3% moisture comprising natural rubber and a first filler loading of carbonaceous aggregated filler having an STSA of at least 120 m 2 /g, the first filler loading being greater than 60 phr, by a wet masterbatch method; and
blending the elastomer composite with a second elastomer material comprising an elastomer and optional particulate filler to produce an elastomer composite blend having a second filler loading, the second filler loading being at least about 10 phr lower than the first filler loading, wherein M300/M100 of a vulcanizate of the elastomer composite blend is at least 0.5 higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

15. The process of claim 14 , wherein the M300/M100 of the vulcanized elastomer composite blend is at least (0.017*COAN-0.7) higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

16. The process of claim 14 , wherein the elastomer in the second elastomer material is natural rubber and the vulcanized elastomer composite blend satisfies tan delta 60≤0.04 (M300/M100)−0.106.

17. The process of claim 14 , wherein the elastomer in the second elastomer material is a synthetic rubber and the vulcanized elastomer composite blend exhibits M300/M100 of at least −0.0064*STSA+6.39.

18. A process for producing an elastomeric composition containing a filler, the process comprising:
providing an elastomer composite having a moisture content less than 3% comprising natural rubber and a first filler loading of carbonaceous aggregated filler, the first filler loading being greater than 60 phr, by a wet masterbatch method; and
blending the elastomer composite with a second elastomer material comprising natural rubber and optional particulate filler to produce an elastomer composite blend having a second filler loading, the second filler loading being at least about 10 phr lower than the first filler loading, wherein M300/M100 of a vulcanizate of the elastomer composite blend is at least 0.5 higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

19. The process of claim 18 , wherein the M300/M100 of the vulcanized elastomer composite blend is at least (0.017*COAN-0.7) higher than M300/M100 for a vulcanized elastomer composite of the same composition but prepared according to CTV Comparative Method 1.

20. The process of claim 18 , wherein the elastomer in the second elastomer material is natural rubber and the vulcanized elastomer composite blend satisfies tan delta 60≤0.04 (M300/M100)−0.106.

Assignees

• Cabot Corp

Inventors

• Adler Gerald D
• Prakash Anand
• Dickinson Ralph E
• Tirumala Vijay R

Classifications

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J3/226

  using a polymer as a carrier · CPC title

• C08K3/06

  Sulfur · CPC title

• B60C1/0025

  Compositions of the sidewalls · CPC title

• C08K2003/2296

  of zinc · CPC title