Polypropylene compositions

Patent metadata

Field	Value
Publication number	US-9982120-B2
Application number	US-201515117320-A
Country	US
Kind code	B2
Filing date	Feb 4, 2015
Priority date	Feb 6, 2014
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

The present disclosure relates to a heterophasic polypropylene compositions comprising 78-85% by weight of a propylene homopolymer or copolymer matrix with up to 2.0% by weight of ethylene units, 15-22% by weight of an elastomeric ethylene-propylene copolymer and a clarifying agent. The composition has an intrinsic viscosity of the xylene soluble fraction at room temperature of from 0.5 to 1.5 dl/g and a melt flow rate (230° C., 2.16 kg) of 0.5 to 10 g/10 min. The compositions of the present disclosure can be used to prepare sheets for thermoforming applications.

First claim

What is claimed is:

1. A polypropylene composition comprising:
(a) 78-85% by weight of a propylene homopolymer or of a copolymer of propylene comprising an ethylene content of up to 2.0% by weight;
(b) 15-22% by weight of a copolymer of ethylene with propylene comprising an ethylene content of 78-90% by weight; and
(c) 0.4-1% by weight of a clarifying agent;
wherein the composition has an intrinsic viscosity of the xylene soluble fraction (XSIV) at room temperature of 0.5-1.5 dl/g and a melt flow rate (MFR, 230° C., 2.16 kg) of 0.5-10 g/10 min.

2. The propylene polymer composition of claim 1 , wherein the clarifying agent is selected among sorbitol derivatives, nonitol derivatives and phosphate derivatives.

3. The propylene polymer composition of claim 2 , wherein the clarifying agent is selected from 1,3:2,4-bis-(3,4-dimethylbenzylidene) sorbitol and 1,2,3-trideoxy-4,6:5,7-bis-O-[(4-propylphenyl)methylene]-nonitol.

4. A process for the preparation of the polyolefin composition of claim 1 , comprising at least two sequential polymerization stages, with each subsequent polymerization being conducted in the presence of the polymeric material formed in the immediately preceding polymerization reaction, wherein the polymerization stage of propylene to the polymer component (a) is carried out in at least one stage, and at least one copolymerization stage of mixtures of ethylene with propylene to the elastomeric polymer component (b) is carried out.

5. The process of claim 4 , wherein the polymerization stages are carried out in the presence of a stereospecific Ziegler-Natta catalyst.

6. The process of claim 4 , wherein the stereospecific Ziegler-Natta catalyst comprises:
(i) Mg, Ti, a halogen and an internal electron donor;
(ii) an alkylaluminum compound and, optionally;
(iii) one or more external electron-donor compounds (external donor).

7. The process of claim 4 , wherein the polymerization of the polymer component (a) is carried out in liquid monomer, while the copolymerization stages of the elastomeric copolymer component (b) is carried out in gas phase.

8. A sheet comprising the propylene polymer composition of claim 1 .

9. A thermoformed article comprising the propylene polymer composition of claim 1 .

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Nakajima Takeshi
• Sakai Kazuhiko
• Kuriyama Minoru
• Maruyama Masanori

Classifications

• C08L2207/02

  Heterophasic composition · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08K5/0083

  Nucleating agents promoting the crystallisation of the polymer matrix · CPC title

• C08L2203/30

  used for thermoforming · CPC title