Catalyst preparation method

Patent metadata

Field	Value
Publication number	US-9981252-B2
Application number	US-201615279964-A
Country	US
Kind code	B2
Filing date	Sep 29, 2016
Priority date	May 1, 2009
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

A method for preparing a catalyst comprising (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.

First claim

The invention claimed is:

1. An eggshell catalyst comprising an outer eggshell layer comprising nickel oxide and having a thickness of 1000 microns or less on the surface of a calcined, shaped calcium aluminate cement support, wherein the nickel oxide is concentrated within the eggshell layer and not uniformly distributed within the calcined, shaped calcium aluminate cement support.

2. The eggshell catalyst of claim 1 wherein the calcium aluminate support comprises calcium aluminate cement powder and at least one of alumina or lime.

3. The eggshell catalyst of claim 1 further comprising an alkali metal oxide.

4. The eggshell catalyst of claim 1 wherein the support is in the form of a shaped pellet or extrudate.

5. The eggshell catalyst of claim 4 wherein the support is in the form of a cylindrical pellet having between 1 and 12 holes extending there-through.

6. The eggshell catalyst of claim 5 wherein the support is in the form of a cylindrical pellet having between 1 and 12 holes extending there-through and between 2 and 20 flutes or lobes.

7. The eggshell catalyst of claim 6 wherein the support has 4 holes extending there-though and 4 lobes.

8. The eggshell catalyst of claim 1 wherein nickel oxide content of the catalyst is in the range of from 2 wt % to 25% wt.

9. The eggshell catalyst of claim 1 , wherein the outer eggshell layer comprising nickel oxide has a thickness of 800 microns or less.

10. The eggshell catalyst of claim 1 , wherein the outer eggshell layer comprising nickel oxide has a thickness of 300 microns or less.

11. The eggshell catalyst of claim 4 , wherein each of the length, width, and height of the shaped pellet or extrudate is in the range of from 3 mm to 50 mm.

12. The eggshell catalyst of claim 5 , wherein the cylindrical pellet has a diameter in a range of from 4 mm to 40 mm, and an aspect ratio of length to width of 2 or less.

13. An eggshell catalyst comprising an outer eggshell layer of nickel oxide having a thickness of 1000 microns or less on the surface of a calcined, shaped calcium aluminate cement support, the eggshell catalyst precursor obtained by a method comprising:
(i) preparing a calcined shaped calcium aluminate catalyst support by forming a calcium aluminate cement powder, optionally with additional alumina and/or lime, into a desired shape, curing the cement and subsequently calcining the shaped support; then
(ii) treating the calcined shaped calcium aluminate support with water, said water being essentially free of salts, and drying the support; then
(iii) impregnating the dried support with the solution containing one or more nickel compounds and drying the impregnated support; then
(iv) calcining the dried impregnated support, to form the outer eggshell layer of nickel oxide on the surface of the support; and
(v) optionally repeating steps (ii), (iii) and (iv);
so as to form the eggshell catalyst precursor.

14. An eggshell catalyst obtained by subjecting the eggshell catalyst of claim 13 to a reducing environment, so as to produce an outer eggshell layer having a thickness of 1000 microns or less on the surface of a calcined, shaped calcium aluminate cement support, the outer eggshell layer comprising elemental nickel.

15. The eggshell catalyst of claim 14 , wherein the reducing environment comprises hydrogen.

16. An eggshell catalyst obtained by subjecting the eggshell catalyst of claim 14 to a oxygen environment, so as to provide a passivating layer of nickel oxide on the elemental nickel.

17. An eggshell catalyst comprising an outer eggshell layer comprising elemental nickel and having a thickness of 1000 microns or less on the surface of a calcined, shaped calcium aluminate cement support, wherein the elemental nickel is concentrated within the eggshell layer and not uniformly distributed within the calcined, shaped calcium aluminate cement support.

18. The eggshell catalyst of claim 17 , wherein the elemental nickel further comprises a passivating layer of nickel oxide.

Assignees

• Johnson Matthey Plc

Inventors

• Carlsson Mikael Per Uno
• Oliver Jonathan Geoffrey
• Feaviour Mark Robert
• Birdsall David James
• French Samuel Arthur

Classifications

• C01B2203/1082

  Composition of support materials · CPC title

• C07C1/04

  from carbon monoxide with hydrogen · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C01B2203/1241

  Natural gas or methane · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title