Electrophotographic apparatus

Patent metadata

Field	Value
Publication number	US-9983490-B2
Application number	US-201715469935-A
Country	US
Kind code	B2
Filing date	Mar 27, 2017
Priority date	Mar 31, 2016
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

The present invention provides an electrophotographic apparatus in which the deterioration of electrical properties in repetitive use is suppressed even in the case where an electrophotographic photosensitive member absorbs moisture under a high-temperature and high-humidity environment. An undercoat layer of the electrophotographic photosensitive member provided in the electrophotographic apparatus contains (α) a metal oxide particle, (β) a particular benzophenone compound and (γ) a compound represented by the following formula (2).

wherein R 11 to R 15 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, an alkoxy group or an amino group and A 1 represents an alkenyl group having 2 or more and 4 or less carbon atoms.

First claim

What is claimed is:

1. An electrophotographic apparatus comprising:
an electrophotographic photosensitive member;
a charging roller disposed so as to abut on the electrophotographic photosensitive member; and
a charging unit charging the electrophotographic photosensitive member by applying only a direct-current voltage, wherein
the electrophotographic photosensitive member comprises:
a support;
a photosensitive layer; and
an undercoat layer between the support and the photosensitive layer, the undercoat layer comprising:
(α) a metal oxide particle;
(β) a benzophenone compound represented by formula (1)

wherein R 1 to R 10 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, an alkoxy group or an amino group, provided that at least 3 of R 1 to R 10 is a hydroxy group; and
(γ) a compound represented by formula (2)

wherein R 11 to R 15 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, an alkoxy group or an amino group and A 1 represents an alkenyl group having 2 to 4 carbon atoms.

2. The electrophotographic apparatus according to claim 1 , wherein the (α) is a metal oxide particle comprising a zinc oxide particle.

3. The electrophotographic apparatus according to claim 1 , wherein the (β) is a benzophenone compound wherein 2 adjacent groups of R 6 to R 10 in the formula (1) are hydroxy groups.

4. The electrophotographic apparatus according to claim 1 , wherein the (γ) is a compound wherein A 1 in the formula (2) is a 1-propenyl group.

5. The electrophotographic apparatus according to claim 1 , wherein a content of the (β) in the undercoat layer is 0.1 to 4.0% by mass relative to a content of the (α) in the undercoat layer.

6. The electrophotographic apparatus according to claim 1 , wherein a content of the (γ) is 1.0 to 15% by mass relative to a content of the (β) in the undercoat layer.

7. A process for producing an electrophotographic photosensitive member comprising a support, a photosensitive layer, and an undercoat layer between the support and the photosensitive layer, the process comprising:
forming a coating film through coating with a coating liquid for an undercoat layer; and
drying the coating film, thereby forming the undercoat layer, wherein
the coating liquid for an undercoat layer comprises:
(α) a metal oxide particle;
(β) a benzophenone compound represented by formula (1)

wherein R 1 to R 10 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, an alkoxy group or an amino group, provided that at least 3 of R 1 to R 10 is a hydroxy group;
(γ) a compound represented by formula (2)

wherein R 11 to R 15 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, an alkyl group, an alkoxy group or an amino group and A 1 represents an alkenyl group having 2 to 4 carbon atoms; and
(δ) water, wherein a water content of the coating liquid for an undercoat layer is 2 to 10% by mass relative to a total mass of the coating liquid for an undercoat layer.

8. The process for producing an electrophotographic photosensitive member according to claim 7 , wherein the (α) is a metal oxide particle comprising a zinc oxide particle.

9. The process for producing an electrophotographic photosensitive member according to claim 7 , wherein the (β) is a benzophenone compound wherein 2 adjacent groups of R 6 to R 10 in the formula (1) are hydroxy groups.

10. The process for producing an electrophotographic photosensitive member according to claim 7 , wherein the (γ) is a compound wherein A 1 in the formula (2) is a 1-propenyl group.

11. The process for producing an electrophotographic photosensitive member according to claim 7 , wherein a content of the (β) in the undercoat layer is 0.1 to 4.0% by mass relative to a content of the (α) in the undercoat layer.

12. The process for producing an electrophotographic photosensitive member according to claim 7 , wherein a content of the (γ) is 1.0 to 15% by mass relative to a content of the (β) in the undercoat layer.

Assignees

• Canon Kk

Inventors

• Shimada Tsuyoshi
• Tokimitsu Ryoichi
• Murakami Mai
• Tanabe Kan
• Kitamura Wataru
• Mitsuda Haruhiko

Classifications

• G03G15/0216

  by bringing a charging member into contact with the member to be charged, e.g. roller, brush chargers · CPC title

• G03G5/142

  Inert intermediate layers · CPC title

• G03G5/144 Primary

  comprising inorganic material · CPC title

• G03G2215/025

  using contact charging means having lateral dimensions related to other apparatus means, e.g. photodrum, developing roller · CPC title

• G03G2215/00957

  Compositions · CPC title