Polymer composition for electrical devices

Patent metadata

Field	Value
Publication number	US-9978478-B2
Application number	US-201214115108-A
Country	US
Kind code	B2
Filing date	May 3, 2012
Priority date	May 4, 2011
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

The present invention relates to a polymer composition, to the use of the composition for producing an electrical device, as well as to a cable surrounded by at least one layer including the polymer composition.

First claim

We claim:

1. A cable comprising a conductor surrounded by at least an inner semiconductive layer, an insulation layer and an outer semiconductive layer, in that order, wherein the insulation layer comprises a polymer composition, comprising:
(a) a polyethylene produced in the presence of an olefin polymerisation catalyst selected from very low density polyethylene (VLDPE) copolymers, linear low density polyethylene (LLDPE) copolymers, medium density polyethylene (MDPE) copolymers or high density polyethylene (HDPE) homopolymers or copolymers;
(b) a saturated or unsaturated LDPE homopolymer or a saturated or unsaturated LDPE copolymer of ethylene with one or more comonomer(s), and
(c) an ion exchanger additive;
wherein said ion exchanger additive is hydrotalcite and is present in an amount of 0.0001 to 0.015 wt % of the polymer composition.

2. The cable according to claim 1 , which is a crosslinkable direct current (DC) power cable, wherein said polymer composition of the layer of claim 1 or of the insulation layer of claim 1 further comprises a crosslinking agent.

3. The power cable according to claim 2 , which is a crosslinked direct current (DC) power cable, where the inner semiconductive layer comprises an optionally crosslinked first semiconductive composition, the polymer composition of the insulation layer comprises a polymer composition according to claim 2 which is crosslinked in the presence of said crosslinking agent, and the outer semiconductive layer comprises an optionally crosslinked second semiconductive composition.

4. A cable as claimed in claim 1 wherein the cable is a power cable.

5. A cable as claimed in claim 1 wherein the cable is a DC power cable.

6. A cable as claimed in claim 1 , wherein for the polyolefin (a) each type of polyethylene can be unimodal or multimodal with respect to molecular weight distribution.

7. A cable as claimed in claim 1 , wherein the second polyolefin (b) is an unsaturated LDPE homopolymer or an unsaturated LDPE copolymer of ethylene with one or more comonomer(s) which contains vinyl groups.

8. A cable as claimed in claim 1 , wherein the polyolefin (b) is an unsaturated LDPE copolymer of ethylene with at least one polyunsaturated comonomer and optionally with one or more other comonomer(s).

9. A cable as claimed in claim 8 , wherein the polyunsaturated comonomer is a C8-14 non-conjugated diene.

10. A cable as claimed in claim 1 , wherein the polyolefin (b) contains vinyl groups in total amount of more than 0.20/1000 carbon atoms.

11. A cable as claimed in claim 1 , wherein the ion exchanger additive (c) is an inorganic anion exchanger additive.

12. A cable as claimed in claim 1 , wherein the ion exchanger additive (c) is an anion exchanger additive of hydrotalcite type.

13. A cable as claimed in claim 1 , wherein the polymer composition comprises the ion exchanger additive (c) in an amount of 0.000001 to 0.7 wt %.

14. A cable as claimed in claim 1 , wherein the amount of the polyolefin (a) is 1.0 to 40 wt %, based on the combined weight of the polyolefin (a) and the second polyolefin (b).

15. A cable as claimed in claim 1 , wherein the amount of the second polyolefin (b) is 60 to 99.0 wt %, based on the combined weight of the polyolefin (a) and the second polyolefin (b).

16. A cable as claimed in claim 1 wherein the polymer composition comprises a peroxide in an amount of up to 100 mmol —O—O—/kg polymer composition.

17. A cable as claimed in claim 1 , wherein the polymer composition comprises:
(a) a MDPE polymer or a HDPE polymer,
(b) an optionally unsaturated LDPE homopolymer or an optionally unsaturated LDPE copolymer of ethylene with one or more comonomer(s),
(c) up to 1 wt % ion exchanger additive; and
a peroxide in an amount of less than 37 mmol —O—O—/kg polymer composition.

Assignees

• Andersson Johan
• Englund Villgot
• Hagstrand Per Ola
• Nilsson Ulf
• Smedberg Annika
• Steffl Thomas
• Wolfschwenger Johannes
• Borealis Ag

Inventors

• Andersson Johan
• Englund Villgot
• Hagstrand Per-Ola
• Nilsson Ulf
• Smedberg Annika
• Steffl Thomas
• Wolfschwenger Johannes

Classifications

• C08L2207/066

  LDPE (radical process) · CPC title

• C08L2203/202

  use in electrical wires or wirecoating · CPC title

• Y10T428/2967

  Synthetic resin or polymer · CPC title

• C08L2207/062

  HDPE · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title