Cathode active material for lithium-sulfur battery and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-9985291-B2
Application number	US-201414655944-A
Country	US
Kind code	B2
Filing date	Jan 7, 2014
Priority date	Jan 8, 2013
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

The present invention relates to a cathode active material for a lithium-sulfur battery and a method of preparing the same, and more particularly, to a cathode active material for a lithium-sulfur battery comprising: an amphiphilic polymer comprising hydrophilicity parts and hydrophobicity parts; and a sulfur-carbon composite, and a method of preparing the same. When a lithium-sulfur battery is prepared using the cathode active material, there is an effect which may enhance the electric conductivity in an electrode, cycle characteristics and capacity.

First claim

The invention claimed is:

1. A cathode active material for a lithium-sulfur battery comprising:
an amphiphilic polymer comprising hydrophilic parts and hydrophobic parts; and
solid sulfur-carbon composite particles,
wherein the amphiphilic polymer comprises one or more selected from the group consisting of polyvinyl pyrrolidone (PVP), polyvinyl alcohol (PVA) and a copolymer thereof,
wherein the amphiphilic polymer is positioned on a surface of the solid sulfur-carbon composite particles to form a micelle structure,
wherein the solid sulfur-carbon composite particles are particles which are sulfur particles applied on porous carbon, or particles which are sulfur particles mixed with carbon, and
wherein the amphiphilic polymer is included in an amount of 5 to 20 wt % based on a total weight of the cathode active material.

2. The cathode active material for a lithium-sulfur battery of claim 1 , wherein the hydrophobic parts of the amphiphilic polymer are oriented toward the solid sulfur-carbon composite particles.

3. A cathode comprising the cathode active material for a lithium-sulfur battery of claim 1 .

4. A lithium-sulfur battery comprising:
an anode comprising lithium metal or a lithium alloy;
a cathode comprising the cathode active material of claim 1 ;
a separator positioned between the cathode and the anode; and
an electrolyte impregnated in the anode, cathode and the separator and comprising a lithium salt and an organic solvent.

5. The lithium-sulfur battery of claim 4 , wherein the cathode further comprises one or more additives selected from transition metal elements, IIIA Group elements, IVA Group elements, sulfur compounds of these elements, and alloys of these elements and sulfur.

6. The lithium-sulfur battery of claim 4 , wherein the lithium salt is one or more selected from the group consisting of LiSCN, LiBr, LiI, LiPF 6 , LiBF 4 , LiSO 3 CF 3 , LiClO 4 , LiSO 3 CH 3 , LiB(Ph) 4 , LiC(SO 2 CF 3 ) 3 and LiN(SO 2 CF 3 ) 2 .

7. The lithium-sulfur battery of claim 4 , wherein the lithium alloy as the anode active material is a lithium/aluminum alloy or a lithium/tin alloy.

8. The lithium-sulfur battery of claim 4 , wherein the organic solvent is a single solvent or a mixed organic solvent of two or more solvents.

9. A battery module comprising the lithium-sulfur battery of claim 4 as a unit cell.

10. A method of preparing a cathode active material for a lithium-sulfur battery of claim 1 , the method comprising:
mixing solid sulfur-carbon composite particles and a solution comprising the amphiphilic polymer comprising hydrophilic parts and hydrophobic parts.

Assignees

• Lg Chemical Ltd

Inventors

• Son Byoungkuk
• Jang Minchul
• Kim Yu Mi
• Park Hong Kyu
• Sung Da Young
• Lee Seong Ho

Classifications

• H01M10/0568

  characterised by the solutes · CPC title

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/364

  as mixtures · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/38

  of elements or alloys · CPC title