Dental adhesive composition, dental adhesive primer, dental adhesive bonding material, dental adhesivecomposite resin, and dental adhesive resin cement

Patent metadata

Field	Value
Publication number	US-9987199-B2
Application number	US-201314413356-A
Country	US
Kind code	B2
Filing date	Jun 27, 2013
Priority date	Jul 10, 2012
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

Provided are a dental adhesive composition, a dental adhesive primer, a dental adhesive bonding material, a dental adhesive composite resin, and a dental adhesive resin cement each having an excellent adhesive force and excellent adhesion durability. Specifically, provided are a dental adhesive composition, including (A) a polymerizable monomer containing an acidic group-containing polymerizable monomer, and (B) a dendritic polymer, and a dental adhesive primer, a dental adhesive bonding material, a dental adhesive composite resin, and a dental adhesive resin cement each using the dental adhesive composition.

First claim

The invention claimed is:

1. A dental adhesive composition, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer; and
(C) water,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein an electric conductivity of the dental adhesive composition is 205 μm/cm or more.

2. A dental adhesive composition according to claim 1 , wherein the acidic group comprises a phosphate group.

3. A dental adhesive composition according to claim 1 , wherein (B) the dendritic polymer comprises at least one kind of material selected from a dendrimer and a hyperbranched polymer, and has a weight-average molecular weight of 1,500 or more.

4. A dental adhesive composition according to claim 1 , wherein (B) the dendritic polymer comprises a hyperbranched polymer containing a unit structure represented by the following general formula (I), and at least one unit structure selected from a unit structure represented by the following general formula (IIA) and a unit structure represented by the following general formula (IIB):

in the general formula (I), A represents a single bond for bonding C and R1, >C═O, —O—, —COO—, or —COO—CH2-, R 1 represents a divalent saturated aliphatic hydrocarbon group or a divalent aromatic hydrocarbon group, and R 2 represents a hydrogen atom or a methyl group, in the general formula (IIA) and the general formula (IIB), R 3 , R 4 , and R 5 each represent a hydrogen atom, an alkyl group having a main chain containing 1 to 5 carbon atoms, an alkoxycarbonyl group having a main chain containing 1 to 5 carbon atoms, an aryl group, or a cyano group, and in the general formula (IIB), R 6 represents an alkylene group having a main chain containing 4 to 10 carbon atoms.

5. A dental adhesive composition according to claim 1 , further comprising (D) a polymerization initiator.

6. A dental adhesive composition according to claim 1 , further comprising (E) a filler.

7. A dental adhesive primer, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer; and
(C) water,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein an electric conductivity of the dental adhesive primer is 205 μm/cm or more.

8. A dental adhesive bonding material, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer;
(C) water; and
(D) a polymerization initiator,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein an electric conductivity of the dental adhesive bonding material is 205 μm/cm or more.

9. A dental adhesive composite resin, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer;
(C) water;
(D1) a photopolymerization initiator; and
(E) a filler,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein an electric conductivity of the dental adhesive composite resin is 205 μm/cm or more.

10. A dental adhesive resin cement, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer;
(C) water;
(D2) a chemical polymerization initiator; and
(E) a filler,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein an electric conductivity of the dental adhesive resin cement is 205 μm/cm or more.

11. A dental adhesive composition according to claim 1 , the amount of (C) the water falls within the range of from 5 parts by mass to 20 parts by mass with respect to 100 parts by mass of the oily component.

12. A dental adhesive composition, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer; and
(B) a dendritic polymer,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein the dental adhesive composition does not comprise water.

13. A dental adhesive primer according to claim 7 , the amount of (C) the water falls within the range of from 5 parts by mass to 20 parts by mass with respect to 100 parts by mass of the oily component.

14. A dental adhesive bonding material according to claim 8 , the amount of (C) the water falls within the range of from 5 parts by mass to 20 parts by mass with respect to 100 parts by mass of the oily component.

15. A dental adhesive composite resin according to claim 9 , the amount of (C) the water falls within the range of from 5 parts by mass to 20 parts by mass with respect to 100 parts by mass of the oily component.

16. A dental adhesive composite resin, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer;
(D1) a photopolymerization initiator; and
(E) a filler,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connecting the branching portions,
wherein (B) the dendritic polymer does not have an amino group, and
wherein the dental adhesive composite resin does not comprise water.

17. A dental adhesive resin cement according to claim 10 , the amount of (C) the water falls within the range of from 5 parts by mass to 20 parts by mass with respect to 100 parts by mass of the oily component.

18. A dental adhesive resin cement, comprising:
(A) a polymerizable monomer containing an acidic group-containing polymerizable monomer;
(B) a dendritic polymer;
(D2) a chemical polymerization initiator; and
(E) a filler,
wherein (B) the dendritic polymer has a network structure including at least one kind of branching portion selected from a trifurcated branching portion and a four-furcated branching portion, and a connecting portion for connectin

Assignees

• Inaki Yoshitaka
• Shimizu Tomonao
• Hirata Kouichirou
• Tokuyama Dental Corp

Inventors

• Inaki Yoshitaka
• Shimizu Tomonao
• Hirata Kouichirou

Classifications

• A61K6/30 Primary

  Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives · CPC title

• C08L101/005

  Dendritic macromolecules · CPC title

• C08L43/02

  Homopolymers or copolymers of monomers containing phosphorus · CPC title

• A61K6/0023 Primary

  Human Necessities · mapped topic