Functionalized elastomer via allylboration
US-9580532-B1 · Feb 28, 2017 · US
US9988479B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9988479-B2 |
| Application number | US-201514973770-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 18, 2015 |
| Priority date | Dec 19, 2014 |
| Publication date | Jun 5, 2018 |
| Grant date | Jun 5, 2018 |
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The present invention is directed to a copolymer of 1,3-butadiene or isoprene and a monomer of formula I or V wherein R 1 is a covalent bond, phenylene, a linear or branched alkane diyl group containing 1 to 10 carbon atoms, or a combination of one or more phenylene groups and one or more linear or branched alkane diyl groups containing 1 to 10 carbon atoms; R 2 and R 3 are independently linear or branched alkyl groups containing 1 to 10 carbon atoms; or R 5 is a linear or branched alkane diyl group containing 1 to 20 carbon atoms, or a bridging aromatic group. The invention is further directed to a rubber composition including the copolymer, and a pneumatic tire containing the rubber composition. The invention is further directed to a method of making such a copolymer.
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What is claimed is: 1. A copolymer of a first monomer selected from the group consisting of 1,3-butadiene and isoprene, and a second monomer 2. The copolymer of claim 1 , comprising from 0.1 to 40 percent by weight of units derived from the second monomer, based on the weight of the copolymer. 3. The copolymer of claim 1 , comprising from 0.5 to 20 percent by weight of units derived from the second monomer based on the weight of the copolymer. 4. The copolymer of claim 1 , comprising from 1 to 5 percent by weight of units derived from the second monomer based on the weight of the copolymer. 5. A rubber composition comprising the copolymer of claim 1 . 6. A pneumatic tire comprising the rubber composition of claim 5 . 7. A method of making a copolymer, comprising the step of polymerizing a monomer selected from the group consisting of 1,3-butadiene and isoprene and the monomer 8. The method of claim 7 wherein the polymerization is done in the presence of a catalyst of formula II where BAr F 4 − is tetrakis(3,5-bis(trifluoromethyl)phenyl) borate.
Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title
Isoprene · CPC title
Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title
Compositions of the tread · CPC title
Butadiene · CPC title
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