Sensor devices comprising a metal-organic framework material and methods of making and using the same

Patent metadata

Field	Value
Publication number	US-9983124-B2
Application number	US-201615019811-A
Country	US
Kind code	B2
Filing date	Feb 9, 2016
Priority date	Feb 9, 2015
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

Disclosed herein are embodiments of sensor devices comprising a sensing component able to determine the presence of, detect, and/or quantify detectable species in a variety of environments and applications. The sensing components disclosed herein can comprise MOF materials, plasmonic nanomaterials, or combinations thereof. In an exemplary embodiment, light guides can be coupled with the sensing components described herein to provide sensor devices capable of increased NIR detection sensitivity in determining the presence of detectable species, such as gases and volatile organic compounds. In another exemplary embodiment, optical properties of the plasmonic nanomaterials combined with MOF materials can be monitored directly to detect analyte species through their impact on external conditions surrounding the particle or as a result of charge transfer to and from the plasmonic material as a result of interactions with the plasmonic material and/or the MOF material.

First claim

We claim:

1. A light guide comprising a section modified with a metal-organic framework material comprising a metal selected from copper, silver, gold, aluminum, zinc, cobalt, nickel, magnesium, manganese, iron, cadmium, beryllium, calcium, titanium, tin, chromium, vanadium, or a combination thereof; and an organic ligand selected from a mono-, di-, tri-, or tetra-valent ligand; wherein the light guide does not comprise a grating.

2. The light guide of claim 1 , wherein the section of the light guide modified with the metal-organic framework material is further modified with a plasmonic nanomaterial comprising a metal oxide selected from an indium oxide, tin oxide, titanium oxide, zirconium oxide, cesium oxide, zinc oxide, copper oxide, or gallium oxide; and a dopant selected from Pt, Au, Sn, Al, Nb, or Ta.

3. The light guide of claim 1 , wherein the section of the light guide modified with the metal-organic framework is an exposed core surface area of the light guide.

4. A method of determining the presence of a detectable species, comprising:
exposing a sample to the light guide of claim 1 ; and
analyzing the sample for a near-infrared signal produced by a detectable species absorbed by the metal-organic framework material of the light guide of claim 1 .

5. The method of claim 4 , wherein the sample is an environmental sample selected from a gas sample or an air sample.

6. The light guide of claim 1 , wherein the light guide delivers near-infrared light.

7. The light guide of claim 1 , wherein the light guide is a multi-mode optical fiber or a single-mode optical fiber.

8. The light guide of claim 1 , wherein the section modified with the metal-organic framework material has a surface area ranging from 0.01% to 10% of the light guide.

9. The light guide of claim 1 , wherein the section modified with the metal-organic framework material has a distance of 5 cm to 15 cm.

10. The light guide of claim 1 , wherein the light guide comprises a plurality of sections modified with the metal-organic framework material.

11. The light guide of claim 2 , wherein the plasmonic nanomaterial is fully encapsulated by the metal-organic framework material.

12. The light guide of claim 2 , wherein the plasmonic nanomaterial is embedded within internal pores of the metal-organic framework material.

13. The light guide of claim 11 , wherein the plasmonic nanomaterial is encapsulated within one or more layers of the metal-organic framework material.

14. The light guide of claim 1 , wherein the light guide is physically coupled to the metal-organic framework material.

15. The light guide of claim 1 , wherein the light guide is chemically coupled to the metal-organic framework material.

16. The light guide of claim 1 , wherein a thin layer of the metal-organic framework material having a thickness ranging from 1 nm to less than 500 nm is coupled to the light guide.

17. The light guide of claim 1 , wherein a thick layer of the metal-organic framework material having a thickness ranging from 500 nm to 50 μm is coupled to the light guide.

18. The light guide of claim 1 , wherein the light guide detects gases at concentrations ranging from 100 ppm to 500 ppm.

19. The light guide of claim 1 , wherein the light guide exhibits a response time of 0.1 seconds to 100 seconds.

Assignees

• Univ Oregon State
• Us Dept Energy

Inventors

• Wang Alan X
• Chang Chih-Hung
• Kim Ki-Joong
• Chong Xinyuan
• Ohodnicki Paul R

Classifications

• G01N21/554

  detecting the surface plasmon resonance of nanostructured metals, e.g. localised surface plasmon resonance · CPC title

• G01N21/7703

  using reagent-clad optical fibres or optical waveguides (using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B) · CPC title

• G01N2021/7709

  Distributed reagent, e.g. over length of guide · CPC title

• B01J20/226

  Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF] (preparation of metal complexes containing carboxylic acid moieties C07C51/418; MOF's per se C07F) · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title