Process for producing a toner

Patent metadata

Field	Value
Publication number	US-9983491-B2
Application number	US-201715439435-A
Country	US
Kind code	B2
Filing date	Feb 22, 2017
Priority date	Mar 1, 2016
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

A process for producing a toner of the present invention includes: a first step of heating a dispersion containing an aqueous medium and a binder resin containing a crystalline resin to a temperature higher than or equal to a melting point of the crystalline resin; and a second step of maintaining the dispersion at temperature T (° C.) for 30 minutes or longer in a state where a pH of the dispersion is maintained at 5.5 or higher and 9.0 or lower, in which the temperature T satisfies the following expression, Rc−25≤T≤Rc−5, where the Rc represents a recrystallization temperature (° C.) of the crystalline resin.

First claim

What is claimed is:

1. A process for producing a toner comprising:
a first step of heating an aqueous dispersion of fine particles of a binder resin, the binder resin comprising an amorphous resin and a crystalline resin, to a temperature higher than or equal to a melting point of the crystalline resin in the presence of a metal ion, whereby the fine particles of the binder resin are aggregated and fused to form a dispersion of toner base particles; and
a second step of maintaining the dispersion of the toner base particles at a temperature T (° C.) for 30 minutes or longer where the dispersion is maintained at a pH of 5.5 or higher and 9.0 or lower, the temperature T satisfying the following expression, Rc−25≤T≤Rc−5, wherein the Rc represents a recrystallization temperature (° C.) of the crystalline resin.

2. The process for producing a toner according to claim 1 , wherein the temperature T satisfies the following expression, Rc−25≤T≤Rc−10.

3. The process for producing a toner according to claim 1 , further comprising a step of cooling the dispersion to a temperature lower than Rc−25° C. after the aqueous dispersion is heated to a temperature higher than the Rc in the first step.

4. The process for producing a toner according to claim 1 , further comprising a step of cooling the dispersion to a temperature lower than the Rc at a temperature-lowering rate of 1° C./min or higher after the aqueous dispersion is heated to a temperature higher than the Rc in the first step.

5. The process for producing a toner according to claim 1 , wherein the crystalline resin is a crystalline polyester resin.

6. The process for producing a toner according to claim 1 ,
wherein the binder resin is a hybrid resin having an amorphous resin segment and a crystalline resin segment,
the amorphous resin is the amorphous resin segment of the hybrid resin, and
the crystalline resin is the crystalline resin segment of the hybrid resin.

7. The process for producing a toner according to claim 1 , wherein the metal ion is a divalent metal ion.

8. The process for producing a toner according to claim 1 , further comprising a step of cooling the dispersion to a temperature lower than the Rc at a temperature-lowering rate of 2° C./min or higher after the first step and when the aqueous dispersion is at a temperature of Rc.

9. The process for producing a toner according to claim 1 , further comprising a step of cooling the dispersion to a temperature lower than the Rc at a temperature-lowering rate of 5° C./min or higher after the first step and when the aqueous dispersion is at a temperature of Rc.

10. The process for producing a toner according to claim 1 , wherein the pH of the dispersion in the second step is 6.0 or higher and 8.0 or lower.

11. The process for producing a toner according to claim 1 , wherein a content of the crystalline resin is 3 to 30 mass % based on the toner.

12. The process for producing a toner according to claim 1 , wherein the crystalline resin has a melting point of 50 to 90° C.

13. The process for producing a toner according to claim 1 , wherein the crystalline resin has a melting point of 60 to 80° C.

14. The process for producing a toner according to claim 1 , wherein the toner base particles contain an amorphous polyester resin in an amount of 1 to 50 mass %.

15. The process for producing a toner according to claim 1 , wherein the toner base particles have a core-shell structure having a shell layer on a core, and the shell layer contains an amorphous polyester resin modified with a styrene-acrylic resin.

16. The process for producing a toner according to claim 1 , wherein a content of the crystalline resin in the binder resin is 5 to 50 mass %.

Assignees

• Konica Minolta Inc

Inventors

• Onishi Junya
• Hirano Shiro
• Ueda Noboru
• Sugama Kouji
• Shirai Aya

Classifications

• G03G9/0825

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title

• G03G9/0815

  Post-treatment · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/0804 Primary

  whereby the components are brought together in a liquid dispersing medium · CPC title