Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
US-2015214555-A1 · Jul 30, 2015 · US
US9988312B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9988312-B2 |
| Application number | US-201715460570-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 16, 2017 |
| Priority date | Mar 22, 2016 |
| Publication date | Jun 5, 2018 |
| Grant date | Jun 5, 2018 |
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At least partial substitution of zirconium by hafnium in ion-conducting zirconium-based ceramics provides enhanced chemical stability in alkaline and acid environments.
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We claim: 1. An ion conducting ceramic comprising Na 1+x HF 2 P 3-x Si x O 12 . 2. The ion-conducting ceramic of claim 1 , wherein x=0. 3. A protective layer comprising an ion-conducting zirconium-based ceramic, wherein the zirconium is at least partially substituted by hafnium, that is coated onto another ion-conducting material comprising Na 3 Zr 2 PSi 2 O 12 that is susceptible to a different mechanism of degradation than the protective layer. 4. A protective layer comprising an ion-conducting zirconium-based ceramic, wherein the zirconium is at least partially substituted by hafnium, that is coated onto another ion-conducting material comprising Na 3 Zr 2 P 3 O 12 that is susceptible to a different mechanism of degradation than the protective layer. 5. A protective layer comprising an ion-conducting zirconium-based ceramic, wherein the zirconium is at least partially substituted by hafnium, that is coated onto another ion-conducting material comprising Na 1+x Zr 2 P 3-x Si x O 12 , wherein Zr is at least partially substituted by Hf, that is susceptible to a different mechanism of degradation than the protective layer. 6. The protective layer of claim 5 , wherein x=0. 7. A protective layer comprising Na 1+x Hf 2 P 3-x Si x O 12 that is coated onto another ion-conducting material that is susceptible to a different mechanism of degradation than the protective layer. 8. The protective layer of claim 7 , wherein x=0. 9. The protective layer of claim 7 , wherein the other ion-conducting material comprises Na 3 Zr 2 PSi 2 O 12 . 10. The protective layer of claim 7 , wherein the other ion-conducting material comprises Na 3 Zr 2 P 3 O 12 .
Compounds containing zirconium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title
based on phosphates {, e.g. hydroxyapatite} · CPC title
Lanthanum oxide or oxide-forming salts thereof · CPC title
based on silicates other than clay {(zircon C04B35/48)} · CPC title
Solid solutions · CPC title
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