Catalyst for producing hydrogen and method for producing hydrogen

Patent metadata

Field	Value
Publication number	US-9981845-B2
Application number	US-201615211599-A
Country	US
Kind code	B2
Filing date	Jul 15, 2016
Priority date	Sep 20, 2012
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

A metal-supporting catalyst for decomposing ammonia into hydrogen and nitrogen. The catalyst shows a high performance with a low cost and being advantageous from the viewpoint of resources, and an efficient method for producing hydrogen using the catalyst. The catalyst catalytically decomposes ammonia gas to generate hydrogen. The hydrogen generation catalyst includes, as a support, a mayenite type compound having oxygen ions enclosed therein or a mayenite type compound having 10 15 cm −3 or more of conduction electrons or hydrogen anions enclosed therein, and metal grains for decomposing ammonia are supported on the surface of the support. Hydrogen is produced by continuously supplying 0.1-100 vol % of ammonia gas to a catalyst layer that comprises the aforesaid catalyst, and reacting the same at a reaction pressure of 0.01-1.0 MPa, at a reaction temperature of 300-800° C. and at a weight hourly space velocity (WHSV) of 500/mlg −1 h −1 or higher.

First claim

The invention claimed is:

1. A method for producing hydrogen comprising:
continuously supplying an ammonia gas with a volume fraction of 0.1 to 100% to a catalyst layer comprising supported metal catalyst packed in a reactor; and
performing contact decomposition reaction at a reaction temperature of 350° C. to 800° C.,
wherein the supported metal catalyst comprises
a support comprising a mayenite-type compound which includes 10 15 cm −3 or more of conduction electrons or hydrogen anions, and
particles of catalytically active metal for ammonia decomposition which are supported on a surface of the support,
wherein the contact decomposition reaction is performed at a weight hourly space velocity (WHSV) of 500 /mlg −1 h −1 or more.

2. The method for producing hydrogen according to claim 1 , wherein the contact decomposition reaction is performed at a pressure of 0.01 MPa to 1.0 MPa.

3. The method for producing hydrogen according to claim 1 , wherein the catalytically active metal comprises at least one selected from the metal elements of Groups VIII, IX, and X.

4. The method for producing hydrogen according to claim 1 , wherein the supported metal catalyst includes the catalytically active metal at an amount of 0.01 wt % to 30 wt % of the mayenite-type compound.

5. The method for producing hydrogen according to claim 1 , wherein the supported metal catalyst has a BET specific surface area of 1 to 100 m 2 g −1 .

6. A method for producing hydrogen comprising:
continuously supplying an ammonia gas with a volume fraction of 0.1 to 100% to a catalyst layer comprising supported metal catalyst packed in a reactor; and
performing contact decomposition reaction at a reaction temperature of 350° C. to 800° C.,
wherein the supported metal catalyst comprises
a support comprising a mayenite-type compound which includes oxygen ions which has not been made to include 10 15 cm −3 or more of conduction electrons or hydrogen anions, and
particles of catalytically active metal for ammonia decomposition which are supported on a surface of the support,
wherein the contact decomposition reaction is performed at a weight hourly space velocity (WHSV) of 500 /mlg −1 h −1 or more.

7. The method for producing hydrogen according to claim 6 , wherein the contact decomposition reaction is performed at a pressure of 0.01 MPa to 1.0 MPa.

8. The method for producing hydrogen according to claim 6 , wherein the catalytically active metal comprises at least one selected from the metal elements of Groups VIII, IX, and X.

9. The method for producing hydrogen according to claim 6 , wherein the supported metal catalyst includes the catalytically active metal at an amount of 0.01 wt % to 30 wt % of the mayenite-type compound.

10. The method for producing hydrogen according to claim 6 , wherein the supported metal catalyst has a BET specific surface area of 1 to 100 m 2 g −1 .

Assignees

• Tokyo Inst Tech
• Japan Science & Tech Agency

Inventors

• Hosono Hideo
• Hayashi Fumitaka
• Yokoyama Toshiharu
• Toda Yoshitake
• Hara Michikazu
• Kitano Masaaki

Classifications

• B01J37/10

  in the presence of water, e.g. steam · CPC title

• B01J23/58

  with alkali- or alkaline earth metals · CPC title

• B01J37/0203

  the impregnation liquid containing organic compounds · CPC title

• B01J23/78

  with alkali- or alkaline earth metals · CPC title

• Y02E60/364

  Cross-Sectional Technologies · mapped topic