Method and device for the treatment of a gas stream, in particular for the treatment of a natural gas stream

Patent metadata

Field	Value
Publication number	US-9987587-B2
Application number	US-201414767320-A
Country	US
Kind code	B2
Filing date	Feb 3, 2014
Priority date	Feb 19, 2013
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

A method for the treatment of a gas stream, wherein before the combustion of the gas stream, hydrogen sulfide is separated out of the gas stream in a first absorber by an absorption medium, the treated gas stream purified of hydrogen sulfide is burnt in a combustion apparatus, the carbon dioxide contained in the exhaust gas of the burnt gas stream after combustion is separated in a second absorber by an absorption medium, and the separated hydrogen sulfide and carbon dioxide are separated in at least one desorber from the absorption medium for the regeneration of the latter. The same absorption medium separates the hydrogen sulfide out of the gas stream and the carbon dioxide out of the exhaust gas. A corresponding device for the treatment of a gas stream has a first absorber and a second absorber flow-connected to one another for the exchange of absorption medium.

First claim

The invention claimed is:

1. A method for the treatment of a gas stream, the method comprising:
before the combustion of the gas stream, separating out hydrogen sulfide from the gas stream in a first absorber by an absorption medium,
burning the treated gas stream purified of hydrogen sulfide in a combustion apparatus,
separating carbon dioxide contained in the exhaust gas of the burnt gas stream in a second absorber by the absorption medium, and
separating the separated hydrogen sulfide and the separated carbon dioxide from the absorption medium in at least one desorber for the regeneration of the absorption medium,
wherein the same absorption medium is used for separating the hydrogen sulfide out of the gas stream and for separating the carbon dioxide out of the exhaust gas, the absorption medium containing dioxide flowing out of the second absorber via a discharge line of the second absorber directly into a delivery line of the first absorber.

2. The method as claimed in claim 1 ,
wherein an amine-containing absorption medium is used.

3. The method as claimed in claim 1 ,
wherein an amino acid salt is used as the absorption medium.

4. The method as claimed in claim 1 ,
wherein the desorption of the hydrogen sulfide and the desorption of the carbon dioxide out of the absorption medium takes place in a common desorber.

5. The method as claimed in claim 1 ,
wherein the desorption of the hydrogen sulfide and the desorption of the carbon dioxide out of the absorption medium takes place in each case in a separate desorber.

6. The method as claimed in claim 1 ,
wherein the gas stream comprises a natural gas stream.

7. A device for the treatment of a gas stream, comprising:
a first absorber for separating hydrogen sulfide out of the gas stream by an absorption medium,
a combustion apparatus, following the first absorber, for the combustion of the gas stream purified of hydrogen sulfide,
a second absorber, following the combustion apparatus, for separating carbon dioxide out of the exhaust gas of the combustion apparatus by the absorption medium, and
at least one desorber for the desorption of separated hydrogen sulfide and of separated carbon dioxide out of the absorption medium,
wherein the first absorber comprises a delivery line and a discharge line for the absorption medium, and the delivery line of the first absorber is flow-connected to a discharge line of the second absorber for the exchange of the absorption medium.

8. The device as claimed in claim 7 ,
wherein the first absorber is flow-connected via its discharge line to the delivery line of a first desorber.

9. The device as claimed in claim 8 ,
wherein the first desorber is flow-connected to the delivery line of the second absorber via a recirculation line.

10. The device as claimed in claim 8 ,
wherein the first desorber has connected to it a discharge line which issues in a treatment apparatus.

11. The device as claimed in claim 7 , further comprising:
a branch line connected to the discharge line of the second absorber and flow-connected to the delivery line of a second desorber.

12. The device as claimed in claim 11 , further comprising:
a reboiler connected to the first desorber and/or to the second desorber.

13. The device as claimed in claim 11 ,
wherein the first desorber and the second desorber are coupled thermally to one another.

14. The device as claimed in claim 7 ,
wherein the combustion apparatus comprises a gas turbine.

15. The device as claimed in claim 7 , further comprising:
a heat recovery apparatus arranged between the combustion apparatus and the second absorber.

16. The device as claimed in claim 7 ,
wherein the gas stream comprises a natural gas stream.

Assignees

• Siemens Ag

Inventors

• Brechtel Kevin
• Fischer Bjorn
• Schneider Rudiger
• Schramm Henning

Classifications

• B01D2252/20436

  Cyclic amines · CPC title

• F23R3/40

  characterised by the use of catalytic means · CPC title

• F02C3/04

  having a turbine driving a compressor (power transmission arrangements F02C7/36; control of working fluid flow F02C9/16) · CPC title

• C10L3/104

  Carbon dioxide · CPC title

• F23J7/00

  Arrangement of devices for supplying chemicals to fire · CPC title