Nitrogen oxide decomposition material and use thereof

Patent metadata

Field	Value
Publication number	US-9983165-B2
Application number	US-201414772562-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 6, 2013
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

The present teaching rekates to providing a NOx decomposition agent having an excellent NOx decomposition rate. The NOx decomposition agent containing a perovskite oxide represented by ABx-1MxO 3 , wherein A represents one or more elements selected from the group consisting of La, Sr, Mg, Ca and Ba, B represents Mn, M represents a combination of one or more first metal elements selected from the group consisting of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W and Ce, and one or two second metal elements selected from the group consisting of Ca and Mg, and x represents a number greater than or equal to 0 and less than 1.

First claim

The invention claimed is:

1. A NOx decomposition agent, comprising a perovskite oxide represented by:
AB 1-x M x O 3 ,
wherein
A represents one, two, or more kinds selected from the group consisting of La, Sr, Mg, Ca, and Ba,
B represents one, two, or more kinds selected from the group consisting of Ni, Fe, Co, Mn, Cr, and Cu,
M represents a combination of one, two or more first metallic elements selected from the group consisting of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W, and Ce, and one or two second metallic elements selected from the group consisting of Ca and Mg, the combination having a molar ratio of the first metallic element to the second metallic element such that a charge of the first metallic element and a charge of the second metallic element balance out each other, and
x represents a number greater than 0 and less than 1.

2. The NOx decomposition agent according to claim 1 , wherein B represents Mn.

3. The NOx decomposition agent according to claim 1 , wherein M represents a combination of Ce and Mg.

4. The NOx decomposition agent according to claim 1 , wherein x represents a number equal to or less than 0.2.

5. The NOx decomposition agent according to claim 4 , wherein
A represents La and Sr,
B represents Mn, and
M represents a combination of Ce and Mg.

6. A NOx sensor, comprising:
an electrochemical cell that comprises:
(a) a solid electrolyte;
(b) a first electrode that comprises a NOx decomposition catalytic phase containing a perovskite oxide represented by AB 1-x M x O 3 , the first electrode being exposed to a NOx-containing gas; and
(c) a second electrode that is located to face the first electrode via the solid electrolyte interposed therebetween, the second electrode being kept from coming into contact with the NOx-containing gas;
wherein
the first electrode comprises the NOx decomposition catalytic phase that is essentially composed of the perovskite-type oxide represented by AB 1-x M x O 3 , wherein
A represents one, two, or more kinds selected from the group consisting of La, Sr, Mg, Ca, and Ba,
B represents one, two, or more kinds selected from the group consisting of Ni, Fe, Co, Mn, Cr, and Cu,
M represents a combination of one, two, or more first metallic elements selected from the group consisting of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W, and Ce, and one or two second metallic elements selected from the group consisting of Ca and Mg, the combination having a molar ratio of the first metallic element to the second metallic element such that a charge of the first metallic element and a charge of the second metallic element balance out each other, and
x represents a number greater than 0 and less than 1, and
the first electrode keeps the solid electrolyte from coming into contact with the NOx-containing gas.

7. The sensor according to claim 6 , wherein the first electrode consists of the NOx decomposition catalytic phase.

8. The sensor according to claim 6 , wherein the first electrode is configured to be capable of being exposed to the NOx-containing gas of which oxygen concentration is not controlled.

9. The sensor according to claim 6 , further comprising a temperature controller configured to control a temperature of the electrochemical cell to a predetermined temperature of equal to or greater than 400° C. and equal to or less than 800° C.

10. A method of detecting a NOx in a NOx-containing gas by using the NOx sensor according to claim 6 ,
the method comprising a decomposition step,
the decomposition step including decomposing NOx in the NOx-containing gas by applying a predetermined voltage between the first electrode and the second electrode of the sensor in a state where the first electrode of the electrochemical cell is exposed to the NOx-containing gas.

11. The method according to claim 10 , wherein the predetermined applied voltage (the absolute value thereof) is greater than 0 mV and equal to or less than 100 mV.

12. The method according to claim 10 , wherein
in the decomposition step, the electrochemical cell is operated at a predetermined temperature of equal to or greater than 400° C. and equal to or less than 800° C.

13. A NOx decomposition device, comprising:
an electrochemical cell that comprises:
(a) a solid electrolyte;
(b) a first electrode that comprises a NOx decomposition catalytic phase containing a perovskite oxide represented by AB 1-x M x O 3 , the first electrode being exposed to a NOx-containing gas; and
(c) a second electrode that is located to face the first electrode with the solid electrolyte interposed therebetween, the second electrode being kept from coming into contact with the NOx-containing gas; wherein the first electrode comprises the NOx decomposition catalytic phase that is essentially composed of the perovskite oxide represented by AB 1-x M x O 3 , wherein:
A represents one, two, or more kinds selected from the group consisting of La, Sr, Mg, Ca, and Ba,
B represents one, two, or more kinds selected from the group consisting of Ni, Fe, Co, Mn, Cr, and Cu,
M represents a combination of one, two, or more first metallic elements selected from the group consisting of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W, and Ce, and one or two second metallic elements selected from the group consisting of Ca and Mg, the combination having a molar ratio of the first metallic element to the second metallic element such that a charge of the first metallic element and a charge of the second metallic element balance out each other, and
x represents a number greater than 0 and less than 1, and
the first electrode keeps the solid electrolyte from coming into contact with the NOx-containing gas.

Assignees

• Japan Fine Ceramics Ct
• Toyota Motor Co Ltd

Inventors

• Ueda Taro
• Takahashi Seiji
• Kaneko Toyoharu
• Hashida Tatsuhiro
• Aoki Keiichiro

Classifications

• G01N33/0037

  NOx · CPC title

• B01D53/8628

  Processes characterised by a specific catalyst · CPC title

• B01D53/9422

  for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR) · CPC title

• B01D2255/2047

  Magnesium · CPC title

• B01J23/002

  Mixed oxides other than spinels, e.g. perovskite · CPC title