Electrode active material, electrode and energy storage device including the same, and method of preparing the electrode active material

Patent metadata

Field	Value
Publication number	US-9979018-B2
Application number	US-201615079961-A
Country	US
Kind code	B2
Filing date	Mar 24, 2016
Priority date	May 20, 2015
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

Disclosed is an electrode active material including nanostructures including boron-doped alumina. An electrode including the nanostructures, an energy storage device including the electrode, and a method of preparing the electrode active material are also disclosed.

First claim

What is claimed is:

1. An electrode active material comprising a nanostructure comprising a boron-doped alumina, and
further comprising:
a core active material,
wherein the nanostructure is disposed on a surface of the core active material, and
wherein the boron-doped alumina comprises boron-doped alumina represented by Formula 1:
Al x B y O z   [Formula 1]

wherein 1≤x<30, 1≤y<10, and 1≤z<40.

2. The electrode active material of claim 1 , wherein the electrode active material comprises a composite.

3. The electrode active material of claim 1 , wherein the nanostructure is at least one of a nanowire, a nanorod, a nanobelt, and a nanoribbon.

4. The electrode active material of claim 1 , wherein the nanostructure has an aspect ratio of about 1 to about 200.

5. The electrode active material of claim 1 , wherein the boron-doped alumina comprises at least one of AlBO 3 , Al 4 B 2 O 9 , Al 5 BO 9 , and Al 18 B 4 O 33 .

6. The electrode active material of claim 1 , wherein the nanostructure is disposed at an angle of 0 degrees to about 90 degrees with respect to a horizontal axis passing through a contact point on the core active material surface.

7. The electrode active material of claim 1 , wherein the nanostructure comprises a plurality of nanostructures, and the plurality of nanostructures are disposed at an angle of 0 degrees with respect to a horizontal axis passing through a contact point on the surface of the core active material or are disposed in parallel to the horizontal axis.

8. The electrode active material of claim 1 , wherein the nanostructure comprises a plurality of nanostructures, and the plurality of nanostructures are disposed at an angle of 0 degrees to about 90 degrees with respect to a horizontal axis passing through a contact point on the core active material surface, and
wherein the plurality of nanostructures are disposed at angles equal to or different from one another.

9. The electrode active material of claim 1 , wherein the core active material comprises an active material capable of intercalating and deintercalating lithium ions.

10. The electrode active material of claim 9 , wherein the active material comprises at least one of a metal oxide, a metal composite oxide, a lithium metal oxide, a lithium metal composite oxide, a carbonaceous material, silicon, a silicon oxide, tin, and a tin oxide.

11. The electrode active material of claim 10 , wherein the carbonaceous material comprises at least one of natural graphite, artificial graphite, soft carbon, hard carbon, mesophase pitch carbide, and calcined cokes.

12. The electrode active material of claim 1 , wherein the nanostructure comprises aluminum in an amount from about 0.1 parts by weight to about 99.99 parts by weight based on 100 parts by weight of the core active material.

13. The electrode active material of claim 1 , wherein the nanostructure comprises aluminum in an amount ranging from about 0.1 parts by weight to about 20 parts by weight based on 100 parts by weight of the core active material.

14. The electrode active material of claim 1 , wherein the electrode active material further comprises a carbon based coating layer formed on a surface of the nanostructure.

15. The electrode active material of claim 14 , wherein the carbon based coating layer has a thickness of about 0.1 nm to about 10 nm.

16. An electrode comprising:
a current collector; and
a layer formed on the current collector, the layer comprising the electrode active material according to claim 1 .

17. An energy storage device comprising the electrode according to claim 16 .

18. A method of preparing an electrode active material comprising:
contacting an alumina precursor with a mixture of a boron precursor and a solvent to form a precursor containing aluminum and boron; and
heating the precursor containing aluminum and boron to form a nanostructure comprising a boron-doped alumina, and
further comprising:
a core active material,
wherein the nanostructure is disposed on a surface of the core active material, and
wherein the boron-doped alumina comprises boron-doped alumina represented by Formula 1:
Al x B y O z   [Formula 1]

wherein 1≤x<30, 1≤y<10, and 1≤z<40.

19. The method of claim 18 , wherein the boron precursor is NaBH 4 .

20. The method of claim 18 , wherein the forming the precursor containing aluminum and boron comprises forming a gel type precursor containing aluminum and boron in a sol type mixed solution in which the alumina precursor is dispersed into the mixture of the boron precursor and the solvent.

21. The method of claim 18 , further comprising:
contacting the alumina precursor and the mixture of the boron precursor and the solvent with a core active material solution to form a precursor containing aluminum and boron on a core active material surface; and
heating the precursor containing aluminum and boron on the core active material surface to grow nanostructures comprising boron-doped alumina on the core active material surface.

22. The method of claim 21 , wherein aluminum in the precursor containing aluminum and boron is present in an amount from about 0.1 parts by weight to about 10 parts by weight based on 100 parts by weight of the core active material.

23. The method of claim 21 , wherein the heat treatment is performed at a temperature of about 800° C. to about 1300° C. in an inert gas atmosphere comprising a mixture of methane gas and hydrogen gas.

24. The method of claim 18 , wherein the forming of the nanostructures further comprises heating and carbonizing the precursor containing aluminum and boron.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Ham Dongjin
• Choi Jaeman
• Hwang Seungsik
• Lim Younhee
• Chang Jaejun

Classifications

• H01M4/049

  Manufacturing of an active layer by chemical means · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/483 Primary

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/366

  as layered products · CPC title